Sharif Digital Repository

Due to environmental and economical impacts, recovery of the uranium from nuclear wastes is of continuing interest.This work reports the separation of uranyl ionusing transport technique through chloroform liquid membrane containing a mixture of DBDA15C4 and oleic acidas cooperative carrier.The pH of the feed phase (10-4 M of UO22+) was adjusted with nitric acid and acetic acid/NaOH for pHrange of 2-6.The receiving phase was hydrochloric acid 1M.The organic phase was chloroform which includesthe carrier DBDA15C4 (0.0001 M) and also the oleic acid (0.015M).The results showed that the transport increased with increasing pH and reached to maximumat pH of 5.Maximum cooperative effect of oleic... 

High speed machining is becoming a progressive trend in machining processes. The main part of a high speed machine tool is its spindle. The purpose of this thesis is to design and manufcture a high speed spindle for milling machine that can rotate at speed of 16000 rpm. This spindle can be used as a test bed for experimental parametric study on the effects of spindle design parameters on the performance of spindle bearings. Various components of the spindle is studied and designed. High speed angular contact bearings and roller bearings are used in the spindle to provide high precision as well as good thermal performance. The spindle is built and tested for high precision machining with... 

Micromilling is one of the promising micromanufacturing processes used for creating 3D complex micro-scale features such as those used in MEMS devices. The mechanism of chip formation in this technique is different from that in conventional machining, because the size effects due to hardening behavior of microstructures at micro-scales and also the crystallographic orientation of a workpiece texture affects the mechanical behavior where a severe plastic deformation occurs in an induced shear band in front of the tool edge. In the present thesis, micromachining process is investigated by considering these effects. In order to capture the effects of size scale during high speed and large... 

Along with the proliferation of pervasive systems such as RFID systems and sensor networks, the demand for the low-cost, secure-enough primitives has continued to rise. Symmetric-key algorithms especially block ciphers still play an important role as secure ciphers that can be also consistent with the inherent restrictions of pervasive systems. Recently, a lot of block ciphers tailored for these conditions have been designed, such as Present, PrintCipher, Piccolo, and Twine. Biclique attack introduced in AsiaCrypt 2011 is the first and the only method that could break all versions of AES faster than brute-force attack in the single key model. Afterwards, the efficiency of this attack on some... 

Due to the ever-increasing growth of the ubiquitous computing systems such as RFID, IoT, etc. and their important security concerns specially in the domain of user’s privacy, a great attention from the cryptology community is attracted to the design and analysis of lightweight primitives. Lightweight primitives, including block ciphers, hash functions, stream ciphers, and authenticated encryption schemes, are those ones that are specifically tailored to the devices with extreme limitations in power, area and cost. It is natural that the conventional rules for designing a typical all-purpose primitive can not be used here identically, and designers have to relax the conditions of some... 

Gantry milling machines are one of the types of machine tools that have vast application in various industries. Considering requirements such as quality and roughness of work pieces which are becoming restricted day after day, it is necessary that various parts of this machine have sufficient functionality and precision so that it can fulfill the quality requirements; and production of these expensive machines be cost-effective. One of the most important parts of a gantry milling machines is its crossbeam that undergoes deflections when exposed to applied forces during work conditions and can have undesirable effect on work piece precision. Therefore, the goal of this research is to design... 

In metal matrix composites, the metal is reinforced with ceramic particles to get appropriate properties for hardness, resistance to fatigue, wear resistance and strength. Aluminum matrix composites have lower density than steels. These kinds of materials are used in military, automotive and aerospace industries due to their high strength to weight ratio and resistance to corrosion and wear. Application development of these materials are limited due to high machining and production costs. High ductility and strength of these materials and also hardness of ceramic particles cause rapid wear of tools and higher roughness of the surface. In this project the effect of ultrasonic vibration of a... 

The goal of authenticated encryption is to ensure confidentiality, integrity and authenti-cation of the messages simultaneously. The anouncement of CAESAR comptetition has attracted esearchers’ attention to this branch of symmetric cryptography, since 2014. 57 schemes have been introduced as the first round candidates of this competition, from which 29 where selected as second round candidates. Cryptanalysis of these schemes needs a lot of collective effort. In this thesis after describing preliminaries of authen- ticated encryption, general structure of the schemes and their reported cryptanalysis is reviewed. Then, the details of Pr∅st family of authenticated encryption, which is one of... 

With regards to the development of modern power systems, Smart Grid (SG) as an intelligent generation of electricity networks has been faced with a tremendous attention. Fine-grained data sharing in SG plays a vital role in efficiently managing data flow in the SG. As this data commonly contains sensitive information, design of the secure and efficient privacy preserving schemes for such networks with plenty of resource constrained devices is one of the most controversial issues. In this paper, we propose a Secure Ciphertext-Policy Attribute-Based SignCryption (CP-ABSC) scheme which simultaneously provides the authenticity and privacy of the users by enforcing an arbitrary access control... 

In this work, a virtualized ball-end milling model is presented in Unity game engine environment, in which the machining process is simulated by proposing a new geometric approach. The model calculates and illustrates cutter-workpiece engagement area and cutting forces in a real-time manner. To calculate cutter-workpiece engagement, the workpiece’s top surface is considered a set of nodes. Then, using a new geometric method, the engagement area is calculated at any node on the engaging surface. Utilizing the calculated engagement area and adopting mechanistic force model, the cutting forces applied from each node on the workpiece surface to the tool’s cutting edge are calculated. The cutting... 

In recent years, metallic nanoparticles, specially gold and silver nanoparticles, have received great attention for biological and metal ions analysis, due to the surface plasmon resonance phenomena. Gold nanoparticles (AuNPs) have recently gained much interest in colorimetric probe based on aggregation or anti-aggregation of AuNPs, due to their simplicity and having high order of magnitude extinction coefficients, in addition to the dependence of surface plasmon resonance wavelength and intensity on the interparticles distances. In the first part of this thesis, a highly sensitive colorimetric method for detection of copper ions based on anti-aggregation of citrate capped AuNPs was... 

Exoskeletons, or wearable robots, are electromechanical devices that have become the focus of academic and industrial research in recent years, and their applications in power augmentation have increased. One of the most important challenges of these applications is controlling the robot and synchronizing it with the user. The close interaction of the robot with the user and the change of movement pattern between different users and different gait cycles show the importance of estimating the user's movement intention, but the need for online method of estimating the movement intention and the complexity of accurate dynamic modeling has caused researchers to use reinforcement learning (RL) in... 

Laminar-to-turbulent transition is very important concept in fluid dynamics due to its significant role on skin friction drag and heat transfer. It is more important in the fluid-based systems such as wind turbines. Employing computational fluid dynamics is still not efficient on prediction of flow transition, especially in complex problems such as oscillating airfoils. In one hand, flow transition models are not still suitable for general engineering flows such as oscillating airfoils. On other hand, due to the lack of experimental data, the existing flow solvers have not proven in the accurate simulation of the flow field simulation for complex problems such as oscillating airfoils. This... 

Machining chatter is unstable and destructive vibrations that leads to damages to the surface of workpiece and reduces the tool life. These damages have significant effects on surface quality and material removal rate. Many studies have been done on chatter modeling and control in various machining processes. On the other hand, recently, ultrasonic vibrations have been used in many manufacturing processes including cutting to enhance the quality of products. Therefore, it is important to investigate the effect of ultrasonic vibrations on the stability of cutting process. Although a number of advantages such as improved surface roughness of workpiece and reduced machining forces have been... 

In Ultrasonic Assisted Machining (UAM) a mechanical vibration is added to the relative motion of the tool and workpiece. The frequency of vibration is typically from 20kHz to 100kHz and the amplitude is in the range of 10 to 20 microns. Experiments show that using this method improves the machining performance. Reduction in machining forces and tool wear and improving the cooling condition are some of the advantages of UAM. In this work, the forces of ultrasonic assisted milling are investigated. Applying thin shear plane theorem provides an acceptable theoretical base with minimum dependence on experimental data to analyze machining forces. To evaluate the model and find the effect of... 

Regenerative chatter is a self-exited vibration that causes poor surface finish, tool wear and breakage and excessive noise. It is, therefore, essential to avoid chatter occurrence passively by selecting cutting conditions that guarantee the stability of the process, or detect and suppress chatter at its onset during the process. The latter has become more important due to the complex and nonlinear dynamics of metal removal and the rising interest in automated systems. Wavelet and Hilbert-Huang transforms are used to detect chatter in machining processes including milling and surface grinding, in this thesis. In the first part of the thesis, chatter detection in milling is studied. The... 

In this thesis, desublimation (deposition) of xenon gas has been studied. Through the past decades, desublimation, became one of the important methods of separation. High purity products and applicability when common methods of separation, as distillation, are not applicable, make desublimation more efficient. Heat transfer phenomenological study of direct phase change of gas to solid (desublimation), evaluation of variation of different parameters during the phase change and finally comparison of experimental results of desublimation and mathematical modeling data are the main considerations in present thesis. Because of low cost and accessibility and heat transfer phenomenological study... 

In some applications in the field of information technology such as social networks and medical databases in different hospitals, sometimes an entity needs to calculate the extent of its sharing of information documents with other institutions. Access to one entity's information is not possible due to the confidentiality of users' information. Therefore, in order to calculate common documents, users should be able to do so without revealing their private information. Therefore, it is required protocols such that can only obtain the shared information between two mentioned entities, while preserving the confidentiality of uncommon information. The schemes that meet the above objectives are... 

The internet of things is a network of interconnected things (people, electronic devices, mechanical machines, etc.) that are able to transfer data. The applications of internet of things in electronic health (eHealth) are becoming increasingly interested. Deployment of eHealth facilitates the access of users to healthcare services, and improves the quality of the services. Using cloud computing provides the accessibility of healthcare services, and enables a data owner to share his health data with doctors and healthcare service providers. Health data is considered sensitive. So, leakage of any information about it endangers data owner privacy. Attribute-based encryption is a cryptographic... 

Thermal penetration is one of the separation methods. In this process, due to the temperature difference, the concentration gradient in one of the gas or liquid phases in the resulting system and the relative separation of the components is possible. The column used for this work is the Classius-Dickel column. This column consists of two vertical plates, one warm and the other cold, spaced a short distance apart. Due to the temperature gradient, the gradient is deliberately created, which creates a concentration gradient in the column, so that the light component accumulates at the top of the column and the heavy component at the bottom of the column. The difference in concentration between...