Sharif Digital Repository

In this work, graphene oxide (GO) and Amino ethyl phosphonic acid (AEPA) functionalized graphene were synthesized using chemical method. In addition, reduced graphene was prepared by chemical and supercritical methods. Physical, chemical, morphological properties of as-synthesized materials were investigate using XRD, FTIR, RAMAN, UV, TEM, TGA, and BET. Thickness of monolayer GO which synthesized using Hummer’s method was evaluated 1 nm using AFM. FTIR and CHN results were affirmed the presence of AMPA onto graphene nanosheets. Adsorption properties of functionalized graphene for Th ions from aqueous solution was examined. Isotherm adsorption results demonstrated that maximum adsorption... 

Due to both dynamic and opportunistic spectrum access, Cognitive radio networks is a promising solution for spectrum scarcity problem. In cognitive radio networks, users need to have a control channels in order to cooperate for sharing the sensing information, channel sharing and etc. In Ad-hoc cognitive radio networks because of the absence of infrastructure and central nodes, every user runs a distributed algorithm to create a common control channel. If the control channel gets jammed, network’s performance degrades dramatically, therefore the jammer’s target in cognitive radio networks is the control channels to disturb the networks’ performance. The traditional solution to confront... 

Technology, especially in recent centuries, has changed human form of life. Case studies show that there is a mutual relationship between human being and technology; Human is a technological being and technology is also a social entity. Therefore, trying to develop a conceptual framework to describe the important role of technical artifacts in our life can be regarded as a legitimate philosophical concern. Peter Paul Verbeek is one of the contemporary philosophers who take this concern seriously. He, by using the doctrines of The Empirical Turn in the philosophy of technology, has developed a lexical system, called post-phenomenology, to describe the role of Technology in human’s perception... 

A number of players are positioned on the vertices of a finite graph, and each is wearing a hat whose color has been randomly and equally likely selected from a finite set of colors. Player A sees Player B if and only if there is a directed edge from the vertex corresponding to A to the vertex corresponding to B. The players must agree on a specific strategy before the game begins and carry it out. Once the game begins, no communication is allowed between the players, and each player must simultaneously guess the color of their own hat. The team wins if at least one guess is correct. For a given directed graph, we define the 'guessing number' of the graph as the maximum number of colors for... 

All the main knowledge currents —from the humanities to the experimental sciences— consider themselves explicitly or implicitly indebted to Neo-Kantianism, an approach that, by removing the sensory-material component from the production of reality, prevented the entry of all accidental and unexpected elements into the various fields of human knowledge and gave a not very productive peace to the European world: the peace that came to Europe not only in experimental sciences but also in politics and economy, but it made the existence of Europe weak and sterile. This is the judgment that I have tried to make as far as I can to show what fate the acceptance of Neo-Kantianism brings to man. The... 

In the proccess of making key slots in lock parts, broaching is necessary. The only procedure or at least the best procedure for making the slots is broaching. High speed and precision, surface quality and the ability to create complicated surfaces in one step are the advantages that make broaching suitable for this product. The cost of tool maintainance and replacement is very important to make this process efficient economically, therefore, determining the factors affecting tool life are important for industries. The purpose of this study is to increase the life of narrow broaching tools. In other words, in this study, the purpose is to design and manufacture the tool in such a way that... 

Hyperbolic branching Brownian motion is a branching diffusion process in which individual particles follow independent Brownian paths in the hyperbolic plane H2, and undergo binary fission(s) at rate λ > 0. It is shown that there is a phase transition in λ : For λ ≤ 1/8 the number
of particles in any compact region of H2 is eventually 0, w.p.1, but for λ > 1/8 the number of particles in any open set grows to ∞ w.p.1. In the subcritical case (λ ≤ 1/8) the set Λ of all limit points in ∂H2 (the boundary circle at ∞) of particle trails is a Cantor set, while in the supercritical case (λ > 1/8) the set Λ has full Lebesgue measure. For λ ≤ 1/8 it is shown that w.p.1 the Hausdorff dimension of Λ... 

Lithium has two stable isotopes naturally including 6Li at 7.5% and 7Li at 92.5% relative abundance. In spite of the similarities of lithium isotopes in common chemical reactions, they have some completely distinctive behaviors in nuclear reactions. 6Li has considerable neutron cross section capturing in thermal neutron range about 945 barns while this feature for 7Li is insignificant about 0.037 barns. This difference makes them to play different roles in nuclear uses. 7LiOH is applied for pH adjustment of coolant in light water reactors. 6Li is not only used as a shielding material against thermal neutrons, but also is known as a source of tritium in the blanket of fusion reactors which... 

Thin films of materials, in order to have magnificent structure and properties, can use in complicated technology such as; electronic, optic and magnetic systems. Printed interconnects can be made by the deposition of suspensions of metal nanoparticles (e.g., silver and gold) followed by thermal sintering. The nanoparticle sintering process involves atomic diffusion resulting in shrinkage. As a result, the interconnects are prone to residual stresses generated during the thermal sintering process. The residual stress can cause cracks and delamination in the thin films and can cause permanent geometrical changes in the underlying substrates which may affect the functionality of the... 

One of the most convenient methods for the synthesis of metal oxide nanoparticles, inorganic ceramic materials and catalysts is supercritical hydrothermal method. In its pure form or mixed metal oxide nanoparticles have potential applications are wide. An important aspect of functional metal oxides of uranium dioxide as the selective catalyst for the conversion of methane to methanol and chlorinated organic matter decomposition is used. The main issue that led to the definition of this project was that nanoparticles synthesized with supercritical hydrothermal conditions influenced by change in the temperature. Temperature also affects the particle size and the conversion efficiency. This... 

Spray-wall impingement is one of the phenomenon that associated in different subject such as spray cooling, combustion chamber and gas turbine. With the impingement of spray to the wall, liquid film begins to form. Wall film characteristics is still an important subject to study. Due to the various stages of liquid film formation from injection of spray till spray-wall impingement, the investigation of this phenomenon is far more complicated. This paper is meant to provide detailed data on spray-wall impingement and wall film formation physics with the help of computational analysis of OpenFOAM . A Lagrangian-Eulerian method based on discrete phase model (DPM) was employed to model... 

I-131 isotope is one of the most significant radio medicines for treatments of the thyroid cancer and nuclear tomography of thyroid. As for purification of this radioisotope several methods have been developed among which adsorption-desorption on metallic copper is the most promising. The current study is aimed at elaboration of the kinetics behavior of the different types of metallic copper for adsorption of iodine vapor. The used copper samples included plain and silica-supported Cu nanoparticles as well as micronized copper. The silica-supported Cu nanoparticles were prepared by impregnation of highly porous silica (≈500 m2/g) in Cu(NO3)2 solution, heating of the solution to above... 

In this study, epoxy resin has been modified by nano-clay additives using direct mixing method and epoxy-clay nanocomposites were designed and produced with optimized percentage of clay content. By adding the powder of born carbide and lead oxide in nanocomposites new compounds are obtained. The results are used for protection against neutron and gamma rays, respectively. After preparation of epoxy-clay-born carbide and epoxy- clay-lead oxide nanocomposite the effects of irradiation and carbon fiber on mechanical and thermal properties of nanocomposites were examined. The Nanocomposites were exposed to Electron Beam Irradiation (EBI) in 100 and 500 kGy doses to investigate the effect of... 

Lithium has two stable isotopes, 6Li and 7Li. Abundance of these isotopes are 7.53% and 92.43% respectively. Each isotope has an important role in nuclear industry. For example, 6Li compounds is used in production of tritium in nuclear fusion reactors coated with DT fuel and as fuel in nuclear fusion reactors that operate with laser inertial confinement method applied. 7LiOH is used to adjust the pH of the fluid coolant in light water reactors and also in Breeding Reactors. Lithium isotope separation in different ways so far been brought into operation. The other aspect to this work, it can be both continuous and batch for action. Lithium isotopes for the first time by electrolysis using... 

Improvements in the technology of manufacturing mechanical parts in recent years, has enabled the manufacturers to produce machine tools in small sizes (installable on a desk) which look like conventional counterparts and are called desk-top size machine tools. One important aspect of machine tools operation is the machined surface integrity. Thus, it is necessary to compare desk-top size machines with their conventional counterparts from this point of view. This comparison is the purpose of this thesis in which “surface error” and “surface roughness” of milling machines as a kind of machine tools are compared between conventional and miniaturized machines. To compare the surface errors,... 

According to the development of communication, cryptography has become a vital issue. Several algorithms have been introduced for cryptography applications. Stream ciphers are such algorithms with high speed and appropriate efficiency. Lots of attacks have been applied to stream ciphers. We concentrate on two kinds of attacks in this thesis. Distinguishing attack is a general attack in which the attacker tries to distinguish the observed output sequence from random. Designers apply this kind of attack to test the statistical probabilities of the output sequence. We applied this attack on Grain family and Trivium family. In the proposed attack, nonlinear parts are replaced with linear ones.... 

Stream ciphers are cryptographic schemes being widely used in communications as a means of providing security of data. Hence, scrutinizing their level of security against different cryptanalytic methods has obviously turned to be of great importance. Randomness of the keystream is an important requirement for stream ciphers. The cipher should be designed in such a way that the keystream is free of any statistical biases that would let attackers distinguish it from a random sequence. A distinguishing attack on a stream cipher is one that determines whether a given stream of symbols is a truly random sequence or generated by a specific cipher with an unknown key. In this thesis, we focus on... 

According to development of industry in every field such as nanotechnology and micro electro mechanical system (MEM) fabricating of high speed machining with micro dimension has been expanded. Micro spindles are such a device which is useful in many industries such as air space and electronic field. These machines can work in high speed and production rate with vast variety of features. Their dimensions are in millimeter range. So they can manufacture miniature features. Fabricating and technical science production of a high speed micro spindle with speed of more than 100000 RPM (micro macro milling) is purpose of this project. After to literature review according to science of micro... 

Pretreatment of nuclear waste for valuable and limited uranium resources in the nuclear industry as well as environmental protection is imperative. Wash the affected parts of the Natanz uranium enrichment plant uranium centrifuges with a standard cleaning solution of citric acid, a liquid waste is generated in this study, the preparation of these residues using supercritical water oxidation (SCWO) and near critical (HTWO1) was studied as a result, the optimum operating conditions, and conditions of solvent extraction has been studied. In the result, the optimum operating conditions, and conditions of solvent extraction has been introduced. Also in the UCF2 as a liquid waste contaminated with... 

Forging process is recognized as the high speed method, economical and with ability to produce high strength parts between metal forming processes. Preform design is the most important step in forging process. In the past this work was done based on experiences. In the complex parts because of error in design there was probability of diverse dies, so that method needed to spent so many times and costs. However recently with progress in computer programming we don’t need to produce diverse dies but spend many times. In this field many investigations are done to dispose designers skills, so forging preform design based on inverse finite elements method is denoted for this gold. In this thesis...