Sharif Digital Repository

A fast high-performance liquid chromatography-diode array detection (HPLC-DAD) approach combined to solid phase extraction (SPE) as a pre-concentration step is developed for simultaneous determination of five selected pharmaceuticals (carbamazepine, naproxen, diclofenac, gemfibrozil and mefenamic acid) in water samples. The effective factors on the efficiency of SPE procedure are optimized using faced-centered central composite design (FCCD). In addition, multi-response optimization by using Derringer's desirability function is used to find the optimum experimental conditions for extraction of analytes from well and river waters. Due to the complexity of water matrices and the presence of... 

As a means to relieve traffic congestion, toll pricing has recently received significant attention by transportation planners. Inappropriate use of transportation networks is one of the major causes of network congestion. Toll pricing is a method of traffic management in which traffic flow is guided to proper time and path in order to reduce the total delay in the network. This article investigates a method for solving the minimum toll revenue problem in real and large-scale transportation networks. The objective of this problem is to find link tolls that simultaneously cause users to efficiently use the transportation network and to minimize the total toll revenues to be collected. Although... 

Sol-gel based solid-phase microextraction fibers supported by a stainless steel wire were fabricated and employed for GC-MS determination of oxadiargyl in real samples. The fibers were based on four compounds with different polarity: polar and non-polar (end-capped) poly(dimethylsiloxane) (PDMS), polyethylene glycol (PEG), and poly(ethylene-propyleneglycol)-monobutyl ether (UCON). For this purpose, the surface of the stainless steel was initially modified by (3-mercaptopropyl) trimethoxysilane. The results of the modification procedure were evaluated by cyclic voltammetry and energy dispersive X-ray (EDX) spectroscopy. After the modification, four different sol-gel based SPME fibers with... 

This paper presents a robust tracking approach to handle challenges such as occlusion and appearance change. Here, the target is partitioned into a number of patches. Then, the appearance of each patch is modeled using a dictionary composed of corresponding target patches in previous frames. In each frame, the target is found among a set of candidates generated by a particle filter, via a likelihood measure that is shown to be proportional to the sum of patch-reconstruction errors of each candidate. Since the target's appearance often changes slowly in a video sequence, it is assumed that the target in the current frame and the best candidates of a small number of previous frames, belong to... 

In this brief, we present a fine-grained dark silicon architecture to facilitate further integration of transistors in static random access memory-based reconfigurable devices. In the proposed architecture, we present a technique to power off inactive configuration cells in nonutilized or underutilized logic blocks. We also propose a routing circuitry capable of turning off the configuration cells of connection blocks (CBs) and switch boxes (SBs) in the routing fabric. Experimental results carried out on the Microelectronics Center of North Carolina benchmark show that power consumption in configuration cells of lookup tables, CBs, and SBs can, on average, be reduced by 27%, 75%, and 4%,... 

The aim of the present study was to experimentally investigate the interaction between a low replacement ratio of different nano-particles (SiO2, Al2O3, clay, and CaCO3) and aminosilane in the matrices of cement paste and mortar. Results showed that the optimum content of aminosilane for improving the 28-day compressive strength of cement mortar was 0.75% (by weight of the total binder). The utilization of nano-SiO2 and nano-clay particles improved the strengths of the cement mortar containing hybrid systems of nano-particles/aminosilane at early (7 days) and middle curing ages (28 and 91 days). The 28-day compressive strength enhancement of cement mortar with hybrid systems of nano-SiO... 

A series of biodegradable acrylic terminated polyurethanes (APUs) based on poly(ε-caprolactone) diol (PCL), aliphatic 1,6-hexamethylene diisocyanate (HDI) and hydroxyethyl methyl acrylate (HEMA) was synthesized as potential materials for hard tissue biomedical applications. PCLs with low molecular weights of 1000 and 2000 g/mol were employed to provide different amounts of end capped urethane acrylate in APUs. To control crosslink density, a mixture of two different reactive diluents including mono-functional HEMA and bi-functional ethylene glycol dimethacrylate (EGDMA) with different weight ratios was incorporated into the APUs, called here PUAs. Morphological characteristics and mechanical... 

In this study, N-way partial least squares (NPLS) is proposed to correlate comprehensive two-dimensional gas chromatography-time of flight mass spectrometry (GC × GC-TOFMS) data of different aromatic oil fractions (fresh and weathered) to their toxicity values. Before NPLS modeling, since drift and wander of baseline interfere with information of sought analytes in GC × GC-TOFMS data, a novel method called two-dimensional asymmetric least squares is thus developed for comprehensive correction of the baseline contributions in both chromatographic dimensions. The algorithm is termed comprehensive because it functions to correct the entire chromatogram in both dimensions and it preserves the... 

In this study, we present fabrication and characterization of a gas ionization sensor based on high aspect ratio one-dimensional CuO nanowires as the field enhancing medium. Self-organized arrays of CuO nanowires have been synthesized based on a low-cost thermal oxidation method and integrated into a gas ionization sensor (GIS). The self-organized arrays of CuO nanowires have been employed to detect the identity of several gas species such as He, Ar and CO at ambient temperature and pressure. The sharp nanoscale size of CuO tips provide very high electric fields at moderate voltages (less than 100 V) and provoke the breakdown of different gases. The reduced breakdown current of the metal... 

Gas injection is the second largest enhanced oil recovery process being applied in many reservoirs around the world. Simulation of these processes is necessary for implementation, management, and decision making. Relative permeability is one of the most important factors in numerical reservoir simulation. In this study, several core flood experiments are done and the relative permeability in carbon dioxide (CO2) injection is compared with nitrogen (N2) injection. Oil relative permeability in CO 2 injection is found to be higher than in N2 injection, but gas relative permeability in CO2 injection is found to be lower than in N2 injection. Higher oil relative permeability in CO 2 injection... 

Given a random variable (Formula presented.) and a set of experts (Formula presented.), we describe a method for finding a subset of experts (Formula presented.) whose aggregated opinion best predicts the outcome of (Formula presented.). Therefore, the problem can be regarded as a team formation for performing a prediction task. We show that in case of aggregating experts' opinions by simple averaging, finding the best team (the team with the lowest total error during past (Formula presented.) rounds) can be modeled with an integer quadratic programming and we prove its NP-hardness whereas its relaxation is solvable in polynomial time. At the end, we do an experimental comparison between... 

Solid inflation can support a long period of anisotropic inflation. We calculate the statistical anisotropies in the scalar and tensor power spectra and their cross-correlation in anisotropic solid inflation. The tensor-scalar cross-correlation can either be positive or negative, which impacts the statistical anisotropies of the TT and TB spectra in CMB map more significantly compared with the tensor self-correlation. The tensor power spectrum contains potentially comparable contributions from quadrupole and octopole angular patterns, which is different from the power spectra of scalar, the cross-correlation or the scalar bispectrum, where the quadrupole type statistical anisotropy dominates... 

Bioinspired materials can mimic the stem cell environment and modulate stem cell differentiation and proliferation. In this study, biomimetic micro/nanoenvironments were fabricated by cell-imprinted substrates based on mature human keratinocyte morphological templates. The data obtained from atomic force microscopy and field emission scanning electron microscopy revealed that the keratinocyte-cell-imprinted poly(dimethylsiloxane) casting procedure could imitate the surface morphology of the plasma membrane, ranging from the nanoscale to the macroscale, which may provide the required topographical cell fingerprints to induce differentiation. Gene expression levels of the genes analyzed... 

Injecting low salinity brines is regarded as an enhanced oil recovery (EOR) process through IFT reduction. However, the exact mechanism behind this process is an unsettled and complex issue that has not been well understood yet, especially for heavy crude oil system. Besides, limited information is available regarding the key heavy oil/brine interfacial tension (IFT). The present study aims to investigate the sensitivity of dead heavy crude oil/brine IFT to a wide range of properties/conditions and to reveal the underlying physicochemical mechanisms involved in enhanced oil recovery and IFT reduction by low salinity water injection into heavy oil reservoir. IFT was measured as a function of... 

We outline a comprehensive numerical procedure for modeling of species transport and surface reaction kinetics in electrokinetically actuated microfluidic devices of rectangular cross section. Our results confirm the findings of previous simplified approaches that a concentration wave is created for sufficiently long microreactors. An analytical solution, developed for the wave propagation speed, shows that, when normalizing with the fluid mean velocity, it becomes a function of three parameters comprising the channel aspect ratio, the relative adsorption capacity, and the kinetic equilibrium constant. Our studies also reveal that the reactor geometry idealized as a slit, instead of a...