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Charge Transfer Complexes of Substituted Bis (thiophen-2-Ylmethylene)Benzene-1,4-Diamine Schiff Bases with Iodine and TCNE
, M.Sc. Thesis Sharif University of Technology ; Mohammadi Boghaei, Davar (Supervisor)
Abstract
The charge transfer interaction of two Schiff-bases 2,5-dichloro -bis(thiophen-2-ylmethylene)benzene-1,4-diamine and 2,5-dimethyl-bis(thiophen-2- ylmethylene) benzene-1,4-diamine as donors with I2 and TCNE ethylene as acceptors have been studied spectrophotometrically.
The formation constants and extinction coefficients of charge transfer complexes have been determined by graphical as well as iterative methods. From measurements at different temperatures the thermodynamic functions of the charge transfer complex formation have been studied. The temperature dependence of the K can be used for the determination of the thermodynamic reaction quantities (ΔG, ΔS, ΔH) for linear regression...
The formation constants and extinction coefficients of charge transfer complexes have been determined by graphical as well as iterative methods. From measurements at different temperatures the thermodynamic functions of the charge transfer complex formation have been studied. The temperature dependence of the K can be used for the determination of the thermodynamic reaction quantities (ΔG, ΔS, ΔH) for linear regression...
Spectrophotometric Determination of Azinphos methyl Based on Aggregation of Colloidal Gold Nanoparticle
, M.Sc. Thesis Sharif University of Technology ; Hormozi-Nezhad, Mohammad Reza (Supervisor) ; Torkian, Ayoub (Supervisor)
Abstract
There is an increasing need for food by the growth of population. To meet this need, the use of pesticides is increasing. Among pesticides organophosphorous compounds are the ones with the most usage. Liquid and gas chromatography are commonly used to measure orghanpphosphrous pesticides. These methods are relatively time consuming and require a tedious sample preparation.
Herein we report a sensitive colorimetric method for detection and measurement of Azinphos methyl, based on unmodified gold nanoparticles aggregation and changes in plasmonic band. Azinphos methyl, containing different soft acidic groups acts as a bridge, causes aggregation, and changes in plasmonic band. Changes in...
Herein we report a sensitive colorimetric method for detection and measurement of Azinphos methyl, based on unmodified gold nanoparticles aggregation and changes in plasmonic band. Azinphos methyl, containing different soft acidic groups acts as a bridge, causes aggregation, and changes in plasmonic band. Changes in...