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triphenylphosphine
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Molybdenum(VI) Complexes and Palladium Nanoparticles in Ionic Liquid-Liquid Biphasic and Supported Ionic Liquid phase (SILP) Catalysis, and Green Catalytic Processes using Polymeric Ionic Liquids (PILs
, Ph.D. Dissertation Sharif University of Technology ; Bagherzadeh, Mojtaba (Supervisor)
Abstract
In this thesis, ionic liquids and polymeric ionic liquids were investigated as solvent and support for immobilization of molybdenum and palladium catalysts. Three newly synthesized room temperature ionic liquids containing molybdate anion, [DMIm][MoO2(NCS)4], [RPy][MoO2(NCS)4] (R = butyl or decyl), and previously reported [BMIm][MoO2(NCS)4] were used as catalysts for the reduction of sulfoxides. For facilitating the recyclability of the catalysts, the ionic liquid solvents, [RMIm][PF6] and [RPy][PF6] (RMIm=1-n-alkyl-3-methylimidazolium, RPy= 1-n-alkylpyridinium), were applied to immobilize molybdenum catalysts. These catalysts showed high catalytic activity for sulfoxide reduction in this...
Enhanced Performance of Modified Pd/AL2O3 Catalysts by Triphenyl phosphine Ligand in Acetylene Selective Hydrogenation
, M.Sc. Thesis Sharif University of Technology ; Khorasheh, Farhad (Supervisor) ; Takht Ravanchi, Maryam (Supervisor)
Abstract
Ethylene is considered as one of the key materials in the petrochemical industry and has a particular importance. Polymerized ethylene produces polyethylene, which is widely used in plastics and pipe-manufacturing industries. Ethylene is mainly produced by the processes of catalytic cracking or thermal cracking of heavier hydrocarbon compounds. In these processes, acetylene is produced as a by-product, which deactivates the Ziegler-Nata catalysts in the polymerization unit of ethylene. Therefore, there should be some considerations to reduce acetylene to its minimum value -around zero. For this purpose, the fixed bed catalytic reactor is used to hydrogenate acetylene to ethylene. Various...