Sharif Digital Repository

The anatase phase of titania was stabilised with physically modifying particulate sol-gel process. Two major parameters, peptisation temperature and drying temperature, were identified which were responsible for retarding the anatase to rutile phase transformation, crystal growth and packing of primary particles. The critical nucleus size of transformation was controlled by natural (at 25 °C) and artificial (at 50 and 70 °C) peptisation techniques. Moreover, sintering of primary particles was controlled by cool (at 0 and 5 °C) and normal (at 25 °C) drying techniques. Fourier transform infrared spectroscopy (FT-IR) analysis confirmed that a full conversion of titanium isopropoxide is obtained... 

We study Hydrogen sulfide gas detection properties of pure and 1% copper oxide added WO3 thin films. The spin coated deposits on alumina substrates were annealed at 500 C for 1 hour in order to improve the crystallinity of the films. The sensitivity of pure tungsten oxide is poor even at temperatures of about 100 C but the doped samples exhibit good response to H2S gas. Our data show sensitivity of about 1500 in 10 ppm diluted gas in air at 100 C. The films are sensitive to the gas even at 250 ppb (sensitivity about 2) H2S concentration at 100 C but with rather long recovery time. Crystal structure, morphology and chemical composition of samples were studied by X-Ray diffraction (XRD),... 

Mixing in droplets is an essential task in a variety of microfluidic systems. Inspired by electrokinetic mixing, electric field-induced hydrodynamic flow inside a charged droplet embedded in an unbounded polyelectrolyte hydrogel is investigated theoretically. In this study, the polyelectrolyte hydrogel is modeled as a soft, and electrically charged porous solid saturated with a salted Newtonian fluid, and the droplet is considered an incompressible Newtonian fluid. The droplet-hydrogel interface is modeled as a surface, which is located at the plane of shear, with the electrostatic potential ζ. The fluid inside the droplet attains a finite velocity owing to hydrodynamic coupling with the... 

The electric-field induced response of a droplet embedded in a quenched polyelectrolyte gel is calculated theoretically. The response comprises the droplet translation and the electric-field induced flow fields within the droplet. The gel is modeled as a soft, and electrically charged porous solid saturated with a salted Newtonian fluid. The droplet is considered an incompressible Newtonian fluid with no free charge. An analytical solution, using the perturbation methodology and linear superposition, is obtained for the leading-order steady response to a DC electric-field. The fluid within the droplet is driven due to hydrodynamic coupling with the electroosmotic flow. The fluid velocity... 

Characterization of droplet-hydrogel interfaces is of crucial importance to engineer droplet-hydrogel composites for a variety of applications. In order to develop electrokinetic diagnostic tools for probing droplet-hydrogel interfaces, the displacement of a charged droplet embedded in a polyelectrolyte hydrogel exposed to an oscillating electric field is determined theoretically. The polyelectrolyte hydrogel is modeled as an incompressible, charged, porous, and elastic solid saturated with a salted Newtonian fluid. The droplet is considered an incompressible Newtonian fluid with no charges within the droplet. The droplet-hydrogel interface is modeled as a surface with the thickness of zero... 

Determination of effective transport properties of droplet-hydrogel composites is essential for various applications. The transport of ions through a droplet-hydrogel composite subjected to an electric field is theoretically studied as an initial step toward quantifying the effective transport properties of droplet-hydrogel composites. A three-phase electrokinetic model is used to derive the microscale characteristics of the polyelectrolyte hydrogel, and the droplet is considered an incompressible Newtonian fluid. The droplet-hydrogel interface is modeled as a surface, which encloses the interior fluid. The surface has the thickness of zero and the electrostatic potential ζ. Standard... 

Nanostructured and mesoporous TiO2-Ta2O5 films and powders with various TiO2:Ta2O5 molar ratios and high specific surface area (SSA) have been prepared by a straightforward particulate sol-gel route. Titanium isopropoxide and tantalum ethoxide were used as precursors and hydroxypropyl cellulose (HPC) was used as a polymeric fugitive agent (PFA) in order to increase the SSA. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) revealed that powders contained both hexagonal δ-Ta2O5 and monoclinic β-Ta2O5 phases, as well as anatase and rutile. It was observed that Ta2O5 retarded anatase-to-rutile transformation. Furthermore, δ → β phase transformation temperature increased... 

The original article contained a mistake in Equation 1. The corrected Equation 1 is shown below: MX+Cx+Kx=f.The original article has been updated © Springer Nature B.V. 2022  

For the present article, a pulsating heat pipe (PHP) is fabricated and tested experimentally by bending a copper tube. The effects of working fluid, heat input, charging ratio, inclination angle, magnets location, and ferrofluid (magnetic nanofluid) volumetric concentration have been investigated on the thermal performance of this PHP. Experimental results show that using ferrofluid as a working fluid improves the thermal performance of the PHP significantly. Moreover, applying a magnetic field on a ferrofluidic PHP reduces its thermal resistance. By changing the inclination angle of the PHP from vertical mode to angles close to the horizontal mode, the present PHP has a constant and... 

Nanostructured TiO2-Al2O3 films and powders were prepared by a straightforward aqueous particulate sol-gel route. Titanium (IV) isopropoxide and aluminum chloride were used as precursors, and hydroxypropyl cellulose was used as a polymeric fugitive agent in order to increase the porosity. The effect of Al:Ti molar ratio was studied on the crystallization behavior of the products. X-ray diffraction (XRD) revealed that the powders crystallized at 800°C, containing anatase-TiO2, rutile-TiO2 and cubic-Al2O3 phases. Furthermore, it was found that Al2O3 retarded the anatase to rutile transformation. Transmission electron microscope (TEM) image showed that one of the smallest crystallite sizes was... 

Analyzing the features of the chromosomes can be very useful for diagnosis of many genetic disorders or prediction of the possible abnormalities that may occur in the future generations. For this purpose, karyotype is often used which to make it, there is necessary to identify each one of the 24 chromosomes from the microscopic images. Definition and extraction of the morphological and band pattern based features for each chromosome is the first step to identify them. An important class of the morphological features is the location of the chromosome's centromere. Thus, centromere localization is an initial step in designing an automatic karyotyping system. In this paper, a novel algorithm... 

This study presents optimal placement of Phasor Measurement Units (PMUs) for the purpose of power system observability using topology based formulated algorithms. The optimal PMU placement problem is formulated to minimize the number of PMUs installation subject to full network observability. The Branch and Bound (B and B) and genetic algorithm optimization methods are selected to solve the problem, which are suitable for problems with integer and Boolean variables. Topology-based algorithm used for observability analysis and a hybrid method of topology transformation and nonlinear constraint is used to form constraints. The IEEE 14, 30, 57 and 118-bus and the New England 39-bus test systems... 

In this paper, the truly Meshless Local Petrov-Galerkin (MLPG) method is extended for computation of steady incompressible flows, governed by the Navier-Stokes equations (NSE), in vorticity-stream function formulation. The present method is a truly meshless method based on only a number of randomly located nodes. The formulation is based on two equations including stream function Poisson equation and vorticity advection-dispersion-reaction equation (ADRE). The meshless method is based on a local weighted residual method with the Heaviside step function and quartic spline as the test functions respectively over a local subdomain. Radial basis functions (RBF) interpolation is employed in shape... 

An analytic expression for energy and angular dependence of a secondary charged lepton in the decay of a polarized top quark with anomalous tWb couplings in the presence of all anomalous couplings are derived. The angular distribution of the b-quark is derived as well. It is presented that the charged lepton spin correlation coefficient is not very sensitive to the anomalous couplings. However, the b-quark spin correlation coefficient is sensitive to anomalous couplings and could be used as a powerful tool in the search for non-SM coupling. © 2007 IOP Publishing Ltd  

In this paper we study the noncommutative effects to the lepton spectrum from the decay of a polarized top quark. It is shown that the lowest contribution comes from the quadratic terms of the noncommutative parameter. The deviations from the standard model are significant for small values of the noncommutative characteristic scale. However, the charged lepton spin correlation coefficient has a remarkable deviation from the standard model from very low values of the noncommutative characteristic scale to 1 TeV. © 2006 The American Physical Society  

In this paper, the truly Meshless Local Petrov-Galerkin (MLPG) method is extended for computation of unsteady incompressible flows, governed by the Navier-Stokes equations (NSE), in vorticity-stream function formulation. The present method is a truly meshless method based only on a number of randomly located nodes. The formulation is based on two equations including stream function Poisson equation and vorticity advection-dispersion-reaction eq. (ADRE). The meshless method is based on a local weighted residual method with the Heaviside step function and quartic spline as the test functions respectively over a local subdomain. Moving Least Square approximation (MLS) is employed in shape...