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    Phase Field Simulation of Microstructure Ternary Eutectic Solidification

    , M.Sc. Thesis Sharif University of Technology Dalvand, Mehdi (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    Physical and mechanical properties of cast alloys is partly a function of the morphology and volume fraction of phases from freezing. The microstructure of the eutectic solidification is function of physical properties (especially mobility and surface tension) and the volume fraction of phases involved in the evolution. The prediction of solidification microstructures will be very helpful for improving the mechanical properties of casting alloys and designing of new families of alloys. The theoretical study of the formation of eutectic microstructures is very difficult and almost impossible in general cases and empirical studies are expensive. The purpose of this study is to predict the... 

    Degradation of Polypropylene Random Copolymer in Aqueous Solution of Chlorine Dioxide: Effect of Crystalline Structure and Morphology

    , M.Sc. Thesis Sharif University of Technology Rohollah Shamizadeh (Author) ; Pircheraghi, Gholamreza (Supervisor)
    Abstract
    Polypropylene is a semi-crystalline thermoplastic used in various industries and the second most used polymer globally. Polypropylene is sensitive to degradation by o agents due to having tertiary carbon in its chain. Chlorine-based disinfectants, used to disinfect drinking water, cause the degradation of hot water pipes made of polypropylene random copolymer. The stability of polypropylene against oxidizing chemical agents depends on the type of crystalline phase and polymer morphology. This research investigated the effect of alpha, beta, and gamma crystalline phases and spherulite size on random polypropylene copolymer's chemical stability in chlorine dioxide. Three samples were prepared,...