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dicyanostillbene
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Synthesis of Switchable Diazobenzene Nano-compounds, Fries type rearrangement of Carbonates and Ethers, Synthesis of Dicyano Stillbenes, Aromatics Bromination, Synthesis of Benzothiazoles and Thiophenes
, Ph.D. Dissertation Sharif University of Technology ; Matloubi Moghaddam, Firouz (Supervisor)
Abstract
In this project, Fries rearrangement of aryl benzyl ethers and ary benzyl carbonates, using catalyst and microwave irradiation in solvent-less system have been studied, and Benzylated phenols which have attracted a great deal of interest, due to their medicinal properties, were synthesized. The solvent-free Fries reactions have many advantages such as: reduced pollution, low costs, and simplicity in process and handling. We report the use of N-benzyl DABCO tribromide as an electrophilic bromine source and one of the OATBs for one-step oxidative coupling procedure of benzyl cyanides into Symmetrical α,ά -dicyanostilbenes. The reaction proceeds easily with higher yields and shorter reaction...