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Gold@Silver@Gold Core double-shell nanoparticles: synthesis and aggregation-enhanced two-photon photoluminescence evaluation

Daneshvar e Asl, S ; Sharif University of Technology | 2020

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  1. Type of Document: Article
  2. DOI: 10.1007/s11468-019-01041-5
  3. Publisher: Springer , 2020
  4. Abstract:
  5. A facile, straightforward, and low-cost method is proposed to synthesize gold@silver@gold core double-shell nanoparticles. The technique is a seed-mediated growth protocol that contains four steps of (1) gold seed synthesis, (2) gold seed growth, (3) silver layer coating through silver salt reduction, and (4) gold layer deposition via gold precursor reduction. The prepared nanoparticles had a narrow size distribution and the average particle size of 28 ± 1 nm. Cysteine was introduced to the nanoparticles solution as a coupling agent to assemble nanoparticles. Aggregation-induced two-photon photoluminescence enhancement of three types assembled nanoparticles, i.e., gold@silver@gold, gold@silver, and gold nanoparticles, was studied. It was observed that the assembled core double-shell nanoparticles presented huge enhancement in two-photon photoluminescence signal in comparison with two other nanoparticles. Moreover, the gold@silver@gold nanoparticle is a stable and biocompatible plasmonic nanosystem. This paper provides a novel candidate for two-photon photoluminescence excitation sensing and imaging for biomedical applications. © 2019, Springer Science+Business Media, LLC, part of Springer Nature
  6. Keywords:
  7. Core double-shell ; Gold@silver@gold ; Localized surface plasmon resonance ; Plasmon coupling ; Two-photon photoluminescence
  8. Source: Plasmonics ; Volume 15, Issue 2 , 2020 , Pages 409-416
  9. URL: https://link.springer.com/article/10.1007/s11468-019-01041-5