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Experimental and Theoretical Investigation on the Frictional Performance of Friction Materials of Brake System
, M.Sc. Thesis Sharif University of Technology ; Shojaei, Akbar (Supervisor)
Abstract
Various composite friction materials containing 40 vol.% organic binder (phenolic resin plus styrene-butadiene-rubber (SBR)) with varying phenolic-resin/SBR ratio were prepared. The content of phenolic resin in each composite was indicated by the resin value (RV) index ranging between 0-100%. The composites with RVs greater than 50% form resin-based friction materials in which the primary binder is the phenolic resin. For RVs less than 50%, the composites become the rubber-based materials where the primary binder is the SBR. The analysis of mechanical properties exhibited that the conformability of the composites increases upon incorporation of SBR. The frictional analysis revealed that type...
Investigation of Fracture Toughness of Epoxy Resins by Addition of CNT and Rubber Microparticles
, M.Sc. Thesis Sharif University of Technology ; Bagheri, Reza (Supervisor)
Abstract
Epoxy resins are relatively brittle and have low resistance to crack propagation. It is common to add rubber particles to improve crack resistance in epoxies, although these particles may deteriorate the strength of the matrix. Different nanomaterials are used to overcome the inherent brittleness of epoxies and to keep the mechanical properties. Among them, carbon nanotubes has been attracted many attentions. Fractue behavior and mechanical properties of two kind of novel nanocomposites, i.e, epoxy/carbon nanotube and epoxy/rubber/carbon nanotube are investigated in current study. Electron microscopy investigations were done to assure the CNTs distribution and fracture mechanisms as well....
Effect of Microstructure Factors on Fracture Behavior of Clay-Rubber-Epoxy Hybrid Nanocomposites
, Ph.D. Dissertation Sharif University of Technology ; Bagheri, Reza (Supervisor)
Abstract
The aim of this study is to investigate the effects of nanoclay and rubber particles morphologies on fracture behavior of a lightly cross-linked epoxy. In addition, the role of cavitation resistance of rubber particles on fracture behavior of the nanoclay-rubber-epoxy hybrids was studied. Two types of organoclay and three kinds of rubber modifiers (in micron and nano-size) were incorporated into the epoxy. The results obtained indicate that addition of either intercalated or exfoliated clay increases fracture toughness of the epoxy resin, although the increases in toughness are modest (a 50% increase). The microscopy examinations and the micromechanical models revealed that the...
, M.Sc. Thesis Sharif University of Technology ; Naghdabadi, Reza (Supervisor) ; Sohrabpour, Saeed (Supervisor)
Abstract
Increasing the application of elastomeric structures in industries has caused an interest in the researchers for nonlinear elasticity and viscoelasticity of solids. Such materials which show large deformation and rate dependent behavior are treated by visco-hyperelastic constitutive equations. Based on visco-hyperelastic constitutive equations, total stress is divided into two parts: quasi-static and viscous stress. The method for determining the visco-hyperelastic constitutive equation is strictly dependent on the chosen rheological model. In this project, a new visco-hyperelasic constitutive equation in the integral form was introduced based on the Zener model. Also, based on the internal...
An Investigation on the Role of Silica Hybrid Nanoparticles on the Properties of Styrene Butadiene Rubber (SBR)
, M.Sc. Thesis Sharif University of Technology ; Shojaei, Akbar (Supervisor) ; Salkhi Khasraghi, Samaneh (Co-Supervisor)
Abstract
Hybrid nanoparticle comprising of nanosilica (NS) and nanodiamond (ND), as denoted by ND@NS, was synthesized by a two-step chemistry route and then incorporated into styrene-butadiene rubber (SBR) at low concentrations up to 5 phr by a two-roll mill. Physical hybrids of NS and ND, i.e., ND&NS, with a weight ratio similar to chemical hybrid (80:20 for NS:ND), were also incorporated into SBR. Field emission scanning electron microscopy observations revealed very fine dispersion of nanoparticles in the case of physical hybrids (ND&NS); whereas, agglomerations and aggregation of nanoparticles were evidenced for ND@NS. Tensile and dynamic mechanical analyses exhibited a higher reinforcing effect...