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Investigation of the reaction of dithiocarbamic acid salts with aromatic aldehydes

Ziyaei Halimehjani, A ; Sharif University of Technology | 2012

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  1. Type of Document: Article
  2. DOI: 10.1021/ol301598u
  3. Publisher: ACS , 2012
  4. Abstract:
  5. A reaction of dithiocarbamic acid salts with carbonyl compounds was investigated for the first time in the presence of BF 3•OEt 2. The reaction is temperature dependent and gives gem-bis(dithiocarbamates) at 35-45 °C as a molecule with high equivalents of dithiocarbamate groups. At lower temperatures (15-20 °C), the 2-iminium-1,3-dithietane is obtained as the only product. The structure of a 2-iminium-1,3-dithietane was accomplished by X-ray crystallographic analysis
  6. Keywords:
  7. Dithiocarbamic acid salts
  8. Source: Organic Letters ; Volume 14, Issue 15 , July , 2012 , Pages 3838-3841 ; 15237060 (ISSN)
  9. URL: http://pubs.acs.org/doi/abs/10.1021/ol301598u