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      Synthesis, Structure and Catalytic Application of Mn, Fe and Mo Complexes with Schiff base and Oxazoline ligands and Theoretical Mechanistic Studies on the Role of Heme and non-Heme Iron(IV)-Oxo Species in Hydroxylation and Epoxidation Reactions

      , Ph.D. Dissertation Sharif University of Technology Tahsini , Laleh (Author) ; Bagherzadeh, Mojtaba (Supervisor)
      Abstract
      The first part of this thesis describes the synthesis and characterization of several Mn, Fe and Mo complexes containing tridentate Schiff base and oxazoline ligands and their reactivities as catalysts in the oxidation of organic compounds like olefins and sulfides, as well. The crystal structures of newly prepared cis-dioxo-bis[2-(2′-hydroxyphenyl)-oxazolinato]molybdenum(VI), cis-[MoO2(phox)2] and (N-hydroxyphenyl-salicylidenamine)(acetylacetonato)ethanol iron(III), [FeIII(N-OPh-sal)(acac)EtOH] complexes have been described by X-ray crystallography. Due to the difficulties in the preparation of suitable single crystals of novel... 

      Synthesis, Structure and Catalytic Application of Mn, Fe and Mo Complexes with Schiff base Ligands in the Oxidation of Olefins and Sulfides and Theoretical Mechanistic Studies on the Catalytic Activity of non-Heme Iron and Copper Enzymes

      , Ph.D. Dissertation Sharif University of Technology Latifi, Reza (Author) ; Bagherzadeh, Mojtaba (Supervisor)
    Total 2 records