Sharif Digital Repository

In many uranium mines such as gachin-bandarabbas, use sulfuric acid for leaching operation on ore. This leach liquor, containing uranium, is extracted by organic solvent, such as D2EHPA (dapex process ).althogh this process have being used for many years, there is a vacancy for detailed thermodynamical studying on uranium extraction of uranium from leach liquor. To have a thermodynamical model, we need information on equilibrium concentration of all component that may have effect on uranium extraction in addition we need concentration of solvent , pH, phase ratio and activity coefficient.such a model must have the ability to predict the equilibrium concentration in alloperation condition.... 

In many uranium mines such as gachin-bandarabbas, sulfuric acid is used for leaching operation on ore after crushing operation. This leach liquor, containing uranium, is extracted by specific solvent, including extractant like TOA. However, this operation, named Amex, have been used for many years, there is a vacancy for a detailed thermodynamical studying on uranium extraction from leach liquor.To have a thermodynamical model, we need information about the equilibrium concentration of all the components that may have effect on uranium extraction and also concentration of solvent, pH, phase ratio and activity coefficient alteration. This model must have the ability to predict the equilibrium... 

Centrifuge is a method in which great gravitational-like forces are used. Gravitational forces which cause molecules to move and are relevant to molecular weight; can cause isotope separation. The separation of light isotope from heavy one is done with a centrifugal field which produces a pressure gradient for the gas mixture. Pressure gradient is different for each of the isotopes due to the dependence of pressure gradient to the mass of the materials. But the separation in this way is very limited. The capacity of separation can be brought up by producing an additional axial flow in the rotor. This rotational flow can be produced with internal or external incitement. Rotational flow with... 

This study examines the quality of Corporate Social Responsibility (CSR) disclosure among publicly listed companies in Iran and identifies the factors that influene it. The research sample consists of 546 companies listed on the Tehran Stock Exchange and Iran Fara Bourse, covering the period from February 2023 to January 2024. Data were extracted from audited financial statements and the annual reports of the companies' boards of directors. In the first part of the study, a CSR disclosure quality index comprising 39 factors was developed. The annual reports of the companies were then analyzed to calculate a disclosure score for each company. The average CSR disclosure quality score was... 

How do we enter into empathic relations with inanimate objects (IO)? Do we indirectly infer that they possess mental states, or directly perceive them as mental things? In recent years these questions have been addressed by a number of authors. Some argue in favor of an indirect approach that involves mediatory procedures; others defend a direct approach that postulates no intermediate. In this paper I argue on the side of the latter. I show that Simulation Theory (ST), one of the most elaborated versions of the indirect approach, does not have the capacity to account for our empathy with IO.Investigating ST paves the way for criticizing a special kind of indirect theory, namely Imaginative... 

The main purpose of this dissertation is to give an ethical evaluation of one of the consequences of ICT. Since these technologies are present in every corner of our personal and social life, recognizing their ethical and social consequences are of vital importance. The present dissertation, which is set up in 3 chapters, is allocated for evaluating one of these consequences. In the first chapter which is the first step of our overall argument indeed, one of recent theories in Cognitive Psychology and memory studies, namely Working Memory will be introduced. In the second chapter, introducing another theory in Cognitive Psychology namely Cognitive Load Theory, the role of Working Memory in... 

Smoothed Particle Hydrodynamics (SPH) is a Lagrangian method for simulation of fluid flow. Movable particles are used to interpolate fluid properties instead of fixed Eulerian grids in this method. By essence, the aforesaid particles are movable points which carry the fluid properties such as temperature, enthalpy, density, etc. these variables can also be the stress, strain or the rheological properties of the fluid. Thus, this method needs no grids and the fluid properties are calculated using an interpolation mechanism which classifies this method as meshless. A computational code is designed using SPH for the simulation of multiphase flows. Usage of the Lagrangian formulation has made it... 

Pulsed packed columns are among the most important devices used in liquid-liquid extraction, with wide application in petroleum and petrochemical industries, metal salt extraction, pharmaceutical industries, metallurgy, and other areas. Liquid-membrane technology is an alternative separation technique to the liquid-liquid extraction for the extraction and recovery of metal ions from aqueous solutions. There are three main types of liquid membranes: emulsion liquid membrane (ELM), Bulk Liquid Membrane (BLM), and Supported Liquid Membrane (SLM). Liquid emulsion membrane is one of the pertraction methods with phase dispersion. It is a three-phase dispersion system, consisting: external phase,... 

Oil and gas reservoirs in various parts of the world have declined over time, despite a high percentage of oil. Due to the increasing need for hydrocarbon resources, the need for more cost-efficient harvesting methods and less environmental damage is felt. Injection of saline water is one of the most cost-effective ways of harvesting due to the need for no expensive additives. On the other hand, microscopic glass modeling can be used to better understand and understand the performance of saline water at the microscopic scale. In this study we have been able to visualize the effective factors in infusion of saline water. Improved interfacial tensile and particle migration in kaolin-coated... 

Petroleum based products are the major sources of energy for industry and daily life, With the development of social economy, the demands of the oil have increased dramatically. Petroleum hydrocarbons can cause environmental pollution during various stages of production, transportation, refining and use. Releases of petroleum products(e.g., gasoline, diesel, fuel oil) from aboveground and underground storage tanks or transport pipelines are the major causes of the environment pollution.The major constituents of petroleum hydrocarbons are biodegradable. Many soil microorganisms transform oil hydrocarbons into nontoxic compounds or mineralize them to inorganic compounds. In situ... 

In this work, bioleaching was used to extract valuable uranium from a low grade ore. Bioleaching experiments were carried out in batch cultures using a native strain of Acidithiobacillus ferrooxidans. Experiments were conducted to investigate the effects of rotation speed, initial redox potential, initially added Fe concentration, particle size, pH, temperature, pulp density, and culture type. In the shake flask systems, over 99% of the uranium was bioleached in 48 hours at some conditions. Uninoculated flasks gave only around 25% leaching. At each study, uranium and iron concentrations, solution oxidation– reduction potential and pH were measured. The results showed that 150 rpm, d80=100 ... 

In this work bioleaching of vanadium has been done from Saghand Ore (Anomaly II). Leaching of vanadium was done in several stages. First, Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxxidans were used for dissolution of pure vanadium pentoxide and it was observed that these bacteria are able to dissolve and reduce vanadium with high efficiency. After that these bacteria were employed to leaching of vanadium from ore; however there were no results by those experiments and no vanadium dissolved in liquor although bacterial activity was visible. In the second stage, oxalic acid 0.1 M as an organic acid and three inorganic acids, namely sulfuric, hydrochloridric and nitric acids, in... 

MIMO radar is a next generation radar which transmits arbitrary waveforms at each one of its apertures. It has been shown that design of waveforms for MIMO radars in order to synthesize a desired spatial beampattern, is mapped into a waveform correlation matrix (R) design in the narrowband case. Therefore, waveform design in MIMO radar for beamforming could be broken into two steps, namely correlation matrix design and waveform synthesis for achieving given R. As of now, given a desired beampattern or estimated location information of targets, calculating R has been modeled as an optimization problem like SDP. Also, in some special cases like rectangular beampattern, close form solutions for... 

Many statistical systems such as earthquakes, road trafcs, forest fres, neurocortical avalanches etc. exhibit self-organized criticality (SOC). In such systems without tuning extrenal parameters, the system arrives at criticality. During recent decades, a number of models are introduced which show the same charactristics. These models have made a platform to investigate the physics of self-organized criticality. Among them, sandpile models are the best known models. They exhibit critical behaviour such as scaling laws. Also in some of them conformal invariance is checked nummerically.Most of sandpile models deal with slope parameters, that is, the main dynamical parameters are the local... 

Carbon nanostructures are of great importance in scientific and industrial research. Two case of the important two-dimensional carbon nanostructures are graphitic carbon nitride (g-C3N4) and graphene. In the first part of this work, adsorption of important heavy metal cations including Hg+2, Ag+, Cr+3, Pb+2, Cu+2, Ni+2, Cd+2, Tl+, Sb+3, Zn+2 and As+3 on the surface of (g-C3N4) was investigated by density functional theory (DFT). The main purpose of this theoretical study is to evaluate the ability of g-C3N4 to adsorb pollutant cations. The most prominent result of this work was the ability of g-C3N4 for effective adsorption of As+3 and Sb+3 ions from aqeous solutions. Also, another... 

A general regularity has been found based on an effective pair potential of Lennard-Jones LJ (12, 6) for both dense nonmetallic and nonionic fluids and solids; namely, (Z-1)V2 linearly varies with respect to ρ2, this equation of state (EoS I) is known as LIR. The other equation of state (EoS II), according to wich the isotherm of (Z-1)V2 is linear in term of 1/ρ, wich gives a good description for the metallic and ionic fluids and solids. This equation of state was suggested based on an effective pair potential of LJ (6, 3). Unexpectedly, solid and liquid Ne indicates a significant deviations from EoS I. Recently, a general equation of state (EoS III) based on an effective near-neighbor pair... 

Let Σ be a connected orientable surface of finite type. Due to Nielsen and Thurston’s classification, it is known that any element of the mapping class group of Σ is periodic, reducible, or (exclusively) pseudo-Anosov. Thus it is natural to form a random walk on the mapping class group with a step distribution and ask about the asymptotic distribution of the location of the random walk on each of the mentioned classes. Joseph Maher has proved that if the group generated by the support of is a non-elementary subgroup of the mapping class group, then the random walk will encounter a pseudo-Anosov element with asymptotic probability one. Indeed, this result not only concerns random walks on... 

This research focuses on physics-informed neural networks, which are trained to solve supervised machine learning tasks while adhering to physical laws described by general nonlinear partial differential equations. Previous studies utilized Gaussian process regression to develop functional representations designed for a given linear operator. However, despite the flexibility of Gaussian processes, solving nonlinear problems presents two major limitations: first, authors had to linearize each nonlinear term over time, and second, the Bayesian nature of Gaussian process regression requires specific assumptions that may limit the model’s representational capacity. For these reasons, data-driven... 

This research introduces temperature measurement by a non-intrusive pyrometric method of the ratio of two colors of soot. For pyrometry, the spectral sensitivity of the Nikon D7100 camera was obtained by developing a neural network based on the results of photographing colored papers and their spectrum, and this camera was used for temperature measurement. Based on the dependence of soot radiation on temperature and the spectral sensitivity of the camera, a calibration chart has been extracted on the ratio of the green channel to the red channel of the camera with the soot temperature, which is used to produce the temperature contour using the flame image. The temperature contour of...