Sharif Digital Repository

In the present work, Barium Titanate nanoparticles were synthesized by a facile hydrothermal method at 180oC for 4 hours and their sintering behavior was studied. The characterization tests illustrated that the obtained powder was BaTiO3 single phase with excess Ti content from stoichiometric composition. The average particle size of about 50 nm and a narrow particle size distribution was noticed. SEM investigations showed that the samples sintered at temperatures less than 1250oC had plate-like grains. This behavior resulted from twin plates existed in the grains and facetted grain boundaries. At the temperatures more than 1250oC, the grains became polygonal due to the formation of trace... 

Propylene, as one of the most important raw materials of petrochemical industries, is produced through different methods. One of the major methods is propane dehydrogenation. This reaction is endothermic and many by-products will be produced in high temperature. Therefore catalytic dehydrogenation is preferred. Reduction in catalyst's activity and too many side reactions are the most important problems. Coke formation is the most effective reason of deactivation. Main source of coke is propylene. Experiments show that very small amount of water presence within reaction can reduce rate of coke formation. Water content growth does not always increase activity. If water be more than optimum... 

In this project alumina-zirconia-ceria nanocomposite with 80% mol alumina (0.2Ce0.1Zr0.9O2-0.8Al2O3) was produced by solution combustion synthesis method. In the mentioned method, optimal fuel with composition of 75% urea, 25% ammonium acetate, and stoichiometric amount of glycine (0.75U-0.25AA-1G) was used. Moreover, ammonium nitrate as aid combustion was added to optimal fuel. In order to calcinations, nanopowder obtained from combustion synthesis was heated to 500°C for 1 hour and kept at this temperature for 2 hours. To complete heat treatment, the nanopowder was heated to 1150°C for 2 hours and 10 min and kept at this temperature for 2 hours. Then the specimens were pressed at pressure... 

Ultra-high temperature ceramics (UHTCs) are a class of materials that have melting points above 3000°C and include borides, carbides and nitrides of some transition metals such as ZrB2, ZrC, HfB2, HfC, HfN, TaC. These compounds are of particular interest because of the unique property combination such as high electrical and thermal conductivity, chemical inertness against molten metals or non basic slags, and good thermal shock resistance. Sintering of these compounds is very difficult due to their high melting point and utilization of sintering aids or new consolidation routes is necessary to achieve high density sintered bodies. In this research, phase evolution and kinetics of diffusion... 

Thin films of materials, in order to have magnificent structure and properties, can use in complicated technology such as; electronic, optic and magnetic systems. Printed interconnects can be made by the deposition of suspensions of metal nanoparticles (e.g., silver and gold) followed by thermal sintering. The nanoparticle sintering process involves atomic diffusion resulting in shrinkage. As a result, the interconnects are prone to residual stresses generated during the thermal sintering process. The residual stress can cause cracks and delamination in the thin films and can cause permanent geometrical changes in the underlying substrates which may affect the functionality of the... 

Nowadays, metal matrix composites due to their magnificent properties, has met diverse applications in automobile, aerospace and military industries. Decreasing the reinforcement size from micro-meter to nano-meter, properties of these structures will be improved significantly. Better properties will lead to better applications for them in the future. Thus, the main objective of the current project was investigation on the mechanical properties of metal matrix nanocomposites produced with shock wave sintering. In order to gain this aim, first the sintering of nanoparticles was modeled. A new model was proposed to consider the neighboring particles effects. Using the model, sintering of many... 

Molybdenum disilicide is an intermetallic compound in Mo-Si binary system that is appropriate to use at high temperatures. Because of its special properties such as high melting point, oxidation resistance, good electrical resistivity and thermal conductivity, this material can be used in high temperatures applications such as gas turbines, heat shield and tiles. High melting point of MoSi2 limits the fabrication of this compound by conventional methods. Nowadays modern techniques such as mechanical alloying are being used for synthesis of Molybdenum disilicide. The objective of this study is to investigate the effects of sintering time and temperature on the mechanical and electrical... 

Solid oxide fuel cell (SOFC) is one of the promising candidates for clean energy production. Due to the high operating temperature of SOFC, a protective coating is commonly applied on the surface of interconnects to prevent oxidation. In this study, electrophoretic deposition was employed to prepare a manganese-cobalt spinel coating on the surface of ferritic stainless steel (AISISAE430) substrates. MnCo2O4 powder with an average particle size of 60 nm was utilized and the sintering behavior of the coatings at different temperatures was studied. Non-isothermal and isothermal sintering behavior of the powder compacts were examined by employing a sensitive dilatometer. Master sintering curve... 

Joining of yttria-stabilized zirconia (YSZ) to stainless steel (SS) is considered for various applications such as solid oxide fuel cells, thermal barrier coatings, and medical implants. In the present work, a series of brazing pastes utilizing silver and nickel nanoparticles (~80 nm) mixed with carboxymethyl cellulose as the organic phase were developed to join 5YSZ to 420 SS. The effects of processing parameters such as time and temperature of brazing and the composition of the paste on the microstructure of the joint and its mechanical strength were studied. The mechanism of interface formation was elaborated by scanning electron microscopy (SEM) and electron probe micro analyzer (EPMA).... 

Uranium dioxide (UO2) has been widely used as nuclear fuel in water cooled reactors since 1960s. UO¬2 is a refractory oxide with a melting point in excess of 28000C and therefore, requires high sintering temperature around 17000C in a hydrogen atmosphere for several hours. In the conventional method, the sintering is incorporated with indirect heating of green pellets in a refractory-type electrical resistance furnace. This furnace, however, uses a large number of expensive heating elements and refractory materials to achieve and maintain the high temperature for a long time. Moreover, it consumes much electrical energy and time. Since nanocrystalline materials contain a large fraction of... 

The aim of this study is to investigate the effect of Copper oxide on the microstructure, properties, and grain growth kinetic in Tin oxide- Based varistors. Copper oxide was mixed in Tin oxide with different concentration, including 0, 0.1, 0.25, 0.5, and 1 mol% and the samples were sintered at 1250, 1300, and 1350 oC. Then, phase and microstructural characterization was investigated and consequently, electrical properties were evaluated. According to results, Copper Oxide with forming the liquid phase through the sintering process, accelerated grain growth. It was found that, by increasing concentration of CuO, mean grain size was increased from 2.6 µm in 1250 oC and 5 hours to 17.1 µm... 

One of the newest methods of rapid prototyping is SLS . In this day, SLS is more common in compare others methods, because it uses little time and man does not nearly interfere in the producing stages of part which is made by SLS method. Also, sophisticated parts, which cannot be built by other methods, can be produced by SLS method. One of the disadvantages of SLS method is low dimensions accuracy of parts produced in this way. This problem has two major reasons: Shrinkage and Warpage. These two phenomena are created because of ununiformed temperature distribution. Others features which have effect on dimensions accuracy are residual stress, porosity and removing space of between powder... 

Nowadays filtration process is increasingly used in various areas such as water purification, food industries, filtering the air dust and other separation applications. In this work, the HDPE microporous filters have been fabricated at different temperature, pressure and time conditions via sintering process and then were characterized by different techniques. It can be expected that microstructure and mechanical properties of the samples could be controlled by changing the fabrication parameters of the process and also by changing the properties of the resin such as powder shape, particle size and rheological properties. In the first step, by using DSC, MFI, rheology test and optical... 

Recently, macroporous polymers have gained wide acceptance for applications such as filters, membranes, biodegradable scaffolds, retention media, sound mufflers and etc. In this research, by keeping in mind the importance of the pore structure in the functionality of the porous part, three dimensional images of the pore structure during sintering was obtained using an optimized manual serial sectioning technique. Then, using the Euler number as a property of the topology of the pore surface, evolution of the three dimensional pore structure was scrutinized for two types of powders, powder A with a mean particle size of 200 micron and melt flow index of 0.2 (g/10 min) and powder B with a mean...