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Synthesis of Novel Bimetallic Nanocomposite of Copper and Silver Based on Metal Organic Frameworks and Investigation of Its Application as Catalyst in Sulfonation Reaction
, M.Sc. Thesis Sharif University of Technology ; Matloubi Moghaddam, Firouz (Supervisor)
Abstract
In recent years, bimetallic metal-organic frameworks have attracted the great attention of researchers due to their dual properties and synergistic effects. In this research and inspired by green chemistry, the synthesis of a magnetic nanocomposite of the defective green metal-organic framework was implemented, which carries metallic silver nanoparticles (Ag NPs@Cu-MOF). Then, the sulfonated compounds were synthesized with the prepared nanocomposite because of the importance and widespread medicinal use of sulfur-containing compounds especially sulfonated compounds, and the difficulty of their preparation methods. It is noteworthy to mention that the sulfonation reaction was done by...