Structural and Computational Studies of Chloro and Nitro Cobaloxime Complexes Containing Tris (p-methoxyphenyl) Phosphine Ligand

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Ashtari Larki, Mohammad | 2024

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Type of Document: M.Sc. Thesis
Language: Farsi
Document No: 57466 (03)
University: Sharif University of Technology
Department: Chemistry
Advisor(s): Kia, Reza
Abstract:
In this study, two new cobaloxime complexes with molecular formula [Co(DMGH)2{P(p-PhOCH3)3}(X)] in which X= Cl, NO2 were synthesized and their structure studied. These complexes were identified by FT-IR and1H-NMR 31P{1H}-NMR methods as well as their solid state structure studied by X-ray crystallography. The non-covalent interaction of two complexes including non-classical hydrogen interactions, C─H...π interactions, and dispersion interactions were confirmed and compared theoretically and experimentally by analyzing the data extracted from X-ray single crystal diffraction
Keywords:
Cobaloxime Complexe ; X-ray Radiation ; Intramolecular Interactions ; Intermolecular Interactions ; Phosphine Ligand

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