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    Nanoporous CuS nano-hollow spheres as advanced material for high-performance supercapacitors

    , Article Applied Surface Science ; Volume 394 , 2017 , Pages 425-430 ; 01694332 (ISSN) Heydari, H ; Moosavifard, S. E ; Elyasi, S ; Shahraki, M ; Sharif University of Technology
    Elsevier B.V  2017
    Abstract
    Due to unique advantages, the development of high-performance supercapacitors has stimulated a great deal of scientific research over the past decade. The electrochemical performance of a supercapacitor is strongly affected by the surface and structural properties of its electrode materials. Herein, we report a facile synthesis of high-performance supercapacitor electrode material based on CuS nano-hollow spheres with nanoporous structures, large specific surface area (97 m2 g−1) and nanoscale shell thickness (<20 nm). This interesting electrode structure plays a key role in providing more active sites for electrochemical reactions, short ion and electron diffusion pathways and facilitated... 

    Facile synthesis of nanoporous CuS nanospheres for high-performance supercapacitor electrodes

    , Article Journal of Energy Chemistry ; Volume 26, Issue 4 , 2017 , Pages 762-767 ; 20954956 (ISSN) Heydari, H ; Moosavifard, S. E ; Shahraki, M ; Elyasi, S ; Sharif University of Technology
    2017
    Abstract
    In recent years, development of high-performance supercapacitor electrode materials has stimulated a great deal of scientific research. The electrochemical performance of a supercapacitor strongly depends on its material structures. Herein, we report a simple strategy for high-performance supercapacitors by building pseudocapacitive CuS nanospheres with nanoporous structures, nanosized walls (<10 nm) and relatively large specific surface area of 65 m2/g. This electrode demonstrates excellent electrochemical performance including a maximum specific capacitance of 814 F/g at 1 A/g, significant rate capability of 42% capacitance retention at an ultrafast rate of 50 A/g, and outstanding... 

    A Comprehensive Review of Studies Conducted in Entrepreneurship Education in Order to Achieve a Codified Framework

    , M.Sc. Thesis Sharif University of Technology Emamjome, Fatemeh Sadat (Author) ; Feyzbakhsh, Alireza (Supervisor)
    Abstract
    In the current situation and considering the economic conditions, entrepreneurship and self-employment are important factors of business growth. To prepare people in this field, there is a need for effective training that can motivate people. Identifying the effective methods and different dimensions of the entrepreneurship education framework that can lead to setting up a successful program for training people and facilitate the way to achieve the goal of education is one of the important goals of this research. By studying the literature from 2010 onwards, this research systematically examined 96 articles and tried to improve the framework of entrepreneurship education that was stated in... 

    A study of hyperelastic models for predicting the mechanical behavior of extensor apparatus

    , Article Biomechanics and Modeling in Mechanobiology ; Volume 16, Issue 3 , 2017 , Pages 1077-1093 ; 16177959 (ISSN) Elyasi, N ; Karimi Taheri, K ; Narooei, K ; Karimi Taheri, A ; Sharif University of Technology
    Springer Verlag  2017
    Abstract
    In this research, the nonlinear elastic behavior of human extensor apparatus was investigated. To this goal, firstly the best material parameters of hyperelastic strain energy density functions consisting of the Mooney–Rivlin, Ogden, invariants, and general exponential models were derived for the simple tension experimental data. Due to the significance of stress response in other deformation modes of nonlinear models, the calculated parameters were used to study the pure shear and balance biaxial tension behavior of the extensor apparatus. The results indicated that the Mooney–Rivlin model predicts an unstable behavior in the balance biaxial deformation of the extensor apparatus, while the... 

    Oxidative Addition of Amines to Aldehydes Catalyzed by Supported Cobalt Nanoparticles on SBA-15

    , M.Sc. Thesis Sharif University of Technology Raeisi, Mojdeh (Author) ; Saidi, Mohamad Reza (Supervisor) ; Rajabi, Fatemeh (Co-Advisor)
    Abstract
    Considering the widespread applications of amides, synthesis of these compounds is of great importance. The one pot oxidative addition of amines to aldehydes is one of the most simple and appealing approaches to synthesis amides. With the aim of developing a mild and convenient approach towards preparation of amides, numerous methods have been reported for this important process over the past few decades. These improvements have been mostly related to the optimization of reaction conditions and the use of more challenging substrates including diverse derivatives of aldehydes, and also design a novel and effective catalytic systems. Due to the various advantages of supported heterogeneous... 

    Evaluation of the Damage to Steel MRF Structures Under Near Field Earthquake Pulses Using a Performance-Based Design Approach

    , M.Sc. Thesis Sharif University of Technology Mousavi, Fatemeh Sadat (Author) ; Rahimzadeh Rofooei, Fayaz (Supervisor)
    Abstract
    Research on the characteristics of the near field earthquakes has been very popular in recent years due to the considerable damages they have caused to the structures located within the vicinity of seismic sources. The incapability of response spectra for structural damage assessment has been revealed through recent investigations. The recorded data show that the near field earthquakes are often accompanied by a large energy pulse in the beginning of the records caused by the so-called directivity phenomenon. That has encouraged many researchers to study the possibility of using the velocity pulse of these records to evaluate the imposed seismic demands on structures. Thus, investigating the... 

    Strengthening of metallic beams with different types of pre-stressed un-bonded retrofit systems

    , Article Composite Structures ; Volume 159 , 2017 , Pages 81-95 ; 02638223 (ISSN) Kianmofrad, F ; Ghafoori, E ; Elyasi, M. M ; Motavalli, M ; Rahimian, M ; Sharif University of Technology
    Elsevier Ltd  2017
    Abstract
    Unlike bonded retrofit systems, un-bonded systems do not need any surface preparation prior to bond application, which reduces the overall time and cost of a retrofit plan. Because the carbon fiber reinforced polymer (CFRP) plate in the un-bonded (tendon) systems is not bonded to a metallic substrate, different variants of the retrofit systems can be developed to ease application in the field. This paper presents four different variants of the prestressed un-bonded retrofit (PUR) systems: trapezoidal PUR (TPUR), triangular PUR (TriPUR), Flat PUR (FPUR), and Contact PUR (CPUR) systems. Analytical solutions based on the flexibility approach are developed to predict the behavior of the metallic... 

    On the performance of high voltage electrospray echnique for producing nanoparticles

    , Article 26th Iranian Conference on Electrical Engineering, ICEE 2018, 8 May 2018 through 10 May 2018 ; 2018 , Pages 283-288 ; 9781538649169 (ISBN) Kaboli, S ; Naghibi Nasab, J ; Elyasi, M ; Zarrabi, R ; Vosoghi, M ; Sharif University of Technology
    Institute of Electrical and Electronics Engineers Inc  2018
    Abstract
    Electrospray technique is one of the commonly used methods for generating nanoparticles. In this method, the chemical solution which consists of a polymer and its solvent are injected into an electric field via a nozzle. At the end of this nozzle, due to electric forces, a certain part of this liquid is separated. Then, the separated part is divided into smaller particles and the solvent is evaporated and hence, the nanoparticles are acquired. Produced nanoparticales are collected in deionized water placed under the certain distant from nozzle. However, construction of this method is generally based on practical results. In this paper, modeling and performance evaluation of high voltage... 

    Novel azo-containing polymethacrylates bearing spiroacetal-norbornene moiety and methylene spacers: synthesis and characterization [electronic resource]

    , Article European Polymer Journal ; Volume 37, Issue 10, October 2001, Pages 2111–2121 Pourdjavadi, A. (Ali) ; Mirjalili, Bibi Fatemeh ; Entezami, Ali A ; Zohuriaan-Mehr, Mohammad J ; Sharif University of Technology
    Abstract
    An eight-step synthetic strategy was followed to prepare a series of novel azobenzene-containing methacrylate monomers bearing spiroacetal-norbornene moiety and methylene spacers. Thus, the adduct 2, obtained from cyclopentadiene and acrolein, was converted to 1,3-diol 3. The diol was acetalized with nitrobenzaldehyde 4 under microwave irradiation to obtain nitro compound 5 that was then reduced to amino compound 6. Diazonium salt of 6 was coupled with phenol to produce phenolic compound 7 which was then reacted with n-dibromoalkanes (n=2, 4, 6, 8, 10) to yield bromo compounds 9a–e. Nucleophilic substitution reaction of the bromo compounds with lithium methacrylate produced the methacrylic... 

    One-pot Synthesis of α-Aminonitriles by Reusable Co(II) Supported Nanocatalyst under Solvent-Free Conditions

    , M.Sc. Thesis Sharif University of Technology Ghiassian, Sara (Author) ; Saidi, Mohammad Reza (Supervisor) ; Rajabi, Fatemeh (Supervisor)
    Abstract
    Considering the widespread applications of α-aminonitriles, their synthesis is of great importance. The Strecker reaction represents a direct and appealing approach for the preparation of α-aminonitriles. With the aim of developing a mild and convenient approach towards the construction of α-aminonitriles, numerous methods have been reported for this important process over the past few decades. These have been mostly related to the optimization of reaction conditions and the use of more challenging substrates including ketimines and ketiminium salts and design of novel and effective catalytic systems. Due to the various advantages of supported heterogeneous catalysts and in our aim to... 

    The Application of Chaos Theory and Nonlinear Structures in Financial Time Series

    , M.Sc. Thesis Sharif University of Technology Hosseini Tash, Fatemeh Sadat (Author) ; Modarres Yazdi, Mohammad (Supervisor)
    Abstract
    Financial and monetary markets are appropriate areas of applying Chaos Theory. Firstly, current theories of financial and monetary economics state that economic and financial variables such as exchange rates and stock prices are stochastic, so forecasting them is almost impossible. Secondly, if we find the hidden ordered and deterministic trends, we can achieve considerable profits. In this piece of research, we evaluate different methods and tests of detecting chaos in financial time series, and choose the most applicable methods to test financial markets’ indices. The main three indices of Tehran Stock Exchange, including Price, Finance and Industry indices, are examined. A sample of the... 

    Investigation of hydrogen sensing properties and aging effects of Schottky like Pd/porous Si

    , Article Journal of Sensors and Actuators B: Chemical ; Volume 146, Issue 1 , 8 April , 2010 , PP. 53–60 Razi, F. (Fatemeh) ; Iraji Zad, A. (Azam) ; Rahimi, F. (Fereshteh) ; Sharif University of Technology
    2010
    Abstract
    We prepared porous silicon samples coated by continuous palladium layer in electroless process. Scanning electron microscopy (SEM) showed cauliflower-shape Pd clusters on the surface. I–V curves of Schottky like Pd/porous Si samples were measured in air and in hydrogen. These measurements showed a metal–interface–semiconductor configuration rather than an ideal Schottky diode. Variations of the electrical current in the presence of diluted hydrogen at room temperature revealed that the samples can sense hydrogen in a wide range of concentration (100–40,000 ppm) without any saturation behavior. Hydrogen sensing properties of these samples were investigated at room temperature for a duration... 

    An Integrated Active Circulator for Radar Transceivers with Shared Tx/Rx Antenna

    , M.Sc. Thesis Sharif University of Technology Masoumizadeh, Masoud (Author) ; Fotowat Ahmadi, Ali (Supervisor) ; Akbar, Fatemeh (Supervisor)
    Abstract
    The issue of automation has always been a concern for humans over the years. Replacing humans with machines or intelligent software to perform various tasks can significantly improve the accuracy and speed of those activities. One of the long-standing aspirations of humanity has been the automation of driving. In addition to freeing individuals from the time-consuming task of driving, automating vehicles can also dramatically reduce road accidents. To achieve this goal, vehicles need to be equipped with various sensors such as radar, cameras, lidar, and more. Each of these sensors has its advantages and disadvantages, and as a result, all of them must be used for safe driving. In this... 

    The Study of Function of Lipase Biocatalyst Immobilized on Silica Nanoparticles Used for Biodiesel Production

    , M.Sc. Thesis Sharif University of Technology Kalantari, Mohammad (Author) ; Kazemini, Mohammad (Supervisor) ; Arpanaei, Ayyoob (Supervisor) ; Tabandeh, Fatemeh (Co-Advisor)
    Abstract
    Superparamagnetic core/shell nonporous (S1) and core/shell/shell mesoporous (S2 and S3) nanocomposite magnetite/silica particles with a magnetite cluster core of 130±30 nm, a nonporous silica shell of 90±10 nm thickness, and a mesoporous silica shell of 70±15 nm thickness were prepared thorough a simple method. Mesoporous particles were prepared with two BJH pore sizes (2.44 for S2 and 3.76 nm for S3 particles, respectively). The fabricated S1, S2 and S3 particles present high saturation magnetization values of 20, 13 and 17 emu/g, respectively. As a biological application, the lipase from Pseudomonas cepacia was successfully immobilized onto the amino-functionalized nanocomposite particles... 

    Design and Analysis of a Parallel TKR Simulator for Prosthesis Design Evaluation

    , M.Sc. Thesis Sharif University of Technology Daei Nejad, Fatemeh Sadat (Author) ; Farahmand, Farzam (Supervisor) ; Durali, Mohammad (Supervisor)
    Abstract
    In this project a knee prostheses wear testing simulator based on a parallel mechanism for applying forces and torques, is designed. First according to ISO 14243 standard required degrees of freedom and design constraints are determined and also regarding simulator requirements some considerations in design are outlined. Considering all of these parameters, literature has been searched for proper parallel mechanism and because no suitable parallel mechanism, which is a 3 DoF 2T1R paralle mechanism with rotational degree about z axis, has been found; several new designs of proper mechanism have been presented. Scoring different mechanisms according to outcomed parameters from standard and... 

    Study of Antibacterial Performance of Metal Oxide Nanostructures and their Effect on Bacterial Growth Kinetics

    , M.Sc. Thesis Sharif University of Technology Afkhami, Fatemeh Sadat (Author) ; Naseri, Naimeh (Supervisor) ; Zaker Moshfegh, Alireza (Co-Supervisor)
    Abstract
    Fighting contagious microbial diseases is considered a serious health issue, which has attracted much attention in worldwide. Thus, development of new materials based on nanostructures as a new generation of antibiotics to address this challenge has been of interest to researchers in recent years. Nanostructures based on metallic oxide semiconductors such as oxides with light absorption, production of electron-hole pairs in needle like structures cause tearing bacterial membrane and eventually destroy the bacterium. To this end, we designed experiments to study mechanism and physics governing the process of bacterial degradation to determine the best conditions for inhibiting bacteria... 

    Low Voltage Oscillator Design with the Lowest Reported Phase Noise in the 1/F3 Region at 3.6 GHzTitle

    , M.Sc. Thesis Sharif University of Technology Askarzade Torghabe, Reyhaneh (Author) ; Fotowat Ahmady, Ali (Supervisor) ; Akbar, Fatemeh (Supervisor)
    Abstract
    Oscillators are an important building block in the design of synthesizers for RF system applications. State-of-the-art operation defines that an oscillator should have the best spectral purity while consuming a low amount of power. In recent years, several methods have been presented for reducing phase noise separately in the 1/f2 and 1/f3 regions. As CMOS technology advances, the amount of power supplies decreases, which worsens the inherent flicker noise. In this thesis, it has been tried, while investigating the existing methods in the phase noise in this region, it presents the proposed oscillator which is based on a three-coupled transformer. This voltage bias oscillator operates at a... 

    Sleep Apnea Detection Using Wearable Devices

    , M.Sc. Thesis Sharif University of Technology Rahimi, Hamid Reza (Author) ; Fotowat Ahmady, Ali (Supervisor) ; Akbar, Fatemeh (Supervisor)
    Abstract
    Approximately 1.36 billion people worldwide suffer from sleep apnea, necessitating accurate diagnosis and treatment. Traditional sleep clinics rely on Polysomnography (PSG)-based monitoring devices. However, these devices are not only voluminous but also prohibitively expensive, requiring numerous sensors and wires that disrupt sleep and cause discomfort for patients. To address these challenges, we have developed a wireless wearable system. This system comprises three sensor blocks, each capable of capturing vital signs from the body, resulting in a total of eight signals. The first two sensor blocks capture signals from the body, which are subsequently modulated and transmitted to a user's... 

    Clock and Data Recovery based on Phase Shifting and Accordion Oscillator

    , M.Sc. Thesis Sharif University of Technology Fatemi Mofrad, Ali (Author) ; Fotowat Ahmady, Ali (Supervisor) ; Akbar, Fatemeh (Supervisor)
    Abstract
    The continuous growth of network traffic and people's demand for higher data rates, have driven wireline communication systems towards higher data rates. In these systems, the power consumption of these transmitters and receivers is a crucial and influential factor. This paper presents two different solutions to reduce the power consumption and area of these systems. In the first solution, a low-power phase shifter with variable phase and amplitude control is introduced. The changes in these parameters are mutually orthogonal, ensuring that a change in one characteristic does not affect the others. This phase shifter can be used to generate clock pulses with different phases in wireline... 

    3D distributed modeling of trolling-mode AFM during 2D manipulation of a spherical cell

    , Article Journal of Nanoparticle Research ; Volume 23, Issue 4 , 2021 ; 13880764 (ISSN) Mohammadi, S.Z ; Nejat Pishkenari, H ; Mohammadi Moghaddam, M ; Sharif University of Technology
    Springer Science and Business Media B.V  2021
    Abstract
    In this study, a general 3D distributed modeling of Trolling-Mode AFM (TR-AFM) as a nanorobot is presented to analyze the 2D manipulation process of a spherical cell. To this aim, the analysis is categorized into 3 sections. In the first section, 6 deformations of TR-AFM are taken into account, and the standard model of the system is obtained. Moreover, the system is simulated in ANSYS Workbench. The results of modal and transient analyses of the system from both analytical and software methods reveal high agreement, which confirms the accuracy of the presented analytical model. In the second section, by utilizing the 3D derived model, displacement of a spherical yeast single cell (W303)...