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Efficient oxidation of olefins and sulfides catalyzed by manganese(III)-tridentate Schiff base complex using UHP as oxidant

Bagherzadeh, M ; Sharif University of Technology | 2008

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  1. Type of Document: Article
  2. DOI: 10.1016/j.catcom.2008.01.020
  3. Publisher: 2008
  4. Abstract:
  5. Catalytic studies were performed to develop a simple oxidation system for olefins and sulfides using manganese(III)-tridentate Schiff base complex, Mn(N-OPh-sal)(acac)(EtOH) (N-HOPh-Hsal = N-hydroxyphenyl-salicyldienamine, Hacac = acetylacetone), and urea-hydrogen peroxide (UHP) as terminal oxidant. Conversions up to 90% for olefins at 0 °C and 96% for sulfides at room temperature as well as sulfoxide selectivity up to 73% were achieved in short reaction times. Also this study confirms the accelerating effect of strong π-donor axial ligands such as imidazole (ImH) on the oxidation reactions. © 2008 Elsevier B.V. All rights reserved
  6. Keywords:
  7. Catalyst activity ; Hydrogen peroxide ; Manganese compounds ; Oxidation ; Urea ; Manganese(III)-tridentate Schiff base complex ; Urea-hydrogen peroxide (UHP) ; Olefins
  8. Source: Catalysis Communications ; Volume 9, Issue 7 , 2008 , Pages 1600-1606 ; 15667367 (ISSN)
  9. URL: https://www.sciencedirect.com/science/article/abs/pii/S1566736708000095