Sharif Digital Repository

In this study, standard composite laminate specimens with micro and nano sized particle additives are made to study the effect of the additives on the fracture toughness of the specimens in standard tests. The composite laminates are made from epoxy resin and unidirectional glass fibers. The mode I and mode II fracture toughness of the specimens are measured under various loadings in standard tests. The fracture surface is then, fractogaphed by microscopic instruments. In conclusion, the fracture behavior of laminated composites, toughened by micro and nano particles is discussed. The results show that using rubber particles will improve fracture toughness of neat epoxy resin and laminated... 

In the first stage of this research, different amounts of glycidoxypropyltrimethoxysilane (GPS) were grafted as a coupling agent on the surface of nanosilica particles (NS). Surface characterization was done by Particle Size Analyzer and Thermal Gravimetric Analyzer (TGA) and that way, samples were distinguished from each other. More comparisons were taken by Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). Then the different amounts of modified NS were added into the matrix of an epoxy resin and the physical and mechanical properties of samples were tested with Abrasion Resistance test, Tensile Strength test, Thermal Mechanical Analysis (TMA),... 

Growing production of cement and concrete in developing countries like Iran in addition to high amounts of energy consumption and pollutants formation through production of cement has motivated researchers to partially replace it with suitable additive materials. In this study, the chemo-physical and microstructural properties of rice husk ash as an agricultural waste and its performance in cement mixtures as a pozzolan is experimantally investigated. Parameters influencing the pozzolanic properties of this material that are studied include the effect of acid leaching before pyro-processing, heating rate, retention time, and grinding time. Additionally, this material is compared with other... 

Due to the diameter and size of nanoparticles, they have been applied in various fields to make materials with better properties. In this thesis, the purpose has been to investigate the influence of nano alumina and nano alumina incorporating nano silica particles on mechanical properties of cement mortars. Different portions of nano alumina that include 1, 3, and 5% have been used. Nano silica with 1 and 2% has been used. At first, nano particles were dispersed by sonication with water, and then the cement mortars with various percent of nano additives with the same workability have been made. After different curing periods (7, 28 days), the specimens have been tested for bending and... 

Regarding to the effect of nanoparticles on mass transfer and hydrodynamics characteristics, limited number of studiesavailableinthe literature.In this work, mass transfer performanceand hydrodynamic characteristics nanofluidshavebeeninvestigated in the liquid−liquid extraction process. The chemical system of toluene-acetic acid-water was used, and two Extraction columnswith diameter of 10cm and height of 55cm and 6 cm were designed. The drops were organic nanofluids containing silica nano-particles and carbon nano-tubes.Synthesized silica nanoparticles by sol-gel methods, were modified with Triethoxyoctylsilane and Polydimethylsiloxane as well as Carbon nano-tubes were modified with dodecyl... 

Today, energy crises and the environmental pollution have become serious problems for the human being. To address these problems, extensive efforts have been made to replace fossil fuels with other clean energy resources such as fuel cells. In the meantime, polymer electrolyte fuel cells are very important as they are now commonly used in the field of transportation, and their importance become even more obvious as we consider the fact that the by-products from electricity production by such cells are simply water and heat. This research studies the efficiency of the polymer called “polysulfone” as an electrolyte fuel cell, which has the above named mechanical thermal and chemical... 

Recent studies in nanotechnology field have shown this technology could solve many challenges and needs in oil and gas industry. As yet, many applications of nanoparticles in enhanced oil recovery have been reported. One of the most important applications is wettability alteration due to presence of nanoparticles in injecting fluid, which has recently been studied by several research groups. These studies indicate that, presence of nanoparticles in injecting water would improve oil recovery. However, there is no adequate information about the mechanisms affecting fluid flow in reservoir rock and its mathematical modeling.The aim of this project is to evaluate the effect of injection of... 

Loess as a kind of collapsible soils is a well-known Aeolian deposit, which is characterized by some specific Engineering properties including high initial void ratio, relatively low initial density and water content and high percentage of fine-grained particles. Collapsible soils such as loess, sustain large stress under dry condition. However, they experience a high and sudden decrease in their volume by reaching to their critical moisture content. As a result, their natural condition is not suitable for construction works if the possibility of the exposure of the soil to excessive water is present. This research presents the utilization of an innovative method for stabilization and... 

The aim of this study was to evaluate the effects of applying low replacement ratios (0.75% and 1.50% of the binder weight) of nano-SiO2 particles with different specific surface areas (200 and 380 m2/g) on the properties of high-performance concrete (HPC). Mechanical (compressive and splitting tensile strengths), electrical resistivity, non-destructive (ultrasonic pulse velocity), and microstructural (mercury intrusion porosimetry, X-ray diffraction, and scanning electron microscopy) tests were conducted to investigate the macroscopic and microscopic effects of nano-SiO2 particles on HPC characteristics. The results indicated that the performance of nano-SiO2 particles significantly... 

The main object of this thesis is synthesizing poly(vinyl acetate)/ colloidal silica nanocomposites via emulsion and in-situ polymerization methods. At the first, nanocomposites were produced in the presence of poly(vinyl alcohol) as the protective colloid, ammonium persulphate as the initiator and sodium bicarbonate as the buffer in an aqueous solution. Then, structural, thermal, rheological, mechanical and surface properties of produced nanocomposites with various colloidal silica content (0.5 %, 1 %, 1.5 %) were evaluated by DLS, FTIR, SEM-EDS, DSC, TGA, dynamic and steady rheological tests, tensile and shear mechanical tests, AFM and static water contact angle. The particle size of... 

Nowadays, concrete is considered as one of the most important and useful engineering construction materials. Different concrete with diverse characteristics are used in various designs every day. One of the main considered parameters in concrete usage is its compressive strength. So far, many additives are used to increase the compressive strength of concrete most important of which are Nano-Silica and Micro-Silica. In addition, some of concrete characteristics such as water-to-cement ratio have significant effects on the concrete strength. Many experiments and investigations are conducted so far to study the effects of each of mentioned factors separately on the concrete strength. However... 

Electrospinning process has been widely used to produce nanofibers from polymer blends. Poly(vinyl alcohol) (PVA) and chitosan (CS) have numerous biomedical applications such as wound healing and tissue engineering. Nanofibers of CS/PVA have been prepared by many works, however, a complete physicochemical and mechanical characterization as well as cell behavior has not been reported. In this study, Non-toxic, biodegradable, and biocompatible chitosan/poly(vinyl alcohol)(PVA)/nano silica nanofibers were prepared by electrospinning. The properties of the nanofibers at various blend ratios were investigated by differential scanning calorimetry (DSC), Fourier transform infrared (FTIR)... 

Collapsible soils, a kind of which is Loess, are mainly in silt size in the nature, and are present in many part of Iran, such as Golestan, Semnan, Khorasan, Yazd, Kerman, Hormozgan, Sistan and Balouchestan provinces. when the water content of the soil is lower than a critical water content, the soil shows high shear strength. However, increase in water content due to leakage of water, wastewater or heavy rains in the presence of enough induced pressure, when a certain coupled hydro-mechanical condition is reached, will result in a sudden collapse or excessive deformation. Hence, improvement or stabilization of this kind of soil is of high importance. In this research, specimens are prepared... 

In recent years, the use of polyurethane foams has been of interest for many researchers and craftsmen. Polyurethane foams, due to their excellent properties, can be used in important applications such as advanced military industries, insulation and those requiring strength and maneuverability. The aim of this research project is to produce polyurethane / sodium silicate or nano-silica nanocomposites. Prior to the fabrication and synthesis process of polyurethane containing sodium or nano-silica, deposited silica nanoparticles were synthesized using high-rubbed sodium silicate and sulfuric acid, followed by various tests including XRD, FE-SEM and BET to verify It was done. Sodium silicate... 

As the reservoir matures, especially in fractured reservoirs, oil production is usually accompanied by the production of some unwanted water. Water production causes environmental problems and imposes high costs on the production system, including the cost of separating water and oil, corrosion of facility, and sometimes, leading to abandoning well. One way to solve this problem is to use gels as a blocking agent. Today, preformed particle gels are used as an alternative to in situ gels, which can solve some issues of in-situ gels, such as uncertainty in gelling time and penetration depth.This research comprises three main parts. In the first part, four samples of preformed particle gels... 

Hybrid nanoparticle comprising of nanosilica (NS) and nanodiamond (ND), as denoted by ND@NS, was synthesized by a two-step chemistry route and then incorporated into styrene-butadiene rubber (SBR) at low concentrations up to 5 phr by a two-roll mill. Physical hybrids of NS and ND, i.e., ND&NS, with a weight ratio similar to chemical hybrid (80:20 for NS:ND), were also incorporated into SBR. Field emission scanning electron microscopy observations revealed very fine dispersion of nanoparticles in the case of physical hybrids (ND&NS); whereas, agglomerations and aggregation of nanoparticles were evidenced for ND@NS. Tensile and dynamic mechanical analyses exhibited a higher reinforcing effect...