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    Separation of Olefins from Paraffins Using Nanocomposite Polymeric Membranes

    , M.Sc. Thesis Sharif University of Technology Karami, Meysam (Author) ; Soltanieh, Mohammad (Supervisor) ; Goodarznia, Iraj (Supervisor)
    Abstract
    In this study, fabrication of polymeric nanocomposite membranes for separation of olefins from paraffins was investigated. Silver nanoparticles were prepared by Polyol chemical reduction method. At first, dense ethylcellulose and ethylcellulose-silver nanoparticles membranes were fabricated by solvent-evaporation method. Then Asymmetric EC and EC-silver nanoparticle nanocomposite membranes were fabricated by dry/wet phase inversion method as a means to improve flux rates and olefin selectivity in olefin/paraffin separations. The membranes properties and The Effects of incorporating nanoparticles in polymer matrix in low concentration on gas permeability and membranes morphology were... 

    Analysis of Fuel Gas Distribution in Ethane Cracking Furnace

    , M.Sc. Thesis Sharif University of Technology Behrouzi, Zargham (Author) ; Moosavi, Ali (Supervisor)
    Abstract
    Ethylene process is one of the most complex systems in petrochemical industries.The first section of the ethylene plant is the cracking furnace.The radiant section of predicted olefin furnaces is symmetrical with respect to a plane through the center line of the furnace and at an angle of 90° with the side walls. There are a total of 24 vertical radiant coils located centrally in the firebox wherein, bottom andside wall burners supply the heat necessary. Each four coils known as a ZONE so, as a result there are six zones, called zone A through F. Failures(rapture, creep, material degradation) rate on the coils decreases from zone A to zone F (A, B, C, D, E and F) respectively.From... 

    Life Cycle Environmental Assessment of Polyethylene Process/Multiobjective Optimization

    , M.Sc. Thesis Sharif University of Technology Shayannezhad، Amir Shayannezhad (Author) ; Farhadi, Fatollah (Supervisor) ; Vafa, Ehsan (Supervisor)
    Abstract
    The environmental impacts of chemical processes significantly affect the design of these processes and emphasize issues such as changing the reaction path, separation methods, thermal integration, and finally multi-objective optimization. Therefore, it is necessary to investigate the influence of environmental indicators in the design of chemical processes. The background system in this assessment includes two process units, olefin and polyolefin. Environmental impacts assessment has been carried out using the ReCiPe endpoint method (an efficient method for life cycle impact assessment that will be described in chapter 2) and these impacts have been determined in the form of damage to human...