Sharif Digital Repository

Hydroxyapatite is the most important bio ceramic, due to its structure and chemical composition which is similar to bone. Since feeble fracture toughness, brittleness and low tensile strength have restricted their use, for overcoming this problem, they were often used as a secondary component. HAp-Al2O3 nano-composite powder combined the benefits of biocompatibility of HAp and high strength of Al2O3. When HAp-Al2O3 nano-composite powders were sintered at a higher temperature than 1100- 1200°C, HAp was decomposed and converted to the second phase of TCP, due to the formation of calcium aluminate increasing decomposition speed of HAp to TCP at higher degree than 1100-1200°C temperatures;... 

Ternary mesoporous nanocomposites of RGO/Fe3O4-ZnO were prepared successfully via hydrothermal technique. Fe3O4-ZnO core/shell nanoparticles were decorated on the surface of reduced graphene oxide platelet to improve charge separation efficiency and magnetic properties. The phase, microstructure and specific surface area of the prepared samples were determined via X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy/selected area electron diffraction (TEM/SAED) and Brunauer–Emmett–Teller (BET) techniques. A vibrating sample magnetometer (VSM) was used for recording the magnetization hysteresis curves. The methylene blue (MB)... 

In the present study, SiC samples with 3, 5, 7.5 and 10 wt% Al2O3–Y2O3 as additives were made by powder metallurgy method, then sintering was performed by microwave-assisted process. β–SiC samples sintering was performed for 100 min. The highest sintered relative density 91.06% was achieved at 10 wt% additives content. The maximum values of hardness and toughness were up to 23.3 GPa and 6.14 MPa.m− 1/2. α–SiC and α–SiC/β–SiC samples sintering was performed for 120 min. The maximum value of density and hardness were up to 96.38% T.D and 24.88 GPa in α–SiC with 7.5 wt% additives, whereas the highest toughness was achieved at 10 wt% additives content in β–SiC samples. The α–SiC samples... 

The original version of this article unfortunately contained a mistake. The presentation of Eq. 1,2, and 3 was incorrect.The correct versions are given below. The original article has been corrected. (Formula Presented.) (1) (Formula Presented.) (2) (Formula Presented.) (3). © 2018, Springer-Verlag GmbH Germany, part of Springer Nature  

In this study, PZT-PCN ceramic was made via sol–gel seeding method and effects of conventional sintering (CS) as well as two-step sintering (TSS) were investigated on microstructure, phase formation, density, dielectric and piezoelectric properties. First, high quality powder was achieved by seeding method in which the mixture of Co3O4 and Nb2O5 powder was added to the prepared PZT sol to form PZT-PCN gel. After drying and calcination, pyrochlore free PZT-PCN powder was synthesized. Second, CS and TSS were applied to achieve dense ceramic. The optimum temperature used for 2 h of conventional sintering was obtained at 1150 °C; finally, undesired ZrO2 phase formed in CS procedure was removed... 

SrFe12-xTix/2Zn x/2O19 (x = 0-2.5) powders were synthesized by use of chlorides through co-precipitation method. The obtained powders were then milled by high energy ball mill to crash hard agglomerates and achieve nanoparticles. In order to evaluate microwave absorption versus frequency, composites including ferrite, as a filler, and matrix of polyvinylchloride (PVC) with weight ratio of 70% ferrite were prepared. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), vibrating sample magnetometer (VSM) and vector network analyzer (VNA) were employed to study the structural, magnetic and microwave absorption properties... 

The possible interactions near the triple-phase boundaries (TPB) metal/glass/air, and their effects on joint strength are investigated. Two types of samples (joined couples and glass coated coupons) are prepared with the coupon of AISI 430 (nickel plated and uncoated) and a slurry of compliant silicate sealing glass (SCN-1). The joined and coated samples are heated at 850 °C for 1000 h in air. The joined couples are cooled using two different schedules and then tested in uniaxial tension. For investigating the metal-oxides precipitation procedure in glass near the TPB, glass coated coupons are either cooled at the rate of 5 °C min−1 or water-quenched from aging temperature. The mechanical... 

Strontium hexaferrites with the composition of SrFe12−xTix/2Znx/2O19 (x = 0–2.5 in steps of 0.5) were synthesized using chlorides by means of co-precipitation route. The structural, magnetic and microwave absorption properties of the samples were surveyed. The results confirmed that the magnetoplumbite single phase was obtained for all samples and the hexagonal particles dispersed within size range of 1–2 µm. With increasing amount of dopant, coercivity decreased from 5640 to 1486 Oe while the maximum saturation magnetization was 63 emu/g and belonged to x = 0.5. The reflection loss results denoted that the prepared composites had excellent microwave absorption properties and the maximum... 

Bismuth ferrite, BiFeO 3, is almost the only material that is simultaneously magnetic and a strong ferroelectric at room temperature. As a result it is the most investigated multiferroic material. In this study, bismuth ferrite thin films were deposited on silicon wafer (100) and glass by pulsed-laser deposition and their structural, optical, and electrical properties were measured. Our study indicates that Bi richness in these films can stimulate formation of oxygen vacancy in the system which in its turn leads to delocalization of carriers and a more intensified photoconductivity response. X-ray diffraction analysis revealed formation of BiFeO 3 (BFO), but it also showed formation of Bi 2O... 

Barium strontium titanate (BST, Ba1-xSrxTiO3) thin films have been extensively used in many dielectric devices such as dynamic random access memories (DRAMs). To optimize its characteristics, a microstructural control is essential. In this paper, Ba0.6Sr0.4TiO3 thin film has been deposited on the SiO2/Si substrate by the pulsed laser deposition (PLD) technique at three different oxygen working pressures of 100, 220 and 350 mTorr. Then the deposited thin films at 100 mTorr oxygen pressure were annealed for 50 min in oxygen ambient at three different temperatures: 650, 720 and 800°C. The effect of oxygen working pressure during laser ablation and thermal treatment on the films was investigated... 

Ceramic-matrix composites containing TiC-TiN have been used in a variety of application because of their superior properties such as high hardness, good wear resistance and high chemical stability. In this research, effect of coke and coke/calcium beds in synthesis of Al2O3-Ti(C, N) composites using alumino-carbothermic reduction ofTiO2 has been investigated. Al, TiO2 and active carbon with additives of extra carbon and NaCl and without additives, in separate procedures, have been mixed. Afterwards, mixtures were pressed and synthesized in 1200°C for 4hrs, in coke and coke/calcium beds, separately. Al2O3-Ti(C,N) composite was synthesized in ternary system of Al-TiO2-C with excess carbon and... 

Inclusion of carbon nanotubes (CNTs) into the titanium dioxide coating on 1050 aluminium alloy was studied with the aim at enhancing the corrosion resistance of the surface. Composite coatings with various contents of CNTs were prepared via the sol-gel method and dip coating. XRD and FTIR phase and structural evaluations showed the presence of anatase phase in all thin films. Concomitant enhanced corrosion behaviour in the presence of CNTs was resulted from polarization potentiodynamic test. Band-gap evaluation was performed using absorbance spectra of coatings and showed considerable decrease of band-gap energy in the presence of CNTs. Photocatalytic properties and hydrophilicity of... 

A new method for guiding the motion of fullerene and fullerene-based nanocars is introduced in this paper. The effects of non-flat substrates on the motion of C60, a nanocar and a nanotruck are investigated at different conditions and temperatures. Their behavior is studied using two different approaches: analyzing the variation in potential energy and conducting all-atom classical molecular dynamics simulations. This paper proposes that the use of a stepped substrate will make their motion more predictable and controllable. The results of the simulations show that C60 stays on the top side of the step and cannot jump over the step at temperatures of 400 K and lower. However, at temperatures... 

Fluorine-doped tin oxide (FTO) nano-powders were synthesized by a gel combustion method. To analyse the effect of processing factors and their interactions and to achieve an equation for nano-powder particle size in terms of code factors, D-optimal factorial design was used. Stannous chloride penta-hydride, ammonium fluoride and citric acid were used to synthesize the FTO nano-powders. The structure, morphology and composition of the synthesized powders were characterized by X-ray diffraction, field emission scanning electron microscopy and X-ray photoelectron spectroscopy, respectively. The results revealed the formation of homogenous FTO nano-powders with an average particle size of 20 nm... 

The rotational and translational motions of nanocars and nanotrucks as well as their motion regimes at different temperatures are investigated. In recent years, few similar types of molecular machines have been simulated. In contrast to previous studies, which have used the Rigid-Body Molecular Dynamics (RBMD) method, an all-atom model and classic atomistic dynamics have been employed in this paper to achieve better accuracy. Our results demonstrated that the exibility of the chassis and its attachment to the gold surface played an important role in the motion of a nanocar. In fact, a heavier and more exible nanocar chassis reduces its speed compared to a nanotruck. In addition, the results... 

In the present work, G-TiO2 and G-ODA-TiO2 hybrids were prepared by concurrent surface functionalization and reducing of graphene oxide (GO) using octadecylamine (ODA). The G-TiO2 and G-ODA-TiO2 powders were deposited on the copper surface by electrophoretic deposition (EPD) technique. The wettability of coatings revealed the preferable hydrophobic characteristic of G-ODA-TiO2 compared to G-TiO2 and bare copper with water contact angles of 130°, 101°, and 87°, respectively. The anti-corrosion performance of specimens in a 0.5 M H2SO4 solution was appraised by the potentiodynamic polarization (Tafel analysis), which clearly showed that G-TiO2 and G-ODA-TiO2 coatings can act as a great barrier... 

In this study the effects of HfB2 addition were investigated on the sintering behavior, densification and microstructure of ZrB2-SiC in the presence of B4C and MoSi2 as a sintering catalyst. 5, 10, 15 and 20 wt% of HfB2 was substituted with ZrB2 in ultra-high temperature ceramic composites of ZrB2-SiC. Additionally, the effect of using nano-scale against common micron size SiC was compared. All compositions were sintered for 1 h in 2100 °C and 2150 °C. Relative and bulk density and open porosity percentage of samples were calculated by Archimedes method. Dimensional changes of pellets and their weight reduction after pyrolysis and sintering proved that increasing of HfB2 leads to increasing... 

In this study, magnesium boro/carbothermal reduction of zirconium silicate (ZrSiO4) was employed to synthesize zirconium-based composite nanopowders of ZrB2–SiC, ZrB2–ZrC–SiC, ZrC–SiC, and ZrC. For this aim, three different temperatures of 1200 °C, 1300 °C, and 1450 °C were selected as the supposed temperatures for synthesis. Elemental Mg and NaCl were also selected to assist reduction process. In addition, effects of different C/Zr ratios as well as using elemental boron and B4C as two different boron sources were investigated on the final produced phases. Subsequently, XRD and SEM/EDS analyses were carried out to elaborate microstructure and phase studies. Finally, STA carried out up to... 

Pb(Zr 0.52Ti 0.48)O 3 (PZT) nanotubes with diameters of 80-100 nm and a wall thickness of 15-20 nm were prepared by sol-gel template technique and using multi-walled carbon nanotubes (MWCNT) as sacrificial templates. The coating process of MWCNT with PZT precursor sol and removal of the carbon nanotubes by an interrupt heat treatment were discussed and studied by Raman spectroscopy. Simultaneous thermal analysis (STA) revealed that PZT nanotube crystallized at the low temperature of 410°C by the significantly low activation energy of crystallization of 103.7 kJ/mol. Moreover, based on the X-ray diffraction (XRD) pattern and selected area electron diffraction pattern the crystal structure of... 

Thin films of titanium dioxide with high surface area are prepared by sol-gel dip-coating technique. In this regards, Titania nano sols with high photocatalytic activity were prepared by dissolving titanium alkoxide in alcohol and water under acidic conditions. Photocatalytic activities of titanium dioxide thin films were measured in the presence of methylene blue. Microstructure and photocatalytic activity of the films, nanopowders and titanium dioxide sols were investigated using X-ray diffraction, scanning electron microscopy, specific surface area, zeta sizer and ultraviolet-visible spectrometry techniques. Particle size analysis of sols showed that the mean particle sizes were 15 to 128...