Sharif Digital Repository

In this work, cycling-induced aging occurring in 18650-type LiFePO4/graphite full cells at different C-rates is studied extensively. The mechanism of performance degradation is investigated using a combination of electrochemical and microstructural analyses. Half-cell studies are carried out after dismantling the full cells, using fresh and cycled LiFePO4 cathode and graphite anode to independently study them. The results show that the capacity of LiFePO4 electrodes is significantly recovered. The rate of capacity fading in the discharge state considered as irreversible capacity in the graphite is higher than LiFePO4 half cells, indicating a greater degradation in the performance of this... 

In this work, cycling-induced aging occurring in 18650-type LiFePO4/graphite full cells at different C-rates is studied extensively. The mechanism of performance degradation is investigated using a combination of electrochemical and microstructural analyses. Half-cell studies are carried out after dismantling the full cells, using fresh and cycled LiFePO4 cathode and graphite anode to independently study them. The results show that the capacity of LiFePO4 electrodes is significantly recovered. The rate of capacity fading in the discharge state considered as irreversible capacity in the graphite is higher than LiFePO4 half cells, indicating a greater degradation in the performance of this... 

Nowadays, the LiNi0.8Co0.1Mn0.1O2 (NCM811) cathode material has attracted great research interest due to its high energy density and less usage of costly raw materials. However, the high nickel content of NCM811 brings about an extremely unstable interface between the electrode and electrolyte and therefore inferior cyclic stability. Herein, we have proposed a straightforward method to deliver 1, 2, and 4 wt % of TiO2 nanoparticles (NPs) on the surface of the NCM811 cathode material and to improve its properties at room and high temperatures. Based on scanning electron microscopy and transmission electron microscopy observations, the coating thickness varies from 10 to 35 nm and the 2 wt %... 

LiNi0.8Co0.1Mn0.1O2 (NCM811) has been considered as a promising cathode for Li-ion batteries (LIBs) due to its high electrochemical capacity and low cost; however, poor cycling stability is one of the main restricting factors in industrial applications of the NCM811 cathode material. Notably, the capacity fading and low structural stability of NCM811 are intensified at elevated temperatures. ZrO2- and composite rGO-ZrO2-coated NCM811 were fabricated by a facile wet chemical method and evaluated at 25 and 55 °C to overcome these impediments. The ZrO2 coating provides superior cycling and thermal stability and perfectly protects the cathode active material from deleterious side reactions, and... 

Background: Rotaviruses are the cause of acute gastroenteritis and severe diarrheal diseases in children worldwide. Children under the age of five are more susceptible to rotavirus infections. Due to such as the lack of effective drugs and supportive therapy only, the development of new antiviral agents against rotaviruses is required. Multi-drug-resistant Acinetobacter baumannii is also one of the most challenging Gram-negative bacteria to control and treat due to its antibiotic resistance, particularly in intensive care units. Objective: This study aimed to investigate the activity of zinc oxide nanoparticles against human rota-virus and multi-drug resistant Acinetobacter baumannii.... 

Cupric oxide (CuO) is a semiconductor of choice for photocathode in photoelectrochemical (PEC) applications due to its great sunlight absorption capability. However, photocorrosion is the main drawback of CuO. Herein, CuO/graphitic carbon nitride (g-C3N4) with a unique microstructure, enhanced PEC performance, and considerable photostability is synthesized under microwave irradiation. A facile, one-pot method is utilized to directly deposit the nanocomposite onto fluorine-doped tin oxide from a solution containing copper precursor and urea. Possible mechanism of CuO/g-C3N4 formation through this novel method is investigated. It is elucidated that controlled amounts of urea critically... 

Noise analysis techniques including Feynman-α (variance-to-mean) and Rossi-α (correlation) have been simulated by MCNP computer code to calculate the prompt neutron decay constant (α0), effective delayed neutron fraction (βeff) and neutron generation time (Λ) in a subcritical condition for the first operating core configuration of Tehran Research Reactor (TRR). The reactor core is considered to be in zero power (reactor power is less than 1 W) in the entire simulation process. The effect of some key parameters such as detector efficiency, detector position and its dead time on the results of simulation has been discussed as well. The results of proposed method in the current study are... 

The first step to locate Partial Discharge in power transformers is to find a model that can clearly explain the behavior of the winding in high-frequency. The detailed model is one of the models used for the study of PD. One of the fundamental problems of the described model is to find its parameters. And the accuracy in calculating these parameters has significant impact on reducing the simulation error and PD locating. The current paper seeks to calculate the parameters of the detailed model 20kv distribution transformer winding by using the finite element method (FEM). Comparing the results of this model with pulse waveforms obtained from the PD to the winding in the laboratory... 

In this research, cellulose acetate butyrate (CAB) electrospun nanofiber membrane (ENM) was prepared by electrospinning method in order to separate the contaminants of an industrial wastewater. The influence of various electrospinning parameters on morphology and average fiber diameter of the membranes were investigated by scanning electron microscopy and image analysis. The permeability of the membranes was evaluated by measuring pure water flux. In order to investigate the performance of the prepared membranes for tomato wastewater treatment, the rejection of the pollution indices and flux were determined. The results demonstrated the potential of using CAB nanofiber membrane for... 

Two-dimensional semiconductor materials can be combined with conventional silicon-based technology and sort out part of the future challenges in semiconductor technologies due to their novel electrical and optical properties. Here, we exploit the optoelectronics property of the silicon/SnS2 heterojunction and present a new class of backward diodes using a straightforward fabrication method. The results indicate an efficient device with fast photoresponse time (5-10 μs), high photoresponsivity (3740 AW-1), and high quantum efficiency (490%). We discuss device behavior by considering the band-to-band tunneling model and band bending characteristics of the heterostructure. This device structure... 

In the present paper, the light output distribution due to poly-energetic neutron/gamma (neutron or gamma) source was calculated using the developed MCNPX-ESUT-PE (MCNPX-Energy engineering of Sharif University of Technology-Poly Energetic version) computational code. The simulation of light output distribution includes the modeling of the particle transport, the calculation of scintillation photons induced by charged particles, simulation of the scintillation photon transport and considering the light resolution obtained from the experiment. The developed computational code is able to simulate the light output distribution due to any neutron/gamma source. In the experimental step of the... 

This paper presents a new approach for fuel burn up evaluation and radioactive inventory calculation used in Tehran Research Reactor. The approach is essentially based upon the utilization of a program written by C# which integrates the cell and core calculation codes, i.e., WIMSD-4 and CITVAP, respectively. Calculation of fuel burn up and radioactive inventories has been done for 26 core configuration of Tehran Research Reactor with HEU fuel element. The present inventory and fuel enrichment of each fuel element have been calculated  

In the present study, simulation of a direct geometry spectrometer for neutron Time-of-Flight (nTOF) is performed based on the Monte Carlo method to calculate the energy spectrum of the neutron source. To this end, the ability to simulate the simultaneous emission (such as the simultaneous emission of the neutron and gamma particles from the241Am-9Be neutron source) and the neutron Pulse Height Distribution (nPHD) were added to the MCNPX computer code. In addition, a post-processing software was developed to analyze the massive amounts of the data in the output of the PTRAC card. The application of the nTOF as a direct method to calculate the neutron spectrum eliminates the error induced by... 

Rolling-element bearing (REB) failure is one of the general damages in rotating machinery. In this manner, the correct prediction of remaining useful life (RUL) of REB is a crucial challenge to move forward the unwavering quality of the machines. One of the main difficulties in implementing data-driven methods for RUL prediction is to choose proper features that represent real damage progression. In this article, by using the outcomes of frequency analysis through the Envelope method, the initiated/existed defects on the ball bearings are identified. Also, new features based on developing faults of ball bearings is recommended to estimate RUL. Early-stage faults in ball bearings usually... 

Over the past decade, the power industry in many countries around the world has been undergoing massive changes to introduce competition. In power systems under transmission open access, an optimal schedule of generation of units to satisfy the demand at the minimum production and transmission costs with consideration of system operation constraints is an important issue. In this paper, a method for centralized economic dispatch in deregulated power systems is presented. The considered constraints are minimum and maximum power generation of units, capacity of transmission lines and ramp rate limits. Genetic algorithm is used to solve a nonlinear objective function. Simulations are performed... 

A new cationic flocculant was synthesized by graft copolymerization of acrylamide (AM) and 3-(methacryloylamino)propyl]trimethylammonium chloride (MAPTAC) onto salep using free radical polymerization initiated by ammonium persulfate (APS) to produce cationic salep [S-g-P(AM-co-MAPTAC)]. Reaction parameters (monomers/salep ratio, concentration of reactants, MAPTAC/AM ratio, and APS) were optimized using a full factorial experimental design to obtain the highest settling rate for cement suspensions. The best performing product was characterized by gel permeation chromatography (GPC), FTIR, 1H NMR spectroscopy, and thermogravimetric analysis (TGA). The resulted cationic flocculant may be... 

Due to high surface to volume ratio and tunable band gap, two dimensional (2D) layered materials such as MoS2, is good candidate for gas sensing applications. This research mainly focuses on variation of Density of States (DOS) of MoS2 monolayes caused by ethanol adsorption. The nanosheets are synthesized by liquid exfoliation, and then using Scanning Tunneling Spectroscopy (STS) and Density Functional Theory (DFT), local electronic characteristic such as DOS and band gap in non-vacuum condition are analyzed. The results show that ethanol adsorption enhances DOS and deform orbitals near the valence and conduction bands that increase transport of carriers on the sheet. © 2018 IOP Publishing... 

To locate accurately the occurrence of a partial discharge in a power transformer winding, a wide frequency band model of the winding is required. In this paper a wide frequency band Multi Conductor Transmission Line model (MTL) is employed to simulate the propagation of PD signal in transformer windings. The MTL model is briefly reviewed and the related equations of the model are reformulated to easily simulate occurrence of a PD signal along the winding. Software is developed in Matlab to calculate the windings resonance frequencies and the magnitudes of over-voltages occurring between different disks along the winding. Then propagation of PD signal in a power transformer (900MVA, 525kV),... 

A semi-analytical solution for rotating axisymmetric disks made of functionally graded materials was previously proposed by Hosseini Kordkheili and Naghdabadi [1]. In the present work the solution is employed to study thermoelastic creep behavior of the functionally graded rotating disks with variable thickness in to the time domain. The rate type governing differential equations for the considered structure are derived and analytically solved in terms of rate of strain as a reduced to a set of linear algebraic equations. The advantage of this method is to avoid simplifications and restrictions which are normally associated with other creep solution techniques in the literature. The thermal...