Sharif Digital Repository

Three new Cu(I) complexes containing bidentate N^N donor ligands with the general formula [Cu(N^N)2][PF6] (N^N = 2,3-diphenyl-6,7-di-p-tolyl-1,4,5,8-tetraazaphenanthrene (L1), 2,3-diphenyl-6,7-di(2-thienyl)-1,4,5,8-tetraazaphenanthrene (L2), and 2,3-diphenyl-6,7-di-p-fluorophenyl-1,4,5,8-tetraazaphenanthrene (L3), were prepared by the reaction of [Cu(CH3CN)4][PF6] with two equivalents of the N^N ligand. Single-crystal X-ray diffraction analysis confirmed that in each complex the metal displays a distorted tetrahedral geometry surrounded by the four N atoms of the two sterically hindered substituted tetraazaphenanthrene (TAP) ligands. Density functional theory (DFT) and time-dependent density... 

We present fabrication, characterization, and experimental results describing electrical actuation and readout of the mechanical vibratory response of electrospun ZnO nanofibers. For a fiber with an approximate radius of 200 nm and a length of 70 ìm, a resonance frequency around 3.62 MHz with a quality factor (Q) of about 235 in air at ambient conditions is observed. It is shown that the measured frequency of the resonance is consistent with results from finite element simulations. Also, the measurements were performed in an enclosed chamber with controlled levels of ethanol vapor. The adsorption of ethanol causes a shift in the resonance frequency of the fibers, which can be related to the... 

In this paper, we describe a carbon dioxide mineralization process and its associated solid products. These solid products include amorphous silica, iron hydroxides and magnesium carbonates. These products were subjected to various characterization tests, and the results are published here. It was found that the iron hydroxides from this process can have different crystalline properties, and their formation depended very much on the pH of the reaction conditions. Different forms of magnesium carbonate were also obtained, and the type of carbonate precipitated was found to be dependent on the carbonation temperature. Hydromagnesite was obtained mainly at low temperatures, while dypingite was... 

Context. The extrasolar planet WASP-67 b is the first hot Jupiter definitively known to undergo only partial eclipses. The lack of the second and third contact points in this planetary system makes it difficult to obtain accurate measurements of its physical parameters  

Dijet production has been measured in pPb collisions at a nucleon–nucleon centre-of-mass energy of 5.02 TeV. A data sample corresponding to an integrated luminosity of 35 nb−1 was collected using the Compact Muon Solenoid detector at the Large Hadron Collider. The dijet transverse momentum balance, azimuthal angle correlations, and pseudorapidity distributions are studied as a function of the transverse energy in the forward calorimeters (E4<|η|<5.2 T). For pPb collisions, the dijet transverse momentum ratio and the width of the distribution of dijet azimuthal angle difference are comparable to the same quantities obtained from a simulated pp reference and insensitive to E4<|η|<5.2 T. In... 

Carbon dioxide sequestration by a pH-swing carbonation process was considered in this work. A multi-step aqueous process is described for the fractional precipitation of magnesium carbonate and other minerals in an aqueous system at room temperature and atmospheric pressure. With the aim to achieve higher purity and deliver more valuable mineral products, the process was split into four steps. The first step consists of Mg leaching from the magnesium silicate in a stirred vessel using 1 M HCl at 80 °C, followed by a three step precipitation in reactors in sequence to remove Fe(OH)3, then Fe(OH)2 and other divalent ions, and finally MgCO3 nucleation and growth. Hydrated magnesium carbonate... 

A search for excited quarks decaying into the γ + jet final state is presented. The analysis is based on data corresponding to an integrated luminosity of 19.7 fb-1 collected by the CMS experiment in proton-proton collisions at √s=8TeV at the LHC. Events with photons and jets with high transverse momenta are selected and the γ + jet invariant mass distribution is studied to search for a resonance peak. The 95% confidence level upper limits on the product of cross section and branching fraction are evaluated as a function of the excited quark mass. Limits on excited quarks are presented as a function of their mass and coupling strength; masses below 3.5 TeV are excluded at 95% confidence... 

A search for supersymmetry through the direct pair production of top squarks, with Higgs (H) or Z bosons in the decay chain, is performed using a data sample of proton-proton collisions at s=8 TeV collected in 2012 with the CMS detector at the LHC. The sample corresponds to an integrated luminosity of 19.5 fb-1. The search is performed using a selection of events containing leptons and bottom-quark jets. No evidence for a significant excess of events over the standard model background prediction is observed. The results are interpreted in the context of simplified supersymmetric models with pair production of a heavier top-squark mass eigenstate t~2 decaying to a lighter top-squark mass... 

The ratio of the top-quark branching fractions R=B(t→Wb)/B(t→Wq), where the denominator includes the sum over all down-type quarks (q = b, s, d), is measured in the tt- dilepton final state with proton-proton collision data at s=8 TeV from an integrated luminosity of 19.7 fb-1, collected with the CMS detector. In order to quantify the purity of the signal sample, the cross section is measured by fitting the observed jet multiplicity, thereby constraining the signal and background contributions. By counting the number of b jets per event, an unconstrained value of R=1.014±0.003(stat.)±0.032(syst.) is measured, in a good agreement with current precision measurements in electroweak and flavour... 

Constraints are presented on the total width of the recently discovered Higgs boson, ΓH, using its relative on-shell and off-shell production and decay rates to a pair of Z bosons, where one Z boson decays to an electron or muon pair, and the other to an electron, muon, or neutrino pair. The analysis is based on the data collected by the CMS experiment at the LHC in 2011 and 2012, corresponding to integrated luminosities of 5.1fb -1 at a center-of-mass energy s=7TeV and 19.7fb -1 at s=8TeV. A simultaneous maximum likelihood fit to the measured kinematic distributions near the resonance peak and above the Z-boson pair production threshold leads to an upper limit on the Higgs boson width of ΓH...