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A new vanadium Schiff base complex as catalyst for oxidation of alcohols

Bagherzadeh, M ; Sharif University of Technology | 2010

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  1. Type of Document: Article
  2. DOI: 10.1080/00958972.2010.520316
  3. Publisher: 2010
  4. Abstract:
  5. The monoanionic bidentate Schiff base, N-(phenolyl)-benzaldimine (HL), has been employed to synthesize a new vanadium(IV) complex of general composition [VO(L)2] (where L = O, N donor of Schiff base). The ligand and complex have been fully characterized by elemental analyses, molar conductance data, FT-IR, 1H- and 13C-NMR, and UV-Vis spectroscopies. Oxidation of alcohols to their corresponding aldehydes and ketones was conducted by this complex catalyst using Oxone as oxidant under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent under air at room temperature
  6. Keywords:
  7. Bidentate Schiff base ; Catalytic oxidation ; Oxone ; Vanadium complex
  8. Source: Journal of Coordination Chemistry ; Volume 63, Issue 21 , May , 2010 , Pages 3849-3858 ; 00958972 (ISSN)
  9. URL: http://www.tandfonline.com/doi/abs/10.1080/00958972.2010.520316