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ONO pincer type binuclear Pd(II) complex: Synthesis, crystal structure and catalytic utilization of the resulting organopalladium complex in catalytic copper-free Sonogashira coupling reaction

Bagherzadeh, M ; Sharif University of Technology | 2016

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  1. Type of Document: Article
  2. DOI: 10.1016/j.ica.2016.07.032
  3. Publisher: Elsevier S.A , 2016
  4. Abstract:
  5. New binuclear palladium (II) complex featuring ONO pincer type hydrazone ligand was synthesized and characterized by spectroscopic and single-crystal XRD analysis. This complex showed excellent catalytic activity towards the copper-free Sonogashira cross coupling reaction. The main advantages over previous methodologies include low catalyst loading, less problematic reaction media (H2O–DMSO) and reusability in homogenous systems for optimal performance
  6. Keywords:
  7. Crystal structure ; Organopalladium ; Pincer complex ; Sonogashira coupling reaction
  8. Source: Inorganica Chimica Acta ; Volume 451 , 2016 , Pages 227-232 ; 00201693 (ISSN)
  9. URL: http://www.sciencedirect.com/science/article/pii/S0020169316304108