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YSZ Coating on Ferritic Stainless Steel Interconnect through Sol-Gel Method and Studying its Reaction with Glass Sealant in SOFC
, M.Sc. Thesis Sharif University of Technology ; Faghihi Sani, Mohammad Ali (Supervisor) ; Nemati, Ali (Supervisor)
Abstract
Solid oxide fuel cells are used to convert solid-state energy to direct electrical current by electrochemistry mixing a gas fuel and an oxidant in an oxide electrolyte. One of the most interesting aspects of this field for the researchers is the reaction between the metal interconnect and the glass sealant. In the current research, deposition of the YSZ coating onto the metal interconnect in order to impede the reaction with glass sealant and prohibition of its oxidation in oxidizing/reducing environment in high temperature, was mainly investigated. Effect of applying YSZ Thin layer in the intersection of Crofer steel and glass sealant on strength and chemical durability of these two...
Investigation of Mechanical Properties of Glass-Ceramic Sealant for Solid Oxide Fuel/Electrolysis Cells
, Ph.D. Dissertation Sharif University of Technology ; Kokabi, Amir Hossein (Supervisor) ; Faghihi-Sani, Mohammad Ali (Supervisor) ; Abdoli, Hamid (Co-Supervisor)
Abstract
The structural integrity of the sealing material is critical for the reliability of solid oxide fuel/electrolysis stacks. In this study, the mechanical properties of a rapid crystallizing glass of BaO-CaO-SiO2 system were evaluated. The crystallization as a determining factor in the mechanical behavior of the glass-ceramic sealant was investigated via high-temperature X-Ray diffraction spectrometer. Three- and four-point bending tests were carried out to measure the flexural strength (σ) of sealant material bars and head-to-head joined specimens at room- and high-temperatures. In addition, the elastic modulus (E) was measured by impulse excitation test up to 900 ºC. Also, the indentation...