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Performance of polypropylene fiber reinforced concrete-filled UPVC tube columns under axial compression
, Article Construction and Building Materials ; Volume 231 , 20 January , 2020 ; Khaloo, A ; Borhani, M. H ; Tale Masoule, M. S ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
This paper aims to study the behavior of UPVC-confined columns reinforced with polypropylene fibers under axial compression. A sum of 42 column specimens has been tested, including 18 Unconfined Concrete Cylinders (UCC) and 24 confined Concrete-Filled UPVC Tube (CFUT) specimens. To investigate the sensitivity of these columns to various parameters, different levels of material volumes have been used, which include two concrete strengths of 40 and 50 MPa, two tube grades of PN6 and PN10, and three polypropylene fiber content of 0, 1 and 3 kg/m3 of the concrete mixture. The influence of each variable on the ultimate strength, ductility and confinement effectiveness of the specimens have been...
Efficient carrier utilization induced by conductive polypyrrole additives in organic-inorganic halide perovskite solar cells
, Article Solar Energy ; Volume 207 , 2020 , Pages 1300-1307 ; Balkan, T ; Solati, N ; Halali, M ; Askari, M ; Kaya, S ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
The morphology of the perovskite layer, the effective extraction of the charge carriers, and their transport are the main factors determining the power conversion efficiency (PCE) of the perovskite solar cells (PSCs). In this work, we demonstrated that the geometric and electronic structures of the PSCs could be modified by using a conductive polymer additive in the lead (Pb) halide layer prepared by a two-step deposition method. Polypyrrole (PPy) as a conductive polymer is used in the perovskite layers which could increase the PCE of CH3NH3PbI3-xClx mixed-halide PSCs. By adding an optimized amount of PPy, PCE has been raised from 10.4 to 13.2%. PPy acts as a conductive channel facilitating...
Modeling and simulation of flow and uranium isotopes separation in gas centrifuges using implicit coupled density-based solver in OpenFOAM
, Article European Journal of Computational Mechanics ; Volume 29, Issue 1 , 2020 , Pages 1-26 ; Salehi, A. A ; Keshtkar, A. R ; Shadman, M. M ; Askari, M. H ; Sharif University of Technology
River Publishers
2020
Abstract
The performance of a gas centrifuge that is used for isotopes separation is dependent on the gas flow inside it. In this study, for modeling the UF6 gas flow, an Implicit Coupled Density-Based (ICDB) solver, was developed in OpenFOAM. To validate the ICDB solver, the gas flow within the rotor in total reflux state was compared with the analytical solution obtained by Onsager model and the numerical solution obtained by the Fluent software. The results showed that the ICDB solver had acceptable accuracy and validity. Also the computational efficiency of Roe, AUSM (Advection Upstream Splitting Method) and AUSM+ up schemes were compared. The results showed AUSM+ up scheme is efficient. Then,...
Mechanically activated synthesis of single crystalline MgO nanostructures
, Article Journal of Alloys and Compounds ; Volume 506, Issue 2 , September , 2010 , Pages 715-720 ; 09258388 (ISSN) ; Yoozbashizadeh, H ; Askari, M ; Kobatake, H ; Fukuyama, H ; Sharif University of Technology
2010
Abstract
One-dimensional (1D) MgO structures were successfully synthesized via carbothermic reduction of mechanically activated mixture of MgO and graphite. Mechanical activation of source materials before carbothermic reduction can substantially enhance the formation of MgO products at a temperature (1000 °C) relatively lower than that required in previous approaches (≥1200 °C). However, the morphology of MgO formed is dependent on the degree of mechanical activation and the condition of the subsequent carbothermic reduction. Two distinctive morphologies were found for MgO products synthesized using our method: single crystalline nanorods with rectangular cross-sections whose diameters range from 50...
Self-organized titanium oxide nanotubes prepared in phosphate electrolytes: Effect of voltage and fluorine concentration
, Article ECS Transactions, 25 April 2010 through 30 April 2010 ; Volume 28, Issue 7 , April , 2010 , Pages 67-74 ; 19385862 (ISSN) ; 9781607681830 (ISBN) ; Dolati, A ; Goodarzi, M ; Askari, M ; Ghahramaninezhad, A ; ECS All Divisions ; Sharif University of Technology
2010
Abstract
TiO2 a nanotube array was prepared using an anodization process. The process proceeded in a two-electrode cell containing of platinum sheet as the cathode electrode. Two phosphate-base electrolyte solutions containing different amounts of HF and NH4F were prepared. Different concentration of fluorine ions were examined in respected electrolytes. Current transient techniques were used to produce the TiO2 nanotubes at constant voltage of 18-25V. It was revealed that anodization at 18-22V, in so-called electrolytes would end up to nano-tubular structure. However the tubular structure prepared at 20V and from phosphate electrolyte containing of 0.5 wt% NH4F as well as 0.5 wt% HF, was recognized...
Feasibility and Performance Analysis of a Thermoacoustic Heat Pump
, M.Sc. Thesis Sharif University of Technology ; Ghorbanian, Kaveh (Supervisor)
Abstract
Thermoacoustics deals with the conversion of heat energy into sound energy and vice versa. This new and emerging technology has a strong potential towards the development of sustainable and renewable energy systems by utilizing waste heat or solar energy. Although thermoacoustic devices are simple to fabricate; however, the design process is very challenging. The thermoacoustic phenomenon is discovered over a century ago; nevertheless, the rapid advancement in this field occurred during the past three decades when the theoretical understanding of the phenomenon is developed along with the prototype devices. There are several advantages of heat engines and refrigerators based on...
Study on Nucleation and Growth of Titanium Dioxide Nano Particles via Gel-Sol Method
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
Nanotechnology is an efficient method suitable for fabrication and production of minimal single dimensional nanometric structures. Such materials and systems can be logically designed that lead to new and optimized biological, chemical and physical properties and characteristics due to their size. Nucleation and growth –appearance of a new phase out of an old phase – is a ubiquitous phenomenon in nature. Fundamental understanding of nanoparticles nucleation and growth mechanism allows more control on form, size and composition and allows tuning of the above said properties easily with use of different reactive conditions as a result of this ability . Nanoparticles of titania are one of...
Optimized Fabrication of Spinel Nanao Powder Mn1.5Co1.5O4 Through Sol-Gel Method Applicable to Solid Oxid Fuel Cell
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
Nowadays, too much attention has been paid to Solid Oxide Fuel Cells (SOFC). One of the key components in SOFC is interconnect which plays an important role in SOFC performance. Interconnect can be either a metallic or ceramic layer that sits between each individual cell. The reduction in operating temperature of SOFC resulted in interests in using metallic interconnectors. However, the oxidation of these metallic materials is big challenge. Chromium (Cr), Nickel (Ni) and Iron (Fe) alloys have been employed to overcome this deficiency. However, these alloys bring another difficulty which is the presence of active elements such as Cr which reduces the performance of interconnects by forming...
Fabrication of Silicon Nanowires with various Silicon Substrates and Investigation of the structural Properties and their Behavior
,
M.Sc. Thesis
Sharif University of Technology
;
Askari, Masoud
(Supervisor)
Abstract
In this thesis, Silicon nanowires were synthesized using carbothermal method via Vapor-Liquid-Solid mechanism catalyzed by gold nanoparticles deposited on various substrates. Silicon nanowires just grew on (100) and (111)-oriented silicon substrates. For a particular set of process parameters, we observed a critical thickness of the nucleating gold film, that had depened on a kind of various substrates. We studied the dependence of the Au-Si alloy droplet size and size distribution on the starting gold film thickness and the annealing conditions. We used a modified heating sequence that deconvoluted the effect of various substrates consumption and gas-phase silicon supply on the Au-Si alloy...
Iron Removal from Copper Electrowinning Procces
, M.Sc. Thesis Sharif University of Technology ; Askari, Masood (Supervisor)
Abstract
Iron is a common impurity in copper minerals. The presence of iron in hydrometallurgical copper PLS causes continuous reactions between Fe(II) and Fe(III) ions. In order to improve energy efficiency and product quality iron removal shall be done. In this study separation of iron from Sarcheshme copper leaching liquor containing 6 g/L Fe, was conducted by solvent extraction using D2EHPA in kerosene. Chloric acid solution was used to strip the loaded iron from organic phase. Results of extraction experiments designed by taguchi method showed 92.49% iron recovery and 2.44% copper extraction under optimum condition. Using same method for stripping experiments, it was found that variation of time...
Low Temperature Metallic Foams
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
Metal foams are considered as a group of new materials and are applied widely in various areas due to their particular properties such as low density, high strength-to-weight ratio and appropriate mechanical, thermal, physical, electrical and magnetic properties. The aim of the present study is acquiring the technical knowledge of Zinc foam production by melting route and also optimizing the effective parameters on the foam stability. For this reason, 4 Zinc foams were produced at different times and temperatures. The amount of Calcium as the melt fluidity reducing agent and Titanium hydride and Zinc carbonate as the blowing agent were the same in all the specimens. The effect of heat...
Influence of Cobalt and Vanadium Dopants on the Performance of TiO2(B) Nanowires used as anode Materials in Lithium-ion Batteries
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
Li-ion batteries have been widely applied as power sources for portable electronic devices. Recently, Li-ion batteries are considered as the most promising energy storage technology for electric vehicle applications however, fundamental improvements are needed. TiO2 (B) is attractive candidate for anodes in rechargeable Li-ion batteries, due to their low cost, non-toxicity and favorable channel structure for fast lithium mobility. It is predicted that synthesis of doped nanostructure of this material, through reducing the diffusion pathway and formation of crystal defects, will increase the capacity of TiO2(B). In this investigation, Co and V doped TiO2(B) nanowires are synthesized by...
Copper Selective Leaching from Sarcheshmeh Reverberatory Furnace Dusts
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
In this study, leaching of Sarcheshmeh Reverberatory Furnace Dust was investigated in the H2SO4-O3 media. Response surface methodology based on central composite face-centered design (RSM-CCF), was applied to optimize the operating parameters. The optimum conditions to obtain the main goal of maximum copper and minimum iron dissolution from dust were identified to be temperature of 30˚C, leaching time of 3hr, initial pH of 0.5, pulp density of 20% and ozone flow rate of 1g/h. The copper and iron concentrations of leaching solution were found to be 27.11 and 0.89983 g/L under the optimum conditions, respectively. The results showed that selective copper extraction from the dust could be...
Solid State Reduction of Iran Titanomagnetites to Extract TiO2 & Fe
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
Titanomagnetites are resources of iron and titanium. high level of titanium in titanomagnetites makes using them in iron making processes very difficult. In this work an attempt was made to produce an iron bearing and a titanium bearing product using solid state reduction of Fanouj mine titanomagnetite concentrate. For this purpose, the concentrate was reduced using coal and then was subjected to magnetic separation. In this work, effect of temperature, time, added coal amount, and additive amount on reduction was studied. The result showed that the optimum conditions are 1325 celsius degree, 2.5 hours, 25 percent added coal and 2 percent additive. In optimum conditions a magnetic product...
Study the Effect of Carbon Content Exist in Midrex Cold Briquetted Sponge Iron on Melting Performance and Comparison with DRI and HBI
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
Midrex sponge iron is an active product and there are several problems with store and export it.Cold briquetting sponge iron method is a new method to protect sponge iron from oxidation and provides the possibility of its storage and transportation. Iran as one of the biggest countries that produce sponge iron, has a lot of sponge iron pilots that equipped with cold briquetted machines,but their production capacity is limited and is about 5 percent of their production capacity. With regard to no need for country to these amount of sponge iron, most of these pilots have to store and transport large volumes of sponge iron and the risk of oxidation and fire threatens these units.By using cold...
Leaching of Titanium-bearing Concentrate of Solid-state Reduction of Titanomagnetite Ores
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
Some of the low-grade titanium resources which are located in the country are titanomagnetite placer deposits. In current study, beneficiation of titanium-bearing concentrate of a placer deposit containing 6.13wt.% TiO2 was investigated by acidic leaching in order to remove impurities. To beneficiate the concentrate, based on the optimum conditions obtained in previous studies, solid-state reduction, magnetic separation, and calcination of non-magnetic product were performed. Afterwards, by studying temperature, time, acid concentration and L:S ratio, the final product was leached under optimal conditions were as follows: H2SO4 concentration of 15wt.%, L:S ratio of 20:1 (mL:g), reaction...
Lithium Extraction with TiO2 Nanotube Synthesized by Anodizing Method
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
Due to the technology advancement and the large-scale application of lithium-ion batteries in recent years, the market demand for lithium is growing rapidly and the availability of land lithium resources is decreasing significantly. As such, the focus of lithium extraction technologies has shifted to water lithium resources involving salt-lake brines and sea water. The ion exchange process is a promising method for lithium extraction from brine and seawater having low concentrations of this element. Among various aqueous recovery technologies, the lithium ion-sieve (LIS) technology is considered the most promising one. This is because LISs are excellent adsorbents with high lithium uptake...
TiO2 Production by Acid Leaching of Upgraded Titanium Slag
, M.Sc. Thesis Sharif University of Technology ; Askari, Masoud (Supervisor)
Abstract
In Iran, titanium dioxide is still not produced and imports of titanium dioxide are required by various industries, including dyeing, electrodeposition, plastics and Therefore, according to the Ministry of Industries and Mines objectives, to obtain the technology of extraction Ti and TiO2, a research was carried out on titanomagnetite concentrate, extracted from the minerals of the plancher titanumitent and low-grade kahnoj. In this research, titanium dioxide is produced by sulfate method. Solid state recovery and magnetic separation were used to isolate titanium and iron. The dissolution process was then performed to achieve maximum dissolution. At this stage, the effects of temperature,...
Modeling of Epistemic Uncertainties in Seismic Hazard Analysis Based on Reliability Methods
, M.Sc. Thesis Sharif University of Technology ; Mahsouli, Mojtaba (Supervisor)
Abstract
The primary objective of this thesis is comprehensive treatment of epistemic uncertainties in probabilistic seismic hazard analysis based on structural reliability methods. The classical methods of probabilistic seismic hazard analysis, i.e., PSHA, traditionally consider a limited number of uncertainties. The ones that they do consider comprise the aleatory uncertainty in the magnitude, the distance, and the residuals of ground motion prediction equations and the epistemic uncertainty in the intensity measures predicted by different such equations. However, there are many sources of epistemic uncertainty that, according to past studies, have a significant impact on the upper tail of the...
Automatic Author Age Identification Using Social Media Texts
, M.Sc. Thesis Sharif University of Technology ; Bahrani, Mohammad (Supervisor)
Abstract
The most common form of communication on the internet and social network websites is text messages. normally communication on social media or even on the web is by posting some sort of text. usually, these messages or posts are short and text used in them may not follow any language standards, this makes it very difficult to process them. Different age groups use a certain language differently and this is shown in the way, each of them writes texts. The advancements made in the field of natural language processing and computational linguistics makes it possible to predict, text authors age groups by analyzing the way they write. This study focuses on ways to automatically recognize the age...