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    Synthesis of Two-Dimensional Fluorinated Covalent-Organic Frameworks by Cyclotrimerization of Alkynes

    , M.Sc. Thesis Sharif University of Technology Ghanbari Bidrouni, Reza (Author) ; Kalhor, Hamid Reza (Supervisor) ; Adeli, Mohsen (Supervisor)
    Abstract
    Covalent organic frameworks are one of the attractive and important research fields that deals with the huge and predesigned polymeric structures. It is a developing field which focuses on the synthesis of different architectures with specific applications. In recent years, fluorinated materials have gained a high interest due to their unique physicochemical properties. The fluorinated microporous structures, due to their potential applications in gas, energy and materials storage as well as catalyst, are of high interest. In this work, fluorinated two-dimensional nanomaterials were synthesized based on hexafluorobenzene and decafluorobiphenyl. Catalyst free [2+2+2] cyclotrimerization of...