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    Nanomagnetic Polyamidoamine Dendrimer as A Novel Sorbent for Solid Phase Microextraction of Chlorophenols from Aquatic Media

    , M.Sc. Thesis Sharif University of Technology Manouchehri, Mahshid (Author) ; Bagheri, Habib (Supervisor)
    Abstract
    In this study, ananomagnetic polyamidoamine (PAMAM) dendrimer was synthesized as a novel SPME fiber coating and implemented to the determination of traces of chlorophenols in water samples. The synthesized magnetic PAMAM shows to have many polar groups with an enhanced internal porosity which is promising to be used as an efficient extracting medium. With this purpose, a thin stainless steel wire was coated by the network of dendritic PAMAM polymer through electrolysis and chemical reactions. The synthesized fiber is physical stable since it was chemically bonded to the substrate. Extraction efficiency of new coating was investigated by headspace SPME of chlorophenols from aqueous samples... 

    Application of Metallic Nanoparticles in Treatment of Wastewater Containing Dyestuffs

    , M.Sc. Thesis Sharif University of Technology Hosseini, Reza (Author) ; Shaygan, Jalalaldin (Supervisor)
    Abstract
    Textile industrial wastewaters are one of the most important sources of environmental contaminants. In the recent years, use of advanced oxidation processes, by producing highly active and reactive components such as hydroxyl radicals has been proposed. The aim of this research is oxidative degradation of methylene blue dye using Cu-nanoparticles immobilized on a polymer support with H2O2 as an oxidant reagent.In general, oxidative degradation of methylene blue with hydrogen proxide in the presence of immobilized CuO nanoparticles on a polymer support as the catalyst was studied. We used polyamidoamine (PAMAM) dendrimer as the polymer support for nanoparticles. fourth generation of PAMAM was...