Sharif Digital Repository

The produced crude oil from the petroleum reservoirs usually has a value of brine (water and salt) this matter can be caused the corrosion of refinery equipment. The large part of this brine creates a stable emulsion with oil, that it couldn't be separated easily. For separation and demulsification of this emulsion, some chemical, mechanical, thermal and electrical methods can be executed. In chemical method, demulsifier materials can be added to water-in-oil emulsion. Different parameters such as properties of oil, type and concentration of demulsifiers, volume factor of water and etc., can affect the efficiency of water-in-oil emulsion separation. In this study, emulsification mechanism,... 

In past two decades, the direction of oil and gas exploration has moved towards deep water drilling. The pressure and temperature in these zones are ideal for gas hydrate formation that can cause serious and sometimes uncontrollable issues during drilling operations. Gas hydrate formation while drilling can cause problems such as occurrence of kick and blowout, plug chock and kill line, and change in rheology of drilling mud. On the other hand, nowadays, nanotechnology has created an evolution in engineering sciences and because of the wide range of this science, drilling industry is affected like other industries. In the meantime, because of high yield, high stability and various methods of... 

Nowadays, due to the advancement of robotic technologies and development of industrial robots, the robot manipulators are widely used for automation of various manufacturing processes, such as finishing processes. In these applications, the contact has to be made between robot end-effector and environment. Therefore, control of interaction force in the constrained manipulators is an important demand. On the other hand, due to use of gear box and belts for energy transmission in robot joints, robot manipulators have flexible joints. The vibration, generated due to the interaction force and robot joint flexibility, can deteriorate surface roughness in automated finishing processes. In order to... 

Hole-transporter-free perovskite solar cells with structure of TiO2/ZrO2/C triple-layer scaffold filled with perovskite are great alternative to the conventional ones due to the possibility of making full printable low-cost and stable devices. In the present work, the impacts of the structures of the quadruple layer scaffold in the form of TiO2/ZrO2/NiO/C and triple layer scaffold in the form of TiO2/ZrO2/C on their photovoltaic performance are studied. In addition, the effects of thickness and deposition method of each layer were investigated as well as the effect of compounding of the carbon counter electrode. All devices were constructed by a simple printable method. Electrochemical... 

This work describes the effect of hydroxyapatite with different morphology including nanorods and whisker on the properties of hydroxyapatite/polycaprolactone (HA/PCL) composite. Biodegradable polymer/Hydroxyapatite (HA) composites with the morphology of nanorods and whisker of (HA) as bone replacement scaffolds are synthesized by sol-gel and hydrothermal methods, respectively with a Ca/P ratio of 1.67 and 20:80 (HA/PCL).The crystallization behavior and porosity of HA/PCL composite are studied by scanning electron microscope and X-Ray diffraction. The response of bone marrow-derived human mesenchymal stem cells (hMSCs) in terms of cell proliferation and differentiation to the osteoblastic... 

The synthesis and usage of TiO2/ZnO nanocomposite thin film in antibacterial activity against E-coli were experimented through a systematic research. TiO2/ZnO nanocomposite films can demonstrate different properties like gas sensing, self cleaning and treatment of the broad range of aqueous pollutants when it is exposed to light with wavelengths less than 400 nm. This phenomenon happens because of the photocatalytic reactions in the nanocomposite thin film which cause active species production on the surface of the thin film. The nanocomposite synthesis was based on sol-gel process in atmospheric pressure. In this study titanium dioxide is prepared by sol gel method from titanium... 

In the present work preparation of Ni-TiO2 films and their microstructural and mechanical properties were studied. For film preparation, DC current mode of electrochemical deposition method was used in Watts Nickel bath with different concentrations of transparent TiO2 sol up to 30 mL/L. It presents a new generation of nano Ni-TiO2 coating as a composite film for corrosion and erosion resistance applications. The best wear volume of 0.0046 mm3 was achieved for 30 mL/L Ni-TiO2 nanocomposite in comparison to 0.0071 mm3 for pure Ni film. Moreover, the coating hardness increased to ~345 HV50 for Ni-TiO2 nanocomposite. Corrosion rate of the coatings improved down to 1.10E-05 mm/year with addition... 

In the present work, the experiments were carried out for two types of PAM (3330 and 3630) with three distinct concentrations (25, 40 and 55 ppm) and TiO_2-water nanofluid for four concentrations (1.5, 2, 2.5 and 3 vol. %), and the Nusselt number and friction factor for each of them expressed separately. The Reynolds number was in the range from 11000 to 21000. The steady state turbulent convective heat transfer and friction factor of the combination of TiO_2-water nanofluid and polymer 3330 in the coiled tube were investigated. The effects of the Reynolds number for 2 vol. % nanoparticles which consists of 25 ppm PAM (3330) determined at the constant temperature of 24°C. It was observed... 

In this thesis, the hardness of Ni-Cr alloys is optimized by design of experiment (DOE) method (Central Composite Design) in pulse electrodeposition performed in chloride solution. Various parameters were evaluated for finding significant factors in pulse electrodeposition of Ni-Cr alloy. Frequency, duty cycle, current density and temperature were selected as effective factors. 30 experiments were designed by the central composite design method. Analyses of Variance (ANOVA) were performed on the results of these 30 experiments. The best models which can predict the hardness, Cr content, deposition rate, thickness and cathode efficiency of Ni-Cr alloy electrodeposits were found and... 

Corrosion is a main problem for oil and gas industries at refineries and petrochemical process. Presence of sulfur compounds in crude oil and creation a corrosive environment for steel structure, caused failure and unfortunate damages. H2S which present at cracking and sweetening process in sour feed obtain hydrogen atoms that can diffuse into steel structure which involve with its instruments and consequent to hydrogen damage .distribution and storage of these sour environments can be done by high strength low alloy steel (HSLA).Electrochemical hydrogen permeation test were performed to measure the hydrogen permeation current through A106/GR B pipeline steel in the electrolytes simulating... 

MPD technique manages drilling pressure to keep bottom hole Pressure balanced in the well. The objective to this studs, is to approximate the well pressure to formation pressure to prevent entry of fluid into the well. MPD is a new method drilling in which, driller controls the annulus pressure in order prevent drilling problems. the circulating fluids system employed by MPD technology is more akin to that of a pressure vessel. In this thesis, using in laboratory-made machine, reacts with sudden changes in pressure at the bottom hole in the shortest possible time. Basically, this system is a system where well bore pressure management is obtained by adjusting the pressures along the well bore... 

TiO2 and TiO2-Graphene have been synthesized by hydrothermal method. Their physical, chemical and morphological properties have been investigated using XPS, XRD, FTIR, TEM, EDX, UV-Vis and AFM analyses. Moreover, photocatalytic efficiency of prepared materials has been examined using degradation of methylene blue. AFM image exhibited that monolayer GO with thickness of 10 nm was synthesized using modified Hummer’s method. FTIR analysis represented main characteristic peak of oxygen bond on the surface of GO, whereas for TiO2-Graphene most of oxygen functionalities on the surface were removed partially or completely. Photocatalytic degradation of MB proved this extension of light absorption.... 

A new strategy for enhancing the efficiency of TiO2 dye sensitized solar cells (DSSCs) doped with Ni ions with different molar percentages (i.e., 0, 0.5, 1, 5 and 10 mol%) was reported. The samples were prepared by sol-gel route and characterized by means of XRD, DRS, UV-visible, FESEM and photovoltaic measurment techniques. It was found that Ni-doped TiO2 nanoparticles had a mixture of anatase, rutile and brookite crystal structures. Moreover, the band gap energy was decreased with increasing Ni molar ratio, The highest cell efficiency of 5.4% was achieved for 1mol% Ni-doped TiO2, being 42% greater than that of pure TiO2 nanoparticles  

Dye-sensitized solar cell (DSSCS) is the third-generation of solar cells based on semiconductors formed between a photo sensitized anode and counter cathode which make a photo electrochemical system. They haven’t been commercially marketed due to their lower efficiency than the previous generations. In order to achieve the higher efficiency, the electron injection and light absorption must be increased. One way to increase electron injection is doping the semiconductor with an external ion to reduce lattice band gap. In this work, we made powder and Nano-structured film of titanium dioxide doped with various molar ratios of Mg by the sol-gel process. The effect of Mg:Ti molar ratio on... 

With development of nanotechnology in medicine, nanoparticles are used for detection of tumor and cancer biomarkers. Magnetic nanoparticles are widely used for therapeutic and diagnostic objectives, because of their biocompatibility, ease of preparation and strong magnetic properties. Genistein (C15H10O5) is a soy isoflavone which is used for its anti-cancer activities. It is used for inhibition of cell proliferation, cell growth, and tumor invasion. The aim of this study is to assess the impact of nano-conjugation of geinstein as chemotherapeutic agent against cancer. For preparation of typical iron oxide Nanoparticles, Magnetite nanoparticles were synthesized by coprecipitating iron (II)... 

The present study is work on fabrication and characterization of a chitosan/ gelatin/ Mg substituted hydroxyapatite nano composite scaffold for bone tissue engineering. At the first step pure and Mg-substituted hydroxyapatite (HA) (Ca10-xMgx(PO4) 6OH2) nano-hexagonal rods with 14–45 nmdiameter.for this, calcium nitrate, magnesium phosphate hydrate and potassium dihydrogenphosphate were used as precursors for Ca, Mg, and P, respectively. Calculated amounts of magnesium ions (Mg+2) especially from 0 to 8% (molar ratio) were incorporated as substituted into the calcium sol solution. Deionized water was used as a diluting media for HA sol preparation and ammonia was used to adjust the pH= 9....