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Tris[(2-oxazolinyl)phenolato]manganese(III) as catalyst for mild and efficient oxidation of sulfides to sulfones with Oxone®

Bagherzadeh, M ; Sharif University of Technology | 2003

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  1. Type of Document: Article
  2. DOI: 10.3184/030823403322840305
  3. Publisher: Scientific Reviews Ltd , 2003
  4. Abstract:
  5. Tris[(2-oxazolinyl)phenolato]manganese(III), Mn(phox)3, catalysed oxidation of dialkyl, diaryl, dibenzyl, and alkyl aryl sulfides to the corresponding sulfones is carried out by Oxone® in biphasic conditions (CH2Cl2/H2O), in the presence of tetra n-butylammonium bromide as phase transfer agent at room temperature in very short reaction times (5 min.) with quantitative yields
  6. Keywords:
  7. Catalytic oxidation ; Mn-oxazoline complex ; Oxone® ; Sulfide
  8. Source: Journal of Chemical Research - Part S ; Issue 12 , 2003 , Pages 765-767 ; 03082342 (ISSN)
  9. URL: https://journals.sagepub.com/doi/abs/10.3184/030823403322840305