Loading...
- Type of Document: M.Sc. Thesis
- Language: English
- Document No: 41964 (57)
- University: Sharif University of Technology, International Campus, Kish Island
- Department: Science and Engineering
- Advisor(s): Ghorbani, Mohammad
- Abstract:
- Main aim of this work was to obtain the harder zinc coating and increasing the anti corrosive properties by mean of adding SiO2 particles by electrophoretic method.
The coating was applied on the substrate surface by mean of electro co-deposition technique in three different electrolytes ethanol, methanol and water. The morphology of the coating in each electrolyte studied by scanning electron microscope (SEM).For the Zn/SiO2 coatings achieved in ethanol solvent the polarization and EIS tests was took place and found that for the Zn/SiO2 coating contain less than 10% SiO2 the corrosion rate decreased but for the coatings contains more than 10% SiO2 the paradox occurred because of the anti wetting properties of SiO2. Coating characteristics such as roughness, hardness and friction coefficient were carried out by atomic force microscope (AFM). Salt spray test was used to monitor the coating resistance beside environmental corrosion and found that the co deposition of SiO2 with Zn at less than 10% represented the better environmental corrosion resistance - Keywords:
- Electrophoretic ; Composite Coating ; Anticorrosive Coating ; Wear Resistance ; Zinc-Silicon Oxide Composite Coating
- محتواي پايان نامه
- view
- Table of contents
- Introduction
- Zinc Coatings
- Electrophoretic Deposition (E.P.D.)
- Electrophoretic Deposition(E.P.D.) Mechanism
- Traditional approaches for EPD
- Flocculation by particle accumulation
- Particle charge neutralization mechanism
- Electrochemical particle coagulation mechanism
- Electrical double layer (EDL) distortion and thinning mechanism
- Literature review
- The characterization of electrodeposited Zn/SiO2 composites before and after corrosion test
- High corrosion resistance for Zn, Co, Cr with Al2O3 and SiO2
- Zinc release from bioactive sol–gel derived SiO2-CaO-ZnO glasses and ceramics
- Lubrication behavior of Zn-SiO2 nano-spheres
- Antibacterial properties of nano-SiO2 supported silver/zinc–silver materials
- Adsorption of Ca2+ and Zn2+ ions at monodispersed SiO2
- Experimental method
- Electrolyte preparation
- Electroplating process
- Effect of bath agitation
- Surface characterization of coatings
- Electrolyte stability
- Coating adhesion to substrate
- Coating thickness determination
- Micro hardness of the coatings
- Electrochemical experiments
- Environmental corrosion tests
- Results and Discussion
- Steel substrate composition
- Solubility in electrolytes:
- Stability of electrolyte
- Thickness of the Zn-SiO2 coatings
- Effect of agitation on the Zn/SiO2 coating uniformity
- Morphology of the Zn-SiO2 coatings
- Electrochemical study of the Zn-SiO2 coatings
- Persian abstract.pdf