Sharif Digital Repository

The surface defluorination of Teflon in powdery form was performed using a chemical treatment. The reaction parameters including the reaction time, sodium, naphthalene concentrations were optimized using a Taguchi method to obtain maximum functionality on the particles surface. The surface functionality of the treated particles was analyzed by FTIR, energy dispersive X-ray analysis (EDX) and surface energy. Both treated (g-PTFE) and untreated (PTFE) Teflon were added to polyamide 66 (PA66) at various loadings up to 6 wt%. Mechanical, differential scanning calorimetry (DSC) and tribological analyses for different PA66/Teflon composites were carried out. The chemical treatment enhanced the... 

Effect of organoclay (OC) on the performance of styrene-butadiene rubber (SBR)/phenolic resin (PH) blend prepared by two-roll mill was investigated. The influence of OC content ranging between 2.5 and 30 phr on the performance of SBR/PH was investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), interfacial energy analysis, tensile, dynamic mechanical, swelling, cure rheometry and thermogravimetric analysis (TGA). It was found that the OC is mainly localized in the SBR phase of SBR/PH blend through the kinetically favored mechanism relevant to rubber chains. The results also demonstrated the positive role of PH on the dispersion of OC. Both PH and OC showed... 

The present study deals with the structure-property relationship of organoclay (OC) filled nanocomposites based on rubber blend comprising of nitrile-butadiene rubber (NBR) and phenolic resin (PH). To obtain a better insight into the characteristics of the NBR/PH/OC hybrid system, a simple model system consisting of NBR/OC nanocomposites is also taken into consideration. A series of NBR/OC and NBR/PH/OC nanocomposites containing a wide range of OC concentrations (2.5-30 phr) are prepared by using traditional open two-roll mill. Structural analysis performed by X-ray diffraction (XRD), scanning electron microscope (SEM), and transmission electron microscope (TEM) exhibits mixed exfoliated and... 

Various compositions of maleated ethylene-propylene-rubber (EPR-g-MA) toughened polyamide 6 without and with short glass fiber, i.e. 5-20 wt.% rubber and 5-20 wt.% fiber, are prepared using an industrial twin-screw extruder at different levels of feed rate (100-250 kg/h), screw speed (200-450 rpm) and barrel temperature (230-260 °C). Trial runs designed based on the Taguchi's orthogonal arrays are subjected to tensile, impact, scanning electron microscopy (SEM) and optical microscopy tests; and the results are used to perform the analysis of variance (ANOVA). It is shown that the rubber particle size decreases significantly by increasing the rubber content for the unreinforced blend. The... 

In the present article, cure kinetics of a commercially available composite friction material used in railroad vehicles is investigated using the rheometer measurements. Effect of ingredients of friction material compound, including rubber matrix, phenolic resin, and fillers, on overall cure kinetics of friction compound is also investigated by comparing the cure kinetics of friction material and rubber matrix compound. A phenomenological model and an Arrhenius-type equation is developed for cure kinetics and induction time of both friction material and rubber matrix. The parameters of the models are extracted from experimental data, using the rheometer at different temperatures and... 

Sedimentation of particles can undermine the uniformity of the product in the manufacture of the particle-filled composites. An adequate mathematical description of the sedimentation process could be helpful for providing necessary information concerning the dominant parameters and can give an insight for the process designer to prevent such an undesirable phenomenon in composite production. The present article deals with the mathematical modeling of settling particles during curing of polymer matrix composites. The sedimentation process is described by the mass conservation law for particles. Since the viscosity of the suspending polymer increases as a result of curing process, a new model... 

In the present article, the cure process of the railroad composite friction materials in the compression molding process is studied. Numerical simulation is used to analyze the process and a series of parametric studies are performed to reveal the effect of process parameters and material variables. The results show that the cure process and also the braking performance are governed by the thermophysical properties of the friction compound formulation, which are in tum dominated by the compound ingredients. It is suggested that such information can be used in designing of compound formulation to achieve a friction material with good frictional and processing properties  

The petroleum industry tends to paint an optimistic picture with respect to future petroleum availability. In order to anticipate demand, the size of connected volume of hydrocarbon of fields needs to be known. During the early stage of life of a reservoir, due to the lake of certain data, connected volume of hydrocarbon is usually based on analogues or rules of thumb and not detailed reservoir modeling. Therefore, there is a great incentive to produce physically-based methodologies to make an estimation of connected volume of hydrocarbon. Percolation theory is used to estimate the connected volume of hydrocarbon very fast. Furthermore, the result has been validated against areal field... 

Reservoir characterization, especially during early stages of reservoir life, is very uncertain, due to the scarcity of data. Reservoir connectivity and permeability evaluation is of great importance in reservoir characterization. The conventional approach to addressing this is computationally very expensive and time consuming. Therefore, there is a great incentive to produce much simpler alternative methods. In this paper, we use a statistical approach called the percolation theory, which considers a hypothesis wherein the reservoir can be split into either permeable (i.e. sand/fracture) or impermeable flow units (i.e. shale/matrix), and assumes that the connectivity of permeability... 

The connectivity of high conductivity pathways in geological formations depend on the spatial distribution of geological heterogeneities that may appear on various length scales. Appropriate modeling of this is crucial within in hydrology and petroleum systems. The approach taken in this study is to use percolation theory to quantify the connectivity, hydraulic conductivity, and breakthrough time behavior between an injector and a producer within such systems. In particular, a three-dimensional overlapping sandbody model is considered which assumes that the geological formation can be split into either conductive flow units (i. e., good sands) or non-conductive units (i. e., poor sands). The... 

Oil reservoirs are very complex with geological heterogeneities that appear on all scales. Proper modeling of the spatial distribution of these heterogeneities is crucial, affecting all aspects of flow and, consequently, the reservoir performance. Reservoir connectivity and conductivity evaluation is of great importance for decision-making on various possible development scenarios including infill drilling projects. This can be addressed by using the percolation theory approach. This statistical approach considers a hypothesis that the reservoir can be split into either permeable (good sands) or impermeable flow units (poor sands) and assumes that the continuity of permeability contrasts...