Sharif Digital Repository

The purpose of this study is fabrication and characterization of a mesoporous Perovskite solar cell using Barium Titanate as the mesoporous electron transfer layer. In this study, TiO2 nanoparticles and BaTiO3 oxide perovskites were prepared by sol-gel synthesis method and their pastes were applied to the conductive substrate by spin coating method and applied to electron transfer layer in perovskite solar cells. Then Perovskite solar cells were fabricated with different structures from the electron transfer layer.The results of X-ray diffraction analysis showed that pure Barium Titanate and Titanium dioxide nanoparticles were successfully synthesized with tetragonal and cubic crystal... 

Quince seed gum is a natural material that was used in Iranian traditional medicine for wound treatment. Alginate is a beneficial biomaterial that has been used in making commercial wound dressings for a long time. In this work, the preparation method and properties of films based on Alginate and Quince seed gum for drug delivery and wound healing have been investigated. According to the obtained results about crosslinking and plasticizing, the suitable condition of synthesis is 0.5% CaCl2 concentration, 2min soaking time, and 13% glycerol in crosslinking solution. In this crosslinking solution, a film with good mechanical properties (tensile strength: 13MPa, elongation: 27.3%, and Young’s... 

In this research, wear behaviors of 6061Al and 6061Al-20 vol% SiC composite -prepared by powder metallurgy method- were investigated in the temperature range 25- 200°C. Dry sliding wear tests were conducted at a constant sliding velocity of 0.34 m/s, an applied load of 20 N and 50N, and a sliding distance of 2450m using a pin-on-disc machine test. Some of the wear tests were carried out with artificially aged specimens in order to determine the aging effects on wear rate of composite. Worn surfaces and wear debris were also examined by using SEM and EDS techniques. Also for determining the effect of age hardening treatment on wear behavior of composite, specimens were solution treated at... 

In this project, Dissimilar Friction Stir Welding (FSW) between aluminum alloys (1100-H12 and 5083-O) and Magnesium alloy (AZ31B-O) with 3mm thickness were butt joined. Fusion welding of aluminum/magnesium alloys has failed because of forming much more intermetallic compounds. By using friction stir welded samples, effect of welding parameters such as tool travel speed, tool rotation rate, tool position respect to weld centerline, and sheet position respect to tool direction on mechanical (tensile strength, yield strength and elongation) and microstructural properties of the welds were investigated. After several tests, range of optimum parameters were obtained. In both 1100 and 5083 alloys,... 

Perovskite solar cells, with high efficiency operation, have been candidated as a cost-effective and environmentally friendly technology. Despite the great progress, there are some primarily issues remained regarding to the perovskite film and its fabrication methods. A very common perovskite cell structure is FTO/TiO2/CH3NH3PbI3/Spiro-OMeTAD/Au. Although, this structure has some advantages, lack of full surface coverage of perovskite film leads researchers to put much effort on finding other constructions. This surface inhomogeneity reduces the amount of light absorption and therefore efficiency. One way to produce a complete and uniform film is applying mixed-halide composition; such as... 

The primary purpose of the present thesis is to understand the dynamic behavior of partially premixed flames of counterflow burners. In this project, work has been done on the previously designed and built counterflow burner. By setting up partially premixed flames in this burner, acoustic excitation of these flames has been done, and finally data acquisition by taking video of the flame and then using image processing to extract the dynamic response of these flames. The flames that we have examined in this project are all in a laminar regime and the fuel used in these flames is also natural gas. The frequencies that we have examined in these flames are 25 and 40 Hz, and these tests were... 

In the present work, the local Chemiluminescence method has been implemented on a laminar premixed propane-air flame. The goal of this work is to achieve a system capable of measuring the intensity of Chemiluminescent radiations of CH* and OH* radicals locally and with high spatial and temporal accuracy. For this purpose, a setup has been designed and developed. In order to achieve high spatial accuracy for local measurements, a Cassegrain lens has been designed and built, which has the ability to collect light from a cylindrical control volume with a cross-sectional diameter of 58 μm and a depth of 3.4 mm. An optical system for dividing and filtering light based on wavelength has also been... 

In this study, growth of MWCNTs in form of thin film and powder for hydrogen storage was investigated. Different analytical techniques including SEM, TEM, STA, XRD, XPS, BET, BJH and Raman spectroscopy were applied to characterize the samples. The results showed that substrate, catalyst thickness and type of catalyst are influenced in yield of the growth, structure and quality of MWCNTs. The study has also indicated that MWCNTs grown on Fe-Pd bimetallic catalyst with 25-75 proportion had the highest growth yield. Moreover, decreasing of the growth temperature from 970 to 920 oC produced single-walled carbon nanotubes (SWCNTs) with high quality (IG/ID = 15.8) and low growth yield.... 

The propagation behavior of Love wave in functionally graded magneto-electro-elastic half-spaces with a quadratic variation is addressed. The magneto-electromechanical coupling factor, the dispersion relations, electric potential, magnetic potential and displacement are obtained analytically for both magneto-electrically open and short conditions. The effect of gradient coefficient on phase velocity, group velocity and magneto-electromechanical coupling factor are plotted and discussed. Research on the wave propagation in magneto-electro-elastic materials is still very limited. This work provides us with a theoretical foundation to design and practically apply SAW devices with high... 

In the proton exchange membrane fuel cells (PEM, the produced water would be divided into two phases of vapor and liquid. distribution of both liquid and vapor phases in different cell layers affects the performance, the efficiency and the life of a fuel cell significantly. Moreover, Nano pores of the cathode catalyst layer are involved with some phenomena such as electrochemical reaction kinetics, heat and mass transfer and interface phase change. One of the most important problems in the performance of fuel cells is distribution of liquid water in the porous areas. Water flooding in fuel cells causes to delay in oxygen transport to active sites in the catalyst layer because the pores of... 

In this study, the interaction between thin plate completely bonded to the transversely isotropic halfspace and a concentrated force applied horizontally (Mindlin-type force) are considered. This problem has been solved analytically. This problem is used as sample for thin solid films and surface coating technology, where the surface of solid is covered by thethin plate for increasing its stiffness. Moreover, this problem is a good sample when homogenous solid is subjected to contact loading and can be seen that mechanical properties of material which is near the solid surface varies; consequently, a two-phase solid is created.Because of the influence of noted inhomogeneity, solid is... 

Hydrodynamics plays a crucial role in defining the performance of fluidized beds. The numerical simulation of fluidized bed is very important in the prediction of its behaviour. From this point of view, in the present study a dynamic two dimensioanl model is developed for the modeling of regenerator system of a UOP fluid catalytic cracking (FCC) unit of Abadan refinery with a high-efficiency regenerator. Of the various modeling and simulation techniques, computational fluid dynamics (CFD) is employed in this thesis. Effects of gas velocity, the transient local solid volume fraction, pressure drop for gas and solid phase, solid holdup distribution and solid circulation pattern have been... 

Nowadays large volume of sensitive data of organizations are stored in the databases. Thus, databases are attractive to the attackers to execute different types of attacks with different purposes. The useful information that attackers try to achieve in the preliminary steps of the attacks against the databases, is the database structure or schema. One of the popular approach to extract the schema of a database is to analyze the returned error messages from its DBMS. Hence, a solution to prevent schema disclosure via the error messages is customizing and modifying them. To achieve this goal, in this thesis, we propose a framework to handle and customize the error messages automatically and...