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glycidol
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Covalent Attachment of Lysozyme Enzyme to Sulfur-Glycerol Copolymer for the Preparation of Proteinosome as a Hierarchical Structure
, M.Sc. Thesis Sharif University of Technology ; Kalhor, Hamid Reza (Supervisor)
Abstract
Hyperbranched copolymers are highly attractive due to their unique properties, such as tunable structure and surface functionality, making them versatile for applications in biotechnologies, pharmaceuticals, and materials engineering. Glycidol, as a reactive monomer with excellent biocompatibility, combined with sulfur, which enhances mechanical and chemical properties, represents a promising combination for hyperbranched copolymer synthesis. In this study, hyperbranched glycidol-sulfur copolymers were synthesized using cationic and anionic ring-opening polymerization methods. FT-IR analysis confirmed the successful incorporation of S-S bonds and sulfur-containing functional groups into the...
Synthesis of Red Phosphorus-Glycerol Copolymer and its Covalent Binding to Lysozyme Enzyme to Investigate the Structure and Function of the Enzyme within the Complex and CQD-Catalyzed Synthesis of Formamide Compounds
, M.Sc. Thesis Sharif University of Technology ; Kalhor, Hamid Reza (Supervisor)
Abstract
Red phosphorus, due to its unique chemical properties, and glycidol, with its reactive functional groups, provide an effective combination for synthesizing new copolymers with potential applications in biological fields, particularly in enzyme stabilization. In this study, a novel copolymer was synthesized using red phosphorus and glycidol through an anionic ring-opening mechanism. The synthesis process was confirmed using various analytical techniques, including FTIR, NMR, and thermal analyses, which demonstrated the successful incorporation of functional groups and an average phosphorus content of 40% in the copolymer. In the next step, modification of this copolymer by linking it to the...