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A simple, economical, and highly efficient synthesis of β-hydroxynitriles from epoxide under solvent free conditions [electronic resource]

Mirmashhouri, B ; Sharif Univercity of Technology

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  1. Type of Document: Article
  2. DOI: 10.1016/j.molcata.2005.11.042
  3. Abstract:
  4. A simple, rapid, and highly regioselective green protocols for the synthesis of β-hydroxylnitriles by the direct reaction of epoxides with trimethylsilyl cyanide in the presence of catalytic amount of lithium perchlorate under solvent free conditions in high to quantitative yield is reported
  5. Keywords:
  6. β-Hydroxylnitriles ; Regioselective ; Trimethylsilyl cyanide ; Lithium perchlorate
  7. Source: Journal of Molecular Catalysis A: Chemical ; 2006, Volume 247, Issues 1–2, Pages 159–161
  8. URL: http://www.sciencedirect.com/science/article/pii/S138111690500806X