Synthesis of Dithiocarbamate by Markonikov Addition Reaction

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Dadras, Arefeh | 2013

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Type of Document: M.Sc. Thesis
Language: Farsi
Document No: 44766 (03)
University: Sharif University of Technology
Department: Chemistry
Advisor(s): Mahmoodi Hashemi, Mohammad; Ziyaei Halimehjani, Azim
Abstract:
Development of strategically important processes which are environmentally benign with simple methodology and work-up by low toxic material is currently reciving considerable attention.In recent years, dithiocarbamates (DTCs) and their synthesis with a green procedure have received many attention because of their undeniable applications.These synthetic compounds play important roles either in academia and industry. Here a simple, efficient and regiospecific method for synthesis of dithiocarbamates is described by one-pot three-component reaction of an amine, CS2 and alkyl vinyl ether via Markovnikov addition reaction in poly ethylene glycol (PEG) under a mild and green procedure with excellent yields and complete regiospecificity
Keywords:
Green Chemistry ; Special Segment ; Dithiocarbamate ; N-Vinyl Pyrrolidone ; Markovnikov Addition

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