Sharif Digital Repository

This investigative study intends to identify and characterize bitumen from seven Iranian bitumen production plants according to the Superpave Performance Grading (PG) system, conventional classic tests, and chemical separation tests. The study then compares the identified performance grades with the thirteen performance-grade binders required for specific climatic zones in Iran. It is observed that the variety of available binders is not adequate to fully cover the required PGs. Blending was initially considered as a suitable and economic method for production of the missing performance grades. However due to similar rheological properties of bitumen samples, resulting in nearly identical... 

Nowadays, foaming agents have wide applications in drilling, cementing, fracturing and oil displacement in the petroleum industry. Typical applications are to make light fluids for drilling operations in naturally fractured reservoirs where lost circulation is a problem. Compared with conventional and aerated drilling fluids, foamy mud is a compressible and relatively homogeneous mixture. A great flexibility for pressure control is thus possible. In this study, a new foaming agent of Yas-Khorramshahr Company is introduced to drilling fluids. Stability of this agent at different concentration and in presence of Salt and crude oil is tested. Also common drilling muds are lightened and... 

Drilling of low pressure layers is one of the major problems in petroleum industry, in which requires a lightweight drilling fluid for drilling of these layers. Use of lightweight Colloidal Gas Aphron (CGA) leads to loss reduction of drilling fluid, decreases formation damage and finally, well stimulation costs will be reduced. Use of nanoparticles can improve the aphron drilling fluid performance. But there is little information in the literature about the role of natural surfactant in the presence of nanoparticles on the CGA based fluid properties. Especially, micro bubbles behavior in the presence of nanoparticles in pore scale is less considered. This study consists of two parts, in the... 

Since the early 90s, nanotechnology has contributed to several developments in a wide range of Science and industry such as medicine, Physics, Chemistry, Aerospace, electronics and Biology. In recent years, nanotechnology has also made development in the oil and gas industry. The drilling fluid is already one of the most important parts in drilling operation.The physical properties of a mud, rheological properties and minimize fluid invasion into the formation with perfect mudcake are important to assist in optimizing results. Nano-materials as one of the achievements of recent years are effective in achieving these purposes. To obtain the above properties, a variety of polymers as... 

One of the major problems in directional and extended reach wells is poor hole cleaning. Directional and horizontal drilling is more complex than vertical wells. Ineffective particles transport leads to several undesirable issues during drilling. This thesis analyzed all parameters which have directly affected directional hole cleaning. The thesis is based on an experimental set-up designed in Sharif University. In the experimental work, two types of drilling fluid, Newtonian and Non-Newtonian with numerous rheological parameters, three different flow rate, three various nozzle sizes and three individual RPMs in three distinct inclinations 30°, 60° and 90° were used to simulate. Also, to... 

For designing a unit operation, knowledge about physical properties is essential. This is attained either by direct measurement, which needs spending time and cost or, using proposed correlations. This project is subjected to theoretical analysis of viscosity as the most important rheological property of dilute suspensions of microgels, or in other words colloidal suspensions of porous spheres. They are applied in drug delivery, enhanced oil recovery, synthesis of catalyst and adsorption of heavy metal ions from aqueous systems for water purification purposes. In dilute suspensions particles are faraway from each other and there is no interaction between them therefore, it is better to... 

With a surge in consumption of modified binders in recent years, different methods have been used to evaluate the properties of modified binders with relative success. None of these methods are able to fulfill all the requirements for evaluation and intrerpretation of the physical, chemical and rheologocal properties of modified binders. Since rheological master curves can present a mechanical interpretation of the binders in a wide range of times and temperatures, in conjunction with other evaluation metheods, they are considered a promising means of evaluating the suitability of modified bindrers. The available master curve models do not possess the sufficient diversity for this purpose.... 

Acidizing efficiency depends on various factors such as formation properties, reservoir and stimulation fluid types and injection scenario. Among these factors, heterogeneity of reservoir’s formation (layered reservoirs and permeability variation versus depth) strongly affect acidizing performance. Accordingly, applying a reliable technique that distribute stimulation fluid uniformly is essential. The aim of carbonate matrix acidizing is to improve fluid flow specially in low permeability zones. Stimulation fluid cannot enter into the low permeability layer due to existence of high permeability layers which are in contact with low permeability ones. So, the stimulation fluid should be... 

In recent years, utilizing the colloidal gas aphron (CGA) drilling fluids is getting more and more commonplace due to their little formation damage and filtration loss. This study tries to investigate the effect of presence of nanoparticles and their type (hydrophobicity) on stability and performance of water and oil based CGA drilling fluids. This is done through analyzing stability, filtration, rheology, and pore blockage tests. Water and oil based CGA drilling fluids consisted of stabilizer, surfactant, and nanoparticles are generated and through examining of the effects of polymer, surfactant, and nanoparticle concentrations, the optimum formulation is obtained. High pressure-high... 

Numerous applications of Lab on a Chips (LOCs) in chemical/biochemical analyses as well as the emergence of advanced methods for their manufacture attracts many researchers’ attention to these micro instruments. Low sample volume consumption and their high controllability are accounted as the main advantage of LOC systems. Micromixers are among the main components of any LOC in which mixing and/or reaction among two components occur. Micromixers have many potential applications in biological and medical sciences, and so they are repeatedly charged by biofluids. Due to sensibility of biofluids, to avoid disintegration, applying electroosmotic flow instead of pressure-induced flow has priority... 

The rheology of oil well cement (OWC) slurries is generally more complicated than that of conventional cement paste. In order to contend with bottom hole conditions, a number of additives are usually used in the OWC slurries. The objective of this research is to develop a fundamental understanding of the important mechanisms that affect the properties of OWC slurry such as rheological properties, free water, compressive strength and thickening time incorporating various chemical and mineral admixtures. The partial replacement of OWC using different nanoparticle weight percent has been proved to be a promising method. The mechanisms underlying the effects of chemical admixtures on the... 

The aim of this project is designing Suitable drilling fluid applicable in deep drilling. This aim will be reached by adding a temperature-resistant polymers or nanomaterials in water-based drilling fluid, Rheological properties of drilling fluid checked. Stability of rheological properties of drilling fluids not constant in HT state. Chain of cause and effect will happen, While the temperature increases, the viscosity and yield point of the fluids decreases. cuttings transportation and removal efficiency will be decreased due to reduction in yield point and viscosity. Evaluation of The effect of these cases conclude that these effects will also impact on filtration loss. The reason is that... 

Polyethylene, due to its low production and maintenance costs, light weight and excellent chemical resistance, is the most widely used material for production of water and gas transfer pipes. Pipe grade polyethylene (PE100) with bimodal molecular weight distribution has excellent mechanical properties, especially long-term creep performance. In order to prevent UV degradation, carbon black is added as masterbatch to PE100 to produce black compounds, which acts as most effective industrial UV stabilizer of polyethylene. Five PE100 black compounds and one white PE100 as reference sample were produced using a twin-screw extruder. Rheological, melt flow DSC, TGA, FE-SEM and tensile tests were... 

Magnetorheological fluids are suspensions of magnetic solid particles suspended in a nonmagnetic matrix fluid. By imposing an external magnetic field, particles are arranged in microstructures aligned with the external field and hence, dramatically affect the fluid flow. Since the strength of the magnetic field determines the resistance of these microstructures against flow, the rheology of the suspension is a function of the intensity of the external magnetic field. The goal of the present work is to study the role of non-gap-spanning magnetic clusters on the rheology of a magnetorheological fluid. Here, first a robust tool for direct numerical simulation of magnetic suspensions is... 

The success of matrix acid production operations and its proper efficiency is one of the main challenges for oil and gas companies. The heterogeneity of the reservoir formation (especially the permeability difference) in the area around the well due to the presence of different reservoir layers results in the non-uniform distribution of acid among them and adds acidizing challenges. In order to improve production conditions, stimulation fluid transfer to the low permeability layer, which is the main target of acidizing. In this study, a new generation of chemical diverter, called Viscoelastic Surfactant, has been used. These materials have two components of elastic and viscous behavior, and... 

In this study, the effect of molybdenum disulfide nanosheets on the rheological behavior of suspensions was investigated using a polyethylene glycol matrix and glass grain fillers with a particle distribution of 60 to 103 microns. Crude molybdenum disulfide was obtained by single-layer and multilayered molybdenum disulfide nanosheets with thicknesses between 50 and 100 nm using acid, oxidation and heat shock methods. This claim was verified by various tests such as FT-IR, FESEM,EDS, TEM, DLS, XRD and so on. Subsequently, using 10 to 40% volumetric glass beads were prepared from the sample matrix. Stirring and ultrasonic, rheological behavior of these suspensions were investigated using... 

Wax precipitation is one of the major problems in the transfer of crude oil from field production to refineries. This wax with asphaltene compounds and some water and solids, closes the oil pipeline. One of the ways to reduce the amount of wax in pipes is to use additives (flow improvers) to crude oil and improve its rheological behavior. In this research, Five Iranian crude oils were characterized with SARA test and then the effects of various additives including ethylene vinyl acetate (EVA) in concentrations of 500 and 1500 ppm, alkyl phenol ormaldehyde resins (NPFR) with 1500 ppm and styrene-(ethylene-cobutylene)- styrene (SEBS) with 1500 ppm on viscosity, wax appearance temperature... 

Casing collapse is a long-standing problem in Kopal oil field, located at a distance of 60 km of east of Ahwaz, Iran. In this field, so far casing collapse has encountered in 18 well-bore out of the 56 drilled-well-bore (~32%) due to creep loading caused by salt flow, which resulted in tremendous economic loss. Among all the different set of factors leading to such a problem, the effects of the local stress distribution on the wellbore wall and casing (resulted from the in-situ stresses, and stress perturbation due to drilling), pore pressure, the casing quality and material, and the applied-cement type are important. In order to investigate these factors and their effects, they should be... 

Wax precipitation may occur in production or transportation of crude oil form field which is a serious problem in petroleum industry. Flow assurance issues concerning wax precipitation make it necessary to develop a precise thermodynamic model to predict the wax appearance temperature and amount of precipitation at different conditions. In this work a new procedure has been proposed to characterize crude oil based on the SARA test considering the wax and asphaltene as single pseudo components. Two scenarios have been investigated for the survey of the crude oil characterization, with and without asphaltene pseudo component. Also, in this work, the Perturbed ...