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cyclopalladium
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Synthesis of Pincer Palladium Complexes and Molybdenium, Gold and Platinum Complexes Containing Azulene Based Ligands: Catalytic and Optical Properties Studies
, Ph.D. Dissertation Sharif University of Technology ; Bagherzadeh, Mojtaba (Supervisor) ; Jamali, Sirous (Supervisor)
Abstract
There are two parts in this thesis. The first one is about the synthesis of azulene based compounds, which are characterized by 13C and 1H NMR. These compounds were included in three imine ligands (1,2 and 3) and a NHC ligand (4). Azulene based materials shows a fluorescence emission. The stimuli-responsive emissive azulene derivatives are very rare. herein, we report the synthesis of stimuli responsive emissive 1- and 1,3-disubstitution azulene-based compounds that can switch on and off the emission upon protonation with trifluoroacetic acid (TFAH) and deprotonation with triethylamine respectively. The type of transitions were studied by computational calculations. The complexation of some...