Sharif Digital Repository

polyamides have found great attractions in wide variety of applications due to their desirable mechanical and tribological properties and appropriate processability. Pure polymers are not suitable for this kind of application due to their low mechanical strength. High strength materials are needed for abrasive applications. Polytetrafluoroethylene (PTFE) is one of the most popular materials for abrasive applications. In this study the effect of PTFE and surface modification on PA/PTFE composite properties is investigated. duo to modification of PTFE powder, PTFE is exposed to sodium naphtalenide (Na/naphtha) etchant so as to deflurinate the surface for obtaining carbonyl, carboxyl and... 

In this research, Al-20Si-5Fe-2X (X=Cu,Ni,Cr) alloys were produced by gas atomizing and melt spinning processes. Microstructure and growth morphology of powder and ribbons were investigated using optical microscopy, scanning electron microscopy and transmission electron microscopy, then, analyzed by solidification models. Powder and chopped ribbons were hot pressed at 400°C/250 MPa and microstructural variations, mechanical properties and thermal coefficient expansion were evaluated after consolidation. Results show that relatively high cooling rate in gas-atomized powders lead to refinement of the microstructure and formation of semi-equilibrium δ intermetallic phase. As the powder particle... 

In recent years the rapid rise of polymer consumption especially in the form of packaging materials became a real menace for the environment. Polyolefin are some of the most dominant packaging materials and responsible by part of the problems in the disposal of one-trip packaging. One of the possible ways of solving this problem is the introduction of additives increasing their susceptibility to environmental degradation into non-biodegradable polymers. One such additive is starch- the natural, cheap, and easily biodegradable polymer. Starch was already used as a filler or as a blend with polyolefin. Addition of dry starch granules to polyolefin follows the general trend of filler effects on... 

In this research ,Al-20Si-5Fe-3Cu-1Mg-XMn alloys were produced by gas atomizing and melt spinning processes. Microstructure and growth morphology of powder and ribbons were investigated using optical microscopy , scanning electron microscopy. powders were hot pressed at 400ºC/250Mpa and microstractural variations, mechanical properties were evaluated after consolidation. Results show that relatively high cooling rate in gas-atomized powders lead to refinement of microstructure and formation of semi-equilibrium δ intermetallic phase . As the powder particle size decrease , the growth morphology changes from primary silicon + euthectic to euthectic + primary dendritic aluminum . Mn changed the... 

Polyamides have found great attraction in the wide variety of application due to their desireable and tribological properties and appropriate processability. Due to their low mechanical strength reinforcing of these types of polymers has always been one of the important academic and industrial issues. In order to improve mechanical properties of such polymers, different kinds of reinforcement particles such as titaniom diaoxide, Nano clay, glass fibers (Short or long glass fiber), etc were used. Carbon nano tubes have high thermal and electrical conduction and mechanical properties; they are widely used as a reinforcement particle for polymer matrix. In this study, carbon nano tube and... 

Electrospinning is a method for producing of micro and nanometer polymeric fibers. Nowadays, electrospun fibers have been demanded a lot because of various applications of fibers in optical industries, tissue engineering, and chemical and biological sensors. Producing of more complicated shape of fibers by using two new methods called Electrical Bending and Mechanical Buckling are interested in this field. The aim of this thesis is to prepare such fibers and study the effective parameters on the shapes of them. Fibers are collected on the aluminum and Fluorine-doped tin oxide (FTO) glass. Then they were observed by optical microscope. In the Electrical Bending method, we used PEO: PAMPS and... 

Vibration is one of the most important factors in design, operation and lifetime of drill strings. There for, investigation of vibrations in drill string, like every other rotary machine, is very important. The main goal of this research is developing a nonlinear model for a drill string system dynamics in an inclined well. Effects of drilling mud flow rate, weight on bit, angular velocity along with viscous damping, on the stability and vibration of a drill string are studied. Dynamic equation of the model is developed considering axial displacement and lateral bending geometric nonlinear coupling. The effect of drilling mud flow is modeled using Paidoussis formulations. Equation of motion... 

Different types of morphologies and phase structures of crystalline TiO2 were synthesized by hydrothermal methods. For the first time, dandelion-like rutile TiO2 powder composed of numerous single crystalline nanorods was synthesized using TiCl4 as the main precursor. TiO2 Nanoparticles were produced using TTIP and 2-propanol, as precursor and solvent, respectively. Field emission scanning electron microscopy analyses revealed that the synthesized TiO2 nanoparticles had average crystallite size in the range 21–70 nm, whereas dandelion-like TiO2 showed diameter in the range 2-10 µm. According to the significant refractive index of TiO2, in particular rutile phase, it can be used in the... 

Syntheses of coats including nickel nano-particles by electrodeposition have been
investigated for over 10 years. A method of testing according to surface reply was chosen
to reveal the effect of each pulse parameters (including duty cycle, frequency, average
current density, off time (toff) and on time (ton)) and the effect of saccharin concentration
on electroplating cathode efficiency, nanostructure. Pulse electroplating test of nickel was
composed by 30 tests. Pulse electroplating with relatively high peak current density was
employed and saccharine was added to increase deposition and rate of nickel nucleation on
surface. According to the results of cathode... 

Synthesis and characterization of Nafion/TiO2 membranes whit different solvent (DMF, DMAc, NMP) for proton exchange membrane fuel cell (PEMFC) were investigated in this study. Nafion/ TiO2 nanocomposite membranes have been prepared by solution casting Method. The structures of membranes were investigated by Scanning Electron Microscopy (SEM). Also water uptake, proton conductivity and ion exchange capacity (IEC) of membranes were measured and compared whit Nafion 112 in microbial fuel cell. The membrane was prepared whit DMF solvent has maximum proton conductivity and best morphology and maximum cell voltage  

Improvement of semiconductors photocatalytic activity by different means has always been one of the challenges for researchers. Semiconductors doping for band-gap engineering and changing morphology to increase specific surface area and photocatalytic reaction sites are amongst these efforts. In this research simultaneous effect of these two parameters for three morphologies containing nanoparticle, nanowire and micro dandelion, simultaneously doped with carbon and nitrogen has been investigated. Final purpose of this thesis is to decrease the band-gap energy close to soft UV photon energies to make surface photodynamic therapy possible. Nanoparticle morphology with size distribution between... 

The increasing role of nanotechnology in our every-day-life, has aroused global concern regarding their hazardous potential, resulting in a demand for parallel risk assessment. Quatitative structure-activity relationships enable researches to use unique properties of nanoparticles as predictors for their toxicity or any other biological response. Extracting rational correlations between physicochemical properties of nanoparticles and their biological response, not only reveals the way that nanoparticles behave upon entering into biological media, but also leads to the design of safer and efficient nanoparticles for various applications of interest. This PhD dissertation presents QSAR tools... 

Blood is the most important liquid in human body. Red blood cells (RBCs) are the main part of blood. RBCs are rounded, but this shape would be changed during different disease. Blood tests taken to diagnose blood diseases. Current instruments do not provide any information about RBCs morphology, and an expert recognize the RBCs morphology by looking at blood smear under microscope. Regards to low accuracy and performance of this method, an automate method must be presented. Capturing images from blood smear under microscope is simple and low-cost. Although there is few methods on RBCs detection and very limited one on RBCs recognition on the literature, no general method to recognize most of... 

Morphology, microstructure, phase composition and arrangement modes of the photoanode electrode are the most important parameters which affect the photovoltaic properties of dye-sentisized solar cells (DSSCs). In most DSSCs the scattering layer has been used to improve their efficiency. In addition, there are different techniques to improve the electron transport using different morphologies of titania such as one-dimensional nanostructures. In this research, the effect of peroskite structures on electron transport and scattering effect is investigated. Using sol-gel process, the compositions will be produced which have special morphology and appropriate band gap in spite of pure titania.... 

Enhancement of photocatalytic characteristics of semiconductors have been always a challenge for the researchers. Doping semiconductors for adjusting their energy gap and changing their morphology in order to increase their effective surface area and reaction sites are examples of their endeavor to overcome the challenge. In this research, nanostructured Aluminum Titanate powder was synthesized with Sol-Gel process and by altering synthesis parameters, the best synthesis condition to get the best possible band gap was discovered. Moreover, we examined the photocatalytic properties of the recently developed material “tialite”, which were not studied before and also evaluated the effect... 

Human brain is one the most efficient biological neural network that is capable of performing most complicated tasks in very short time. Visual system as a part of the brain can process the visual records from the environment and perform very useful processes on them. The information provided from visual system processes play important roles in human intelligence. In this thesis we introduce and investigate one of the well-known theories about visual system called gestalt theories. These theories tried to define how a biological neural network can perform such results. Gestalt theorists developed rules of perception to explain their ideas including Law of Pragnanz, Similarity, Closure,... 

Drop deformation and breakup are of great importance in a wide variety of applications, from fuel combustion to agriculture, pharmaceutical processes, and coating. In this experimental study, droplet secondary bag breakup has been investigated. By conducting experiments on different fluids with a wide range of properties and in different conditions, the effects of different parameters on secondary bag breakup have been addressed. For this purpose, the breakup of these fluids, water, ethanol, glycerin, and SDS solution were scrutinized and by comparing their trajectory and morphological parameters, results are driven. Experimental conditions were such that the Weber number are from 11 to 17... 

Gamma prime (γ') precipitates are the most important phase in nickel-base superalloys that rise to a combination of desirable properties in superalloys. The morphology of these particles has important contribution to the resulting properties of superalloys. Heat treatment process of superalloys is one of the most important factors affecting the characteristics of the γ' phase. In this study, nickel-base superalloys IN738LC and GTD-111 were used to study the evolution of the microstructure and morphology of the γ' precipitates under a variety of heat treatment cycles including partial dissolution, aging for different times and under a range of cooling rates. Morphology and characteristics of... 

One of the most important factors affecting the performance of the vehicle's brake disc is its stiffening coefficient. To improve this feature, many researches have been carried out by leading automotive companies, whose scientific aspects have not yet been widely disseminated. Brake discs are often made of cast iron and are more likely to produce gray iron with type A graphite. However, according to available resources, factors such as graphite morphology, their length-to-thickness ratios, cast iron and heat treatment on the piece affect this important feature. One of the most important factors that make changes in the above mentioned cases is the chemical composition and freezing rate. In... 

Silver nanopowder is of great importance for various medical and industrial applications. Due to the significance of the solubility of silver nanoparticles in these applications as well as the high impact of the nanophysical morphology of the powder on their solubility, we prepared nanoparticles with plate morphology by the chemical reduction of silver nitrate in a soluble phase. Then we measure its solubility in a phosphate buffer salt, which greatly resembles the human blood chemically. The size and shape of the resulting nanosilver powder and also the use of non-toxic materials in their synthesis are important factors in the production of nanosilver powder.We confirmed the successful...