Sharif Digital Repository

Kinetics of oxidation of MgO-C refractories was investigated by shrinking core modeling of the gas-solid reactions taking place during heating the porous materials to the high temperatures. Samples containing 4.5-17 wt pct graphite were isothermally oxidized at 1000-1350°C. Weight loss data was compared with predictions of the model. A mixed 2-stage mechanism comprised of pore diffusion plus boundary layer gas transfer was shown to generally control the oxidation rate. Pore diffusion was however more effective, especially at graphite contents lower than 10 wt pct under forced convection blowing of the air. Model calculations showed that effective gas diffusion coefficients were in the range... 

The most challenging requirement for depositing NiTi-based shape memory thin films is the control of film composition because a small deviation can strongly shift the transformation temperatures. This article presents a technique to control film composition via adjustment of the power supplied to the targets during simultaneous sputter deposition from separate Ni, Ti, and X (e.g., Hf) targets. After optimization of sputter parameters such as working gas pressure, target-substrate distance, and target power ratio, binary Ni100-x Tix thin films were fabricated and characterized by energy dispersive x-ray spectroscopy in a scanning electron microscope (to measure the film composition and... 

Visibility graph of a simple polygon in a plain is a graph in which the number of its vertices corresponds with the number of vertices in the polygon and each of its edges corresponds with a pair of visible vertices in the polygon. Visibility graph reconstruction of a polygon is one of the old and important problems in computational geometry for which no algorithm has been offered yet. Considering that the problem of visibility graph reconstruction of a pseudo-triangle has been solved, we present an O(n2)-time algorithm for pseudo-triangulation of a simple polygon, using the visibility graph corresponding with the polygon (n is number of vertices of the polygon). To do so, first we present a... 

Multi-walled carbon nanotubes (MWCNTs) with diameter of about 50 nm were synthesized using thermal chemical vapor deposition. We have investigated the influence of Mg doping to the MWCNTs on its hydrogen storage property. TEM micrographs showed that Mg was attached to the MWCNTs and discontinuous arrangement of the carbon walls was recognized in the MWCNTs. According to XPS and BET analyses, the surface functional groups and pore size of the Mg-MWCNTs are increased by interactions between the Mg and the MWCNT's outer walls. The electrochemical discharging curves of the MWCNTs and Mg-doped MWCNTs revealed that the hydrogen storage capacity was 363 and 450 mAhg -1, respectively. Volumetric... 

Using multi-walled carbon nanotubes (MWCNTs), the present study focuses on their electrochemical hydrogen storage capacities. The results showed that the hydrogen desorption process is composed of two steps with voltages around -0.75 and -0.15 V. Hydrogen adsorption at -0.15 V took place at temperatures above 30 °C, and the amount of energy required for adsorbing hydrogen was 1.68 eV. The hydrogen storage capacity increased with increasing electrolyte temperature from 30 to 60 °C in both steps. The hydrogen storage capacity of the MWCNTs treated at different atmospheres showed that the decrease in the graphitization of MWCNTs led to the increase in hydrogen adsorption. The results also... 

The effects of HCl, HNO3, H2SO4 and HF acids on the purification and the electrochemical hydrogen storage of multi-walled carbon nanotubes (MWCNTs) were studied. The MWCNTs were synthesized on Fe-Ni catalyst by thermal chemical vapor deposition method. The X-ray diffraction and thermal gravimetric analysis results indicated that the MWCNTs purified by HF acid had the highest impurities as compared with the other acids. The N2 adsorption results at 77 K indicated that all the samples were mainly mesoporous and the purified MWCNTs by HF acid had the highest surface area as compared with the other acids. The hydrogen storage capacities of the purified MWCNTs by the following acids were in... 

Fabrication of organohalide perovskite materials on the top of ZnO nanoparticles (NPs) has some beneficial advantages such as room temperature processing; however, the perovskite is not stable on ZnO NPs layer during the annealing process. In fact, there are only a few reports about the fabrication of perovskite solar cells on ZnO NPs layer. Herein, the decomposition mechanism of CH3NH3PbI3 perovskite materials on ZnO is reported, and it is found that the perovskite film on the top of the ZnO layer is converted into PbI2 during the annealing process due to the existence of hydroxide groups on the surface of the ZnO NPs. Depending on the annealing temperature, the reaction rate and the... 

A technique that expands dynamic range (DR) of frequency down-converters in the C band frequency is presented. Primary characteristics of down-converter are evaluated to confirm that it can be used in microwave receivers. The C band down-converter is carried out by the combination of RF mixers, band pass interdigital filter, and X band combline filter which are designed entirely for this project. Attainment of the perfect receiver is the final purpose of this paper, and a method that causes 72 dB dynamic range, high tangential signal sensitivity and fine gain flatness is used for achieving the mentioned purpose. These efforts improve the dynamic range about 19 dB and gain flatness about 3.07... 

The aeroelastic design of composite wings modeled as thin-walled beams is investigated through the use of curvilinear fiber. The structural model considers non-classical effects such as transverse shear, warping restraint, rotary inertia, nonuniform torsional model and also aerodynamic loads based on Wagner's function. In this paper, a linear spanwise variation of the fiber orientation resulting in a variable-stiffness structure is used to optimize the wing for maximum aeroelastic instability speed purpose, while manufacturing constraints are incorporated. Numerical results indicate improvements of aeroelastic stability of variable-stiffness wings over conventional, constant-stiffness ones  

In this study the ability of Acidithiobacillus ferrooxi-dans, with regard to the biorecovery of heavy metals in shake flask has been investigated. Adaptation experiments with the single metal ions Ni, Co, V, Mo, W and a mixture of the first four metal ions in the medium was developed through serial sub-culturing. Adaptation showed that A. ferrooxidans could tolerate up to 2.3 g/l Ni, 1.4 g/l Co, 1.4 g/l V, 0.045 g/l Mo and 0.005 g/l W, singly. In the presence of multi-metals considering a mixture of Ni-Co-V-Mo, the bacteria was able to tolerate up to 1.5 g/l Ni, 0.8 g/l Co, 0.8 g/l V and 0.05 g/l Mo in steps of 50-100 mg/l for Ni, Co and V, while for Mo and W with increments in concentration... 

A novel method based on microextraction in packed syringe (MEPS), as a sample preparation technique in combination with gas chromatography-mass spectrometry (GC-MS) was developed using a polypyrrole (PPy) nanowires network as the extracting medium. The PPy nanowires network was prepared using a soft template technique and its characterization was studied by scanning electron microscopy (SEM). The use of micelles in this methodology has an important role in the shape of the growing polymer. The pyrrole monomer was introduced into cetyltrimethylammonium bromide (CTAB) micelles and this has led to the formation of nanowires with diameters ranging from 30 to 60 nm. The bulk PPy prepared without... 

Geotextiles are one of the most widely used synthetic materials in filtration and drainage applications. Since in real applications, geotextiles are subjected to various hydraulic gradients and confining stresses, hydraulic behavior of geotextiles under different circumstances is of great practical importance. In this study filtration and drainage properties of several nonwoven needle-punched geotextiles with different properties and unit mass per area of 200g/m2, 400g/m2, 500g/m2 and 800g/m2, under various confining stresses and hydraulic gradients, were studied using standard permittivity and transmissivity equipments. Prepared samples were subjected to hydraulic heads in the range of 10cm... 

In order to evaluate dynamic properties of Babolsar and Toyoura sands at saturation levels of 25, 50, 75 & 100%, a series of cyclic simple shear tests were carried out. The SGI type cyclic simple shear device was used to study the shear modulus, G, and damping ratio, D, of the above mentioned sands at cyclic shear strain of 0.5, 5 & 10%. The effect of degree of saturation (S), vertical consolidation stress (σ vc) and number of loading cycles (N) were investigated. On the basis of the tests results, the shear modulus approximately remains constant by change of degree of saturation from 25 to 50% and decreases when reaches the degree of saturation 75%. Damping ratio approximately is constant... 

In this paper we describe a method for finding polynomial invariants under stochastic local operations and classical communication (SLOCC) for a system of delocalized fermions shared between different parties, with global particle-number conservation as the only constraint. These invariants can be used to construct entanglement measures for different types of entanglement in such a system. It is shown that the invariants, and the measures constructed from them, take a nonzero value only if the state of the system allows for the observation of Bell-nonlocal correlations. Invariants of this kind are constructed for systems of two and three spin-12 fermions and examples of maximally entangled... 

A novel cellulose supported copper NHC complex has been prepared by the reaction of cellulose supported imidazolium salt with copper(i) iodide. The catalyst is active in the synthesis of 1,2,3-triazoles via a one-pot reaction of alkyl/benzyl halides or tosylates and terminal alkynes, with sodium azide in water  

Supply chain sustainability, with economic, environmental, and social values, has gained attention in both academia and industry. For deteriorating and seasonal products, like fresh produce, the issues of timely supply and disposal of the deteriorated products are of great concern. This paper is to develop a possibilistic mathematical model, solved after linearizing the non-linear statements, and to propose a new replenishment policy for a centralized Sustainable Supply Chain (SSC) for deteriorating items. Different transportation vehicle options, which produce various pollution and greenhouse gas (GHG) levels, are considered. Several variables such as the end-customer demand, the partial... 

In this paper, we report on 2D numerical simulation of spectral response for InGaN dual-band photodetector operating at near ultraviolet and visible wavelengths. The back-to-back p–i–n/n–i–p integrated structure enables independent and simultaneous detection of two bands under back-side illumination. The effect of indium content and absorption layer thickness of the two sub-detectors on external quantum efficiency and optical crosstalk between two sub-detectors have been investigated. The optimum values for indium content and thickness of absorption layer in sub-detectors are determined  

In classical analysis, every compact subset of ℝ is Lebesgue measurable, but it is not true in constructive analysis. In this paper, we prove that the statement 'every compact set K in a locally compact space X is integrable with respect to a positive measure μ' is equivalent to LPO, over Bishop's constructive analysis. We also prove that the existence of a compact subset of ℝ which is not Lebesgue integrable is equivalent to the schema ED, which asserts that 'there exists an intuitionistically enumerable subset of ℕ which is not intuitionistically decidable'. Moreover, classically, every open subset of ℝ is Lebesgue measurable, but it is not true constructively. We show that Lebesgue... 

The schema ED asserts that 'there exists an intuitionistically enumerable subset of N which is not intuitionistically decidable.' In this article, we prove that in the presence of Markov's Principle over Bishop's constructive analysis, ¬ED is equivalent to the principle of open induction on [0,1], via Specker sequences. © 2016. Oxford University Press. All rights reserved  

Crosstalk faults occurring in wires of Networks on Chip (NoCs) can seriously threaten the reliability of data transfer. One efficient way to tackle crosstalk faults is numeral-based Crosstalk Avoidance Codes (CACs). Numeral-based CACs reduce crosstalk faults by preventing specific transition patterns to occur. One-Lambda Codes (OLCs) are the most efficient types of CACs. However, the codec of OLCs imposes overheads including power consumption, critical path and area occupation to the routers of NoCs. To find overhead-efficient OLCs, this paper proposes an Algorithm for Generating OLC Numeral systems (AGON). AGON provides a tradeoff for designers in selecting overhead-efficient OLCs. Using...