Sharif Digital Repository

With the increasing development of Internet of Things (IoT) devices, issues such as establishing effective communication, optimizing energy consumption, ensuring reliability and improving the quality of services provided by these devices become more and more complex and critical challenges. With the introduction of fog computing model by Cisco in 2012, some of these challenges were successfully managed. Fog computing is a distributed computing paradigm that acts as a middle layer between cloud data centers and IoT-based devices/sensors. By distributing computing resources closer to edge devices, fog computing enables real-time data processing and analysis. However, one of the key aspects in... 

The dispersed phase holdup is one of the important parameters in the design pulsed column and set the column diameter, height and characteristics of flooding and mass transfer. High efficiency and low space requirements of these columns cause is particularly in the nuclear industry, Due to the possible presence of radiation and the need for protection against radiation, considered and used. In this project, the dispersed phase holdup and mean residence time in a pulsed disc and donut column in a semi-industrial scale using radiotracer and shut down methods compared and presented for water-kerosene system. Also axial dispersion coefficient in the column using radiotracer methods is calculated... 

Successful formulation development for poor water soluble drugs is a critical, long-standing and challengeable problem in cancer treatment. One of the methods for transporting low-soluble drugs is using nanoparticles which are able to pass through capillary walls of tumor tissues due to their small size. An example of the nanoparticles is micelle systems. Functionalized β-cyclodextrin (β-CD) by hyper branched polyglycerol (HPG) can dissolve low-soluble compounds. This polymer can be used in preparing micelles. In this project, β-cyclodextrin (β-CD) by anionic reactions is initiator for polymerization of glycidol monomer. Hydrophobic cavity of the β-cyclodextrin (β-CD) in placing the phenyl... 

In this project rotational barrier around the C-N bond in 4-ethyle-morpholine- carboxylate has been studied using DNMR spectroscopy. Spectra were taken at variable temperature, and then with simulation of bandshape broadening pattern at coalescence region, rate constants of exchange were obtained for all temperatures. For simulation of line-shape broadening Spinworks software was used, that with two interfaces made possible simulation with two bandshape simulator programs, DNMR and MEXICO. The rate constants obtained from simulations, were used for calculation of thermodynamic activation parameters (∆G#, ∆H#, ∆S# and Ea). ∆G# 298 value of 13.66 Kcal/mol for 4-ethyle-morpholine- carboxylate... 

Liquefaction has a profound effect on buildings, bridges, buried pipes and other engineering structures. This phenomenon can lead to the sliding of huge earth masses, submersion and bending of substantial structures, uplift of buried light structures and collapse of retaining walls. In recorded earthquakes, liquefaction has caused major damage to structures and deep foundations, proving that pile foundations are not designed to withstand at liquefaction condition. Considerable damages in pile foundations due to liquefaction in destructive earthquakes has called for extensive study and research concerning the behavior and response of piles under the influence of liquefaction, resulting in... 

The present study deals with the analysis of Atomic Microscope with crack by making use of Strain Gradient Elasticity theory. Empirical observations represent that in micro dimensions, materials show behaviors, which the classic continuum mechanics theories are not able to explain. Thus, taking advantage of non-classic theories, which are capable of explaining such phenomena or behaviors in analyzing materials in micro dimensions seems necessary and of much significance. In this direction, by applying an Euler-Bernoulli beam assumption and neglecting the shear effects, governing equations and boundary conditions of the problem were obtained via taking advantage of variations in Hamilton... 

High rate of failures in construction projects in IRAN and other developing countries shows that current methods for evaluating projects are not reliable and unfailing. The most important criteria for assessing the success of projects is their cost and time performance. Estimate at Completion (EAC) is an important matter, which takes into consideration project performance and future risks in estimating final cost of project. EAC helps project managers to be aware of the final cost of the projects sooner and adopt response strategies. This study constructed an extension on EVM and risk management to develop an evolutionary EAC model to estimate final cost of project. In this model by... 

Upscaling is an important step in hydrocarbon reservoir modeling which reduces the number of grid blocks of high detailed geological models to prepare them for flow simulation. This helps to speed up computational process, to keep the simulation (CPU) time within a reasonable range and to make future engineering analysis (history matching, comparison of production scenarios, Monte Carlo simulation and etc.) possible. The accuracy of post processing analysis heavily depends on the robustness and validation of the applied upscaling method. Although numerous methods have been proposed in the literature, overemphasizing the effect of scale on the behavior of complex governing equations has... 

Effective stress variation is one of the main issues in petroleum and gheothermal reservoir development. These stress variation could cause formation damage, sand production, sloughing shale and various modes of borehole instability like induced fractures and borehole wall shearing. In petroleum engineering, drilling a borehole is the first step in reservoir development. The wellbores are implemented to produce or inject fluids such as water, oil, gas and chemical fluids used during secondary and tertiary recovery processes. Upon drilling a borehole, reservoir pore pressure, rock and fluid temperature and mechanical stresses change which induces borehole instability and variations in rock... 

The goal of this thesis is to devise a guidance law that has the required ability and flexibility to construct a variety of return trajectories for a reentry capsule to the atmosphere. One of the commonly used methods for guiding flying vehicles with a fixed initial position and a fixed target is to load the trajectory data into the vehicle's computer memory. But the devised guidance law in this thesis does not require the trajectory data. Based on the relations governing the Bezier curve, it constructs the desired trajectory online. It also has the ability to provide the desired angle of landing and the desired magnitude of final speed. Further studies indicate that this ability is also... 

In this study, a novel and unprecedented multi-scale hierarchical molecular dynamics (MD) – finite element (FE) coupling method is proposed to demonstrate the influence of temperature on mechanical properties of heterogeneous Nano-crystalline structures. The embedded-atom method (EAM) many-body interatomic potential is implemented to consider pairwise interactions between atoms in the metallic alloys with face-centered-cubic (FCC) lattice structure at different temperatures. In addition, the Nose-Hoover thermostat is employed to adjust the fluctuation of temperature. In order to calculate the equivalent lattice parameter, a weight average between the lattice parameters of atomic structures... 

Antioxidants are compounds with anti-cancer, anti-bacterial, anti-viral, anti-aging and anti-allergic properties. In the present study, a quantum mechanical approach has been used to shed light on the presence effect of glycoside group on the antioxidant ability of chrysin as one of the most important consumable flavonoids and two glycoside derivatives, chrysin-6-C-fucopyranoside and chrysin-3-malonyl-6-C-fucopyranoside which has electron-withdrawing group (EWG) in its C3 of glycoside group. Density functional theory (DFT) using B3LYP and UB3LYP functional and split-valance 6-311++G ** basis set were used to optimize chrysin, its different derivatives, and their radicals. Analysis of... 

In this thesis, We have investigated the accuracy of general equation of state ( EoS III ) and linear isotherm regularity ( EoS I ), introduced on 2009 and 1993, respectively, and the Ghatee’s equation of state ( EoS II ) introduced on 2001, for the pvT data and thermodynamic properties of [BMIM][PF6] ionic liquid. We have carried out simulations at first in a narrow range of pressure, namely within 1-3400 atm and in temperature range from 398 K to 1000 K. The results of fitting of EoS I, EoS II and EoS III into the simulations results, leads to R2 > 0.9936, 0.9800 and 0.9949 respectively, for the pressure range of 1-3400 atm and for the temperature range of 398-1000 K. The results of... 

The goal of this research is to study the effect of local microcracking due to step by step pressure loading on the durability properties of geopolymer concrete. To better understand the behavior of GGBS-based GPC under different pressure stress levels, some experiments such as water permeability and water absorption conducted on the samples at each state of damage. Also, non-destructive tests such as ultrasonic waveform and pulse velocity (UPV) was used to quantify the extent of damage at each step. GGBFS and a blend of sodium silicate solution and 10 molar sodium hydroxide solution with SSSH⁄ ratio of 2 were used for production of GPC samples. GPC, OGPC and OPC samples with water to binder... 

In this research, the effect of various parameters on the behavior of silty sands is evaluated under special loading conditions. To evaluate these parameters, the hollow cylinder apparatus of the Advanced soil mechanics at Sharif University is used. In this research the effect of principal stress directions, initial anisotropic consolidation, silt content, effective mean normal consolidation stress and intermediate principal stress are studied on the behavior of silty sands including the strength and pore water pressure. In order to evaluate these parameters, the specimens are made with wet tamping method with 0, 10, 20, 30 and 40 percent of silt. Before applying shear load to specimen, the... 

In this project, the behavior of single strand DNA (ssDNA) that is end-tethred to surface (surface is covered with an layer of mercaptohexane ) through the Monte Carlo simulation has been investigated. To understand this behavior, a ssDNA has been studied through freely jointed chain (FJC) model with electrostatic, base paring, and base-pair stacking interaction. The concentration of sodium chloride salt in solution is 1 mM and the applied surface potential is -1.5 - +0.25 V. Computational results show that the ssDNA chain can have the following configurations: 1) “very closed”, 2) “closed”, and 3) “open” that considering the amount of energy, the mentioned configurations can be compared... 

In order to increase the strength of metals such as aluminum, severe plastic deformation processes can be used. Due to the fact that the dimensions of their products are usually small due to limitations, the connection of severely deformed sheets can be considered. Friction stir welding seems to be suitable for this purpose as a solid state process, but due to the significant amount of strain energy stored in this type of sheet, after recrystallization in the stir zone and the surrounding areas often experience severe grain growth. In this research, the 1050 aluminum sheets are severely deformed by constrained groove pressing (CGP) process were subjected to friction stir welding.... 

Deformation and breakup of drops are the basisof many interfacial flow studies and appear in a number of industrial applications, e.g., spray painting, spray combustion, emulsion, foam, sedimentation, and rain. Following their formation, drops may enter a region where hydrodynamicforces are large enough to cause their significant deformation and breakup. When a drop breaks apart into a multitude of small fragments due to disruptive hydrodynamicforces, the process is termed secondary atomization or breakup. Due to many engineering and scientific applications of multiphase and multi-component flows, they have been the main topic of many researchers for many years. Particularly, interfacial... 

Many processes in the petroleum engineering industry involve particle transport in oil and gas reservoirs including sand production, fines migration, and nanoparticle injection. In these processes it is important to understand where the particles are travelling in the reservoir and the impact that they have on the formation properties. Large particles can damage the formation and decrease permeability which reduces the productive capacity of the reservoir. During nanoparticle injection, forces at the pore level can cause retention of particles and prevent their recovery. In addition, due to the heterogeneity of typical reservoirs, it is difficult to predict how particles will spread across... 

In recent years, the application of base isolation as a seismic design strategy for reducing the effects of earthquake ground motion has become an advantageous method and much effort has been devoted to base isolation research and there has been a growing acceptance of this approach. In this research, the effect of using base isolators in reducing the dynamic forces of piers and abutments of bridges is studied. More specifically double-span bridges are the target of this research. After modeling a regular bridge in a typical analysis program, it is excited by different earthquake accelerograms and then the effect of using base isolators in dissipating the earthquake energy is investigated