Loading...

Crystal structure of Gua4[Cu2(Cit)2] {Gua = Guanidinium, Cit = Citrate = 2-hydroxo-1,2,3-tricarboxylatopropane}

Boghaei, D. M ; Sharif University of Technology | 2007

142 Viewed
  1. Type of Document: Article
  2. DOI: 10.2116/analscix.23.x123
  3. Publisher: Japan Society for Analytical Chemistry , 2007
  4. Abstract:
  5. The title complex has been synthesized and structurally characterized by single-crystal X-ray diffraction. This complex has a dinuclear structure where two copper(II) ions are bridged by two bent alkoxo groups. The citrate acts as a tetradentate ligand coordinating via three carboxylates and an alkoxo groups in which one of three carboxylates is coordinated weakly. The coordination geometry around the Cu(II) is strongly distorted square pyramidal. The distance between the two copper atoms is 2.8386(3)Å. 2007 © The Japan Society for Analytical Chemistry
  6. Keywords:
  7. Brightness ; Connectors ; CCD Camera
  8. Source: Analytical Sciences: X-ray Structure Analysis Online ; Volume 23, Issue 7 , 2007 , Pages x123-x124 ; 13482238 (ISSN)
  9. URL: https://www.jstage.jst.go.jp/article/analscix/23/0/23_0_x123/_article