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An efficient and convenient approach for synthesizing iodohydrin and iodoether from aromatic alkenes using Hg(BF4)2.SiO2 and I2

Hosseinzadeh, N ; Sharif University of Technology | 2022

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  1. Type of Document: Article
  2. DOI: 10.1080/10406638.2021.1878247
  3. Publisher: Taylor and Francis Ltd , 2022
  4. Abstract:
  5. A new and simple method for synthesizing iodohydrins and iodoethers from aromatic alkenes is described. Iodohydrins and iodoether derivatives were prepared in excellent yield using Mercury(II) tetrafluoroborate (Hg(BF4)2.SiO2)/I2 in aqueous THF or alcohols (methanol, iso-propanol and tert-butanol). The reactions take place at room temperature, short reaction times, and high regioselectivity, following Markovnikov fashion. © 2021 Taylor & Francis Group, LLC
  6. Keywords:
  7. Aromatic alkene ; Iodihydrin ; Iodoalkoxylation ; Iodoether ; Iodohydroxylation ; Mercury tetrafluoroborate
  8. Source: Polycyclic Aromatic Compounds ; Volume 42, Issue 7 , 2022 , Pages 3975-3983 ; 10406638 (ISSN)
  9. URL: https://www.sciencedirect.com/org/science/article/abs/pii/S1040663822001828