Sharif Digital Repository

Theoretical study of NH3(H2O) n=0,1,2,3 adsorption on (8, 0) carbon nanotube was performed at the X3LYP/6-31G* level of density functional theory (DFT). The tube-NH3 interaction was discussed in the terms of binding energy (EB), coupling energy (EC), charge density, molecular orbitals, and dipole moments. The results reveal that addition of water molecules to tube-NH3 system increases the interaction between tube and ammonia molecule  

In this paper, a novel steganographic method is proposed which is based on the spatial domain: Least Significant Bit (LSB). The LSB matching method proposed by Mielikainen utilizes a binary function to reduce the number of changed pixel values. While in this paper a bipolar evaluating system is proposed to assess the performance of different orders for LSB matching. Afterward a genetic algorithm strategy is employed to search for an optimal solution among all the permutation orders. The experimental results show that by employing the proposed bipolar evaluating system, the distortion of the stego-image is reduced while the probability of detection is decreased  

Predicting the effective elastic properties of carbon nanotube-reinforced nanocomposites is of great interest to many structural designers and engineers for improving material and configuration design in recent years. In this paper, a finite element model of a CNT composite has been developed using the Representative volume element (RVE) to evaluate the effective material properties of nanocomposites. Based on this model, the effects of geometrical characteristics such as the aspect ratio, orientation and volume fraction of the CNTs in conjunction with the interphase behavior on the mechanical properties of the nanocomposites are elucidated and the elastic properties of a complex polymeric... 

Concepts developed in the gravitational lensing techniques such as shear, convergence, tangential, and radial arcs maybe used to see how tenable inhomogeneous models proposed to explain the acceleration of the universe models are. We study the widely discussed Lemaitre-Tolman-Bondi (LTB) cosmological models. It turns out that for the observer sitting at origin of a global LTB solution the shear vanishes as in the Friedmann-Robertson-Walker models, while the value of convergence is different, which may lead to observable cosmological effects. We also consider Swiss-cheese models proposed recently based on LTB with an observer sitting in the Friedmann-Robertson-Walker part. It turns out that... 

We used a method to evaluate angular accuracy for air showers direction recorded by a pentagon array of scintillation detectors. This is achieved by using the coincidences between the air showers recorded by the two sub-arrays. Also, using the CORSIKA code the angular precision of this array and the effect of inherent error on it is obtained at different energies of the primary particles and at different zenith angles. © 2020 Elsevier B.V  

The seismic behavior of stainless-steel built-up box columns subjected to constant axial loads and cyclic lateral deformation that are used in special moment frames (SMFs) has been investigated through finite element (FE) analysis. A total of 208 numerical models were conducted to cover a range of parameters affecting the seismic behavior of the columns. These include the web slenderness ratio, flange slenderness ratio, global slenderness ratio, axial load level, and lateral loading protocol. The performance indices of overstrength factor, axial shortening, out-of-plane deformation, plastic hinge length, and rotation capacity were calculated and compared. Local buckling of the columns also... 

An efficient and one-pot synthesis of thiopyrano[2,3-b]indole derivatives via Hetero Diels-Alder reaction of α,β-Unsaturated thio-oxindoles with electron poor acetylenes and Cyclic Dienophiles is described. In the proposed method the reaction is performed under neutral and one-pot reaction conditions, and also the substances can be mixed without any activation or modification and without using any catalysts  

A novel heterogeneous copper catalyst was synthesized in which poly(1-vinyl imidazole-co-ionic liquid) was used as a solid heterogeneous support. The catalyst was readily synthesized in a large scale amount. The catalyst has a high loading level of copper ions and can be used in low weight percentages. The resulting catalyst was highly active in the preparation of triazoles by the Huisgen 1,3-dipolar cycloaddition method. In some cases the catalytic turnover number and frequency reached 70 002 and 3889 h-1, respectively. The catalyst was recycled many times without significant loss of activity. This journal is  

Supported gold(III) on poly(ionic liquid) coated on magnetic nanoparticles produced a highly active, stable, recoverable and high loading for the synthesis of propargylamines (A3 coupling reaction) under green conditions. The reaction of aldehyde, secondary amine and alkyne were followed in aqueous media. The catalyst was characterized by TEM, TGA, AAS, FT-IR, XRD and EDX. A broad diversity of aldehydes, secondary amines, and alkynes, and a good to excellent yield of corresponding propargylamines were synthesized using 1.0% Au. The catalyst was easily recovered and reused 10 times without significant loss of activity  

A new one-pot synthesis of thieno[2,3-b]indole ring systems is described. Condensation of cyclohexyl isocyanide with indolin-2-thiones yielded 3-cyclohexyaminomethylene-indolin-2-thiones, which upon reaction with α-halocarbonyl compounds produced the title compounds. © Georg Thieme Verlag Stuttgart  

Ultrasonic waves have been extensively used in many industrial applications including clean devices, pipes and vessels. A clear extension of this usage is the removal of wellbore contaminants by exposing it to high-power ultrasonic waves. In this paper, a mathematical model for ultrasonic propagation through the porous medium around the wellbore is presented. The equations of wave propagation are written in a cylindrical coordinate according to Biot theory and the induced stress in the rock are calculated at each point using finite difference approach Comparison of imposed local stresses with adhesion forces between scales and rock, the properties of ultrasonic transducer, such as frequency... 

In this paper, to set R&D priorities at sector level, a developed method is proposed which is combined of scenario planning and critical technologies method and then applied for prioritizing R&D issues of membrane technology in National Iranian Gas Company (NIGC). In the first phase (through 3 steps), scope of NIGC is mapped using national documents and viewpoints of experts and managers. This map includes main process of gas processing and gas conversions. Then strategic goals of gas industry including gas exports, conversions, injection and internal use, are developed. Also Strategic Technology Units (STUs) are identified and twenty distinct membrane technologies including technologies of... 

Aryl and alkyl isocyanates have been efficiently converted into symmetrical trisubstituted aryl and alkyl isocyanurates, catalyzed by sodium p-toluenesulfinate on its own or in the presence of tetrabutylammonium iodide (TBAI), in a solvent-free condition. The latter has been shown to have a higher catalytic activity  

In this research, multi-walled carbon nanotubes (MWCNTs) were modified by dendritic macromonomer. Herein, polyamidoamine with acrylamide end groups was incorporated on MWCNTs. Afterwards, poly(N-isopropylacrylamide), (PNIPAM), was grafted on polyamidoamine in a facile synthesis. Then, doxorubicin as anticancer drug was loaded on this nanocarrier. The drug release was studied at below and above the lower critical solution temperature of PNIPAM, (LCST 32 °C), 27 °C and 37 °C, respectively. At 37 °C (body temperature) the polymer shell dehydrated and the drug release increased. The profile of drug release was expressed by Higuchi's equation which indicated that the drug release mechanism was... 

In the past, decision making within the energy sector, especially in Iran, was limited to economic analysis. Lately, multiple criteria decision making has gained great popularity. However, this is not enough to make a right decision by considering sustainability. This paper deals with designing an appropriate multiple criteria decision making method to address the multifaceted nature of such problems. This task is the second precondition to make a decision which meets the sustainability criterion. This is done by revealing new facts about quantitative and qualitative data and the degree of compensation between the criteria. Moreover, this paper illustrates the capability of different methods... 

In this paper, we introduce a new cost function for SIR-Based uplink power control algorithms that takes into account transmission power level as well as target Signal-to-Interference Ratio (SIR) deviation. Existence of Nash equilibrium point, its uniqueness and the algorithm convergence are proved in the framework of so-called standard power control schemes. As shown through simulations, the proposed method results in significant transmit power reduction while achieving almost the same average SIR level. In addition, it is shown that the new scheme results in improved overall network fairness in comparison with another algorithm  

This paper presents the results of an experimental study on the application of strapping technique for retrofit of concrete compressive specimens. In this technique, standard strapping devices, which are used in the packaging industry, are applied to post-tension high strength metal strips around the concrete columns. Experimental program included axial compressive tests on 72 cylindrical and prismatic compressive specimens, which were actively confined by pre-stressed metal strips. The effects of various parameters on strength and ductility of confined concrete were studied including compressive strength of concrete, mechanical volumetric ratio of confining strips, post-tensioning force in... 

The dynamic nature of today’s manufacturing industry, which is caused by the intense global competition and constant technological advancements, requires systems that are highly adaptive and responsive to demand fluctuations. Reconfigurable manufacturing systems (RMS) enable such responsiveness through their main characteristics. This paper addresses the problem of RMS configuration design, where the demand of a single product varies throughout its production life cycle, and the system configuration must change accordingly to satisfy the required demand with minimum cost. A two-phased method is developed to handle the primary system configuration design and the necessary system... 

Herein, we report the impact of single- and co-doping of nanoparticle TiO2 films with carbon and nitrogen on the photovoltaic characteristics of their corresponding dye-sensitized solar cell (DSC) devices. Different DSCs with various compositions of the photoanode electrodes are fabricated to study their structural and electronic properties by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), field-emission scanning electron microscopy (FE-SEM), Brunauer-Emmett-Teller (BET) analysis and X-ray photoelectron spectroscopy (XPS). We find that the interstitial nitrogen atoms for single N doping have a greater impact on the band gap energy (Eg) than the substitutional (to Ti) carbon... 

The dynamic nature of today’s manufacturing industry, which is caused by the intense global competition and constant technological advancements, requires systems that are highly adaptive and responsive to demand fluctuations. Reconfigurable manufacturing systems (RMS) enable such responsiveness through their main characteristics. This paper addresses the problem of RMS configuration design, where the demand of a single product varies throughout its production life cycle, and the system configuration must change accordingly to satisfy the required demand with minimum cost. A two-phased method is developed to handle the primary system configuration design and the necessary system...