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    Theoretical and Experimental Modeling of Vortex Engine in Ramjet Application

    , M.Sc. Thesis Sharif University of Technology Besharat Shafiei, Somayeh (Author) ; Ghafourian, Akbar (Supervisor) ; Saeedi, Mohsen (Supervisor) ; Mozaffari, Ali Asghar (Supervisor)
    Abstract
    Heat transfer to combustion chamber walls is an unwanted phenomenon. Reduction of this heat transfer by using bidirectional swirl flow, as proved in past studies, can result in time and cost saving methods in design and fabrication of combustion chambers. Bidirectional Swirl flow, existing in vortex engine, maintains the chamber wall cool. This characteristic of such flow field, among with many other advantages for it, makes researchers more interested in studying the propulsion of it as well as its other applications. Bidirectional swirl flow in liquid fuel ramjet engines has the proven advantage of keeping the combustion chamber walls cool and in solid fuel ramjet engines in increasing the... 

    Study and Development of Dual Porosity/Permeability Models for Simulation of Forced Gravity Drainage Mechanism in Fractured Porous Media

    , M.Sc. Thesis Sharif University of Technology Samimi Ardestani, Ehsan (Author) ; Massihi, Mohsen (Supervisor) ; Gerami, Shahab (Supervisor) ; Ganjeh Ghazvini, Mostafa (Co-Advisor)
    Abstract
    The available investigations show that gravity drainage mechanism in fractured reservoir make a high recovery factor in comparison with other mechanisms. In recent years, the forced gravity drainage assisted by gas injection is also introduced; despite of its importance there is no comprehensive modeling study in the literature. The fractured reservoir is simulated frequently by dual porosity models in which the transfer function is the key issue for this method of simulation. This study makes an effort by comparison of different transfer functions with fine grid simulation results of a single block model, in order to evaluate their ability for simulation of forced gravity drainage... 

    Analytical Modeling of Oil Production from a Matrix Block by Free Fall Gravity Drainage

    , M.Sc. Thesis Sharif University of Technology Ghorbani Zadeh, Salman (Author) ; Masihi, Mohsen (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Kharrat, Reyaz (Supervisor)
    Abstract
    Free fall gravity drainage is one of the most effective mechanisms of producing the oil from the matrix blocks in the gas invaded zone of the naturally fractured reservoirs. Although several analytical models have been proposed to characterize this mechanism in a matrix block, but these models suffer from the practical or theoretical viewpoints. In this study, a new analytical model was presented to predict the oil production rate versus time from a homogeneous matrix block under free fall gravity drainage mechanism. The model was developed by considering the balance between involved forces in the gas-oil gravity drainage process. By simplifying the equation derived from the momentum... 

    Experimental and Modeling Study of Two-Phase Relative Permeability at Near Miscible Condition

    , M.Sc. Thesis Sharif University of Technology Parvazdavani, Mohammad (Author) ; Masihi, Mohsen (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Rasaei, Mohammad Reza (Supervisor)
    Abstract
    One of the main parameters in modeling of two phase gas and oil flow is an accurate relative permeability functions. This importance will be more intensified when the miscibility condition approaches. In miscible condition due to reduction of interfacial tension between oil and gas phases, parameters of conventional relative permeability functions will change and this changing affects on production results such as oil and gas recovery and also pressure drop along the core. All of the previous studies could not present a unique and consistent model to show the effect of near miscibility condition on relative permeability curves. In this work, these changing of parameters will be investigated... 

    Experimental Investigation of ASP Flooding for EOR in Fractured Heavy Oil Reservoirs Using Micromodel Apparatus

    , M.Sc. Thesis Sharif University of Technology Sedaghat, Mohammad Hossein (Author) ; Massihi, Mohsen (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Rashtchian, Davood (Supervisor)
    Abstract
    Heavy oil reservoirs contain huge amount of initial oil in place in the world. Thus, enhancement of their production attracts lots of attention. Primary and secondary oil recovery methods have just little effects on the production of these reservoirs, thus, using innovative chemical methods which lead them to increase their mobility is recommended to improve their oil recovery efficiency. One of these proper and novel methods which has been established recently to enhance oil recovery is ASP1 flooding that can significantly increase oil recovery from petroleum heavy oil reservoirs. In addition, considerable numbers of reservoirs especially heavy oil reservoirs are fractured reservoirs. In... 

    Solvent effects on kinetics of an heteroatomic nucleophilic substitution reaction in ionic liquid and molecular solvents mixtures

    , Article Russian Journal of Physical Chemistry A ; Volume 87, Issue 12 , December , 2013 , pp 1969-1975 ; 1531-863X Salari, H. (Hadi) ; Pedervand, M. (Mohsen) ; Sadeghzadeh-Darabi, F. (Faramarz) ; Gholami, M. R. (Mohammad Reza) ; Sharif University of Technology
    2013
    Abstract
    Rate constants, k A, for the aromatic nucleophilic substitution reaction of 2-chloro-3,5-dinitropyridine with aniline were determined in different compositions of 2-propanol mixed with hexane, benzene, and 2-methylpropan-2-ol and 1-ethyl-3-methylimidazolium ethylsulfate ([Emim][EtSO4]) with dimethyl sulfoxide at 25°C. The obtained rate constants of the reaction in pure solvents are in the following order: 2-methylpropan-2-ol > dimethyl sulfoxide > 2-propanol > hexane > benzene > [Emim][EtSO4]. Molecularmicroscopic solvent parameters corresponding to the selected binary mixtures were utilized to study the kinetics of a nucleophilic substitution reaction in order to investigate and compare the... 

    Removal of an organic pollutant from waste water by photocatalytic behavior of AgX/TiO2 loaded on mordenite nanocrystals

    , Article Research on Chemical Intermediates ; Volume 38, Issue 8 , 01 September , 2012 , pp 1975-1985 ; 1568-5675 Padervand, M. (Mohsen) ; Salari, H. (Hadi) ; Ahmadvand, S. (Seyed Saeid) ; Gholami, M. R. (Mohammad Reza) ; Sharif University of Technology
    2012
    Abstract
    Mordenite (MOR) nanocrystals were synthesized using the hydrothermal method. Sol–gel and deposition methods were utilized to modify the zeolite surface with TiO2 and then AgBr or AgCl particles. Photocatalysts were characterized by using X-ray diffraction, Brunauer–Emmett–Teller (BET), and scanning electron microscopy techniques. Activity was evaluated by photodegradation of Acid Blue 92 as an azo dye. The effect of silver halide deposition on the photocatalytic behavior of the prepared nanocomposites was studied under both ultraviolet (UV) and visible light, and the results were compared. The results showed that AgCl/TiO2/MOR was more active under UV, while with visible source,... 

    Kinetic and mechanistic study of p-nitrochlorobenzene photoreduction and Bacillus inactivation over aluminosilicate-based nanocomposites

    , Article Monatshefte für Chemie - Chemical Monthly ; Volume 144, Issue 5 , May , 2013 , pp 589-596 ; ISSN: 1434-4475 Padervand, M. (Mohsen) ; Salari, H. (Hadi) ; Sadeghzadeh Darabi, F. (Faramarz) ; Gholami, M. R. (Mohammad Reza) ; Sharif University of Technology
    2013
    Abstract
    Photocatalytic reduction of p-nitrochlorobenzene was studied over aluminosilicate-based AgBr and AgBr-TiO2 photocatalysts which were prepared and characterized. The photoreaction was performed in the presence of LiBH4, which is a strong reducing agent, in the solution medium. A new mechanism is proposed for reduction of p-nitrochlorobenzene under photocatalytic conditions. The effect of pH, illumination source, LiBH4 concentration, temperature, catalyst dosage, and alcoholic scavengers was also studied. The results showed that the best efficiency was obtained over Ag/AgBr/TiO2/aluminosilicates at natural pH under UV light. We observed that the reaction yield was affected by changing the... 

    Aspects of Entanglement in Quantum Field Theory and Quantum Gravity, using the Holography

    , Ph.D. Dissertation Sharif University of Technology Faraji Astaneh, Amin (Author) ; Arfaei, Hessamaddin (Supervisor) ; Mosaffa, Amir Esmaeil (Supervisor) ; Alishahiha, Mohsen (Co-Advisor)
    Abstract
    Entanglement is an immediate consequence of quantum mechanical pos- tulates and is thus an indispensable part of studying quantum systems. A very useful quantity which can appropriately quantify entanglement between the degrees of freedom of a composite quantum system is En- tanglement Entropy (EE).
    Over the last few years, this subject has attracted a lot of interest both in QFT and in the context of holography. On the one hand, an intu- itive geometrical Holographic model for entanglement entropy has been proposed in the context of gauge/gravity duality, and on the other, var- ious issues concerning entanglement have been explored, e.g. in quan- tum computation, quantum information... 

    Preparation of Thermosensitive Polymer Nanoparticles to Apply in Smart Enhanced Oil Recovery Process

    , Ph.D. Dissertation Sharif University of Technology Tamsilian, Yousef (Author) ; Ramazani Saadatabadi, Ahmad (Supervisor) ; Ayatollahi, Shahabeddin (Supervisor) ; Masihi, Mohsen (Co-Advisor)
    Abstract
    With the decline in oil discoveries during the last decades, it is believed that enhanced oil recovery (EOR) technologies will play a key role to meet the energy demand in coming years. Polymer flooding has been commonly used worldwide as one of the EOR processes. Literature reviews show that the active water-soluble polymers have a number of limitations related to their surface absorption, undesirable plugging, polymer concentration limitation,expensive, and low thermal, mechanical, bacterial, and salt tolerance. Up to now, five different polymer categories (i.e. polyacrylamide, hydrolyzed polyacrylamide, acrylamidebased resistant copolymers, associative copolymers, and thermoassociative... 

    Investigation the Minimum Miscibility Pressure for Crude oil with Different Asphaltene Content using Vanishing Interfacial Tension Method

    , M.Sc. Thesis Sharif University of Technology Hemmati-Sarapardeh, Abdolhossein (Author) ; Ayatollahi, Shahab (Supervisor) ; Masihi, Mohsen (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor)
    Abstract
    Interfacial Tension (IFT) as a main parameter for gas flooding efficiency in oil reservoirs depends highly on pressure, temperature, and composition of the reservoir fluids. Therefore, it is important to measure this parameter at real reservoir condition for successful field development plan. In this study, an axisymmetric drop shape analysis (ADSA) has been utilized to measure the equilibrium IFTs in crude oil-CO2 as well as crude oil-N2 systems at different temperatures and pressures. Moreover, minimum miscibility pressures (MMP) and first-contact miscibility pressures (Pmax) of crude oil/CO2 and crude oil/N2 systems at different temperature levels are determined by applying vanishing... 

    Identifying Gene Expression Patterns in Memory T Cell Development

    , M.Sc. Thesis Sharif University of Technology Nazer Kakhki, Naghmeh Sadat (Author) ; Mohammadzadeh, Hoda (Supervisor) ; Hossein Khalaj, Babak (Supervisor) ; Basiri, Mohsen (Co-Supervisor)
    Abstract
    T lymphocytes or T cells are a type of white blood cell that play an important role in the immune system. Memory T cells are a subset of them that are able to reactivate when being re-exposed to the pathogen. Because of the properties of these cells, they are an attractive choice for immunotherapy. Initial memory subgroups were shown to be more persistently effective in immunotherapies. However little is known about development and differentiation of these subgroups. With the discovery of a new subset of T cells, called T memory stem cells (TSCM), They are considered to develop through four stages, naive T cells (TN), T memory stem cells (TSCM), central memory T cells (TCM) and effector... 

    A Study in Genome Editing with Clustered Regularly Interspaced Short Palindromic Repeats

    , M.Sc. Thesis Sharif University of Technology Rostami, Mohammad (Author) ; Sharifi Tabar, Mohsen (Supervisor) ; Rabiee, Hamid Reza (Co-Supervisor) ; Rohban, Mohammad Hossein (Co-Supervisor)
    Abstract
    Clustered Regularly Interspaced Short Palindromic Repeats, or in short, CRISPR is a relatively new technology that enables geneticists and medical researchers to edit parts of the genome by removing, adding, or altering parts of the DNA. Initially found in the genomes of prokaryotic organisms such as bacteria and archaea, this technology can cure many illnesses such as blindness and cancer. A significant issue for a practical application of CRISPR systems is accurately predicting the single guide RNA (sgRNA) on-target efficacy and off-target sensitivity. While some methods classify these designs, most algorithms are on separate data with different genes and cells. The lack of... 

    Investigation of The Effect Of Microgravity On Bone Marrow Stromal Cell Growth And Infiltration On An Optimized 3d Structured Scaffold

    , M.Sc. Thesis Sharif University of Technology Ahmadi, Armin (Author) ; Yaghmaei, Soheila (Supervisor) ; Vossoughi, Manouchehr (Supervisor) ; Haji Ebrahimi, Zahra (Supervisor) ; Janmaleki, Mohsen (Co-Supervisor)
    Abstract
    To develop a novel cell culture method for enhancement of bone marrow stromal cell growth and infiltration into the 3d electrospun PCL-based scaffold, we utilized the RPM system to simulate microgravity. In current study, six different scaffolds are produced using the electrospinningelectrospraying technique. These scaffolds are compared based on their structural (average diameter and SEM micrographs), mechanical (Tensile strength, elongation and wettability) and biological (Biodegradability, bioactivity, biocompatibility, cell adhesion, cell infiltration and antibacterial quality) characteristics. It is noted that the porous nano-hydroxyapatite/titanium hydroxide/polycaprolactone... 

    Colloidal gold nanoparticles: an unexpected catalytic activity in aqueous phase with dioxygen

    , Article catalysis letters ; Volume 144, Issue 7 , July , 2014 , pp. 1219-1222 ; 1572-879X Salari, H. (Hadi) ; Robatjazi, H. (Hossein) ; Hormozi-Nezhad, M. (Mohammad Reza) ; Padervand, M. (Mohsen) ; Gholami, M. R. (Mohammad Reza) ; Sharif University of Technology
    2014
    Abstract
    Selective oxidations of alkenes were investigated using molecular oxygen in aqueous solution under mild conditions. Colloidal gold nanoparticles are particularly versatile catalysts for oxidation reaction with exceptionally high efficiency and significant selectivity. Gold nanorods (Au NRs) exhibited a slightly enhanced activity compare to gold nanospheres  

    Geometrical Fracture Modeling Within Multiple-Point Statistics Framework

    , M.Sc. Thesis Sharif University of Technology Ahmadi, Rouhollah (Author) ; Masihi, Mohsen (Supervisor) ; Rasaei, Mohammad Reza (Supervisor) ; Eskandaridalvand, Kiomars (Supervisor) ; Shahalipour, Reza (Co-Advisor)
    Abstract
    Majority of the oil and gas reservoirs, in the main hydrocarbon production regions around the world, are naturally fractured reservoirs. Fractures play an important role in reservoir fluid flow either in the form of high permeable complex conduits or strong permeability anisotropies. Realistic characterization of naturally fractured reservoirs requires an exhaustive understanding of fracture connectivity and fracture pattern geometry. These subsequently demand description of many fracture parameters such as density (intensity), spacing, orientation, size and aperture. Therefore, a first step in fractured reservoirs characterization is the static geometric modeling of the subsurface fracture... 

    Experimental Investigation of New Polymers for Enhanced Oil Recovery from one of the Iranian Oil Reservoirs

    , M.Sc. Thesis Sharif University of Technology Torkaman, Mohammad (Author) ; Ramazani Saadatabadi, Ahmad (Supervisor) ; Masihi, Mohsen (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Rasaei, Mohammad Reza (Co-Advisor)
    Abstract
    Polymer flooding is a famous enhanced oil recovery method and is used to reduce mobility ratio of displacing fluid to displaced fluid by forming a stable front in displacing process. Due to high costs, polymer flooding faces economical risks and from this point of view, performance investigation of polymer flooding in laboratory scale was concerned. In this project, performance of 7 types of polymers which have different rheological properties were investigated in fractured/non-fractured carbonated and sandstone reservoirs. These polymers consists of 4 commercial polymers, one branched polymer, one synthetic polymer and one polymer composite which have different molecular weight,... 

    Molecular-microscopic properties and preferential solvation in protic ionic liquid mixtures

    , Article Journal of Solution Chemistry ; Volume 42, Issue 9 , October , 2013 , pp. 1757-1769 ; 1572-8927 Salari, H. (Hadi) ; Ahmadvand, S. (Seyedsaeid) ; Harifi-Mood, A. R. (Ali Reza) ; Padervand, M. (Mohsen) ; Gholami, M. R. (Mohammad Reza) ; Sharif University of Technology
    2013
    Abstract
    Structural and molecular-microscopic properties of the solvatochromic probes 4-nitroaniline, 4-nitroanisole, and Reichardt’s dye were investigated in binary mixtures of ethylammonium propionate with methanol, ethanol, 1-propanol and 2-propanol. Solvatochromic parameters (α, hydrogen-bond donor acidity; β, hydrogen-bond acceptor basicity; π*, dipolarity/polarizability; ENT , normalized polarity parameter) in different binary mixtures of ionic liquid with molecular solvents were determined with UV–Vis spectroscopy. The ENT parameters show nearly ideal trends in all solvent mixtures, but the other parameters show different behavior in the mixtures. The π* parameters show a negative deviation... 

    Synthesis and Evaluation of Nanostructured ZIF-67-Based Electrocatalysts for Oxygen Evolution Reaction

    , M.Sc. Thesis Sharif University of Technology Bairami Sorkhehrizi, Zahra (Author) ; Khorasheh, Farhad (Supervisor) ; Ghotbi, Sirus (Supervisor) ; Larimi, Afsaneh Sadat (Supervisor) ; Esmaeilpour, Mohsen (Co-Supervisor)
    Abstract
    Today, due to the decreasing of fossil fuel reserves and the need to use clean fuels, hydrogen is a suitable alternative, and hydrogen production has received considerable attention. One of the best methods of hydrogen production is water splitting. Overall water splitting can be divided into two half reactions including the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), which selecting the appropriate electrocatalyst for these half reactions plays an important role. The four-electron transfer process in OER leads to slow kinetics of the reaction and a large overpotential. The noble metal-based oxides, including IrO2 and RuO2, are known as outstanding OER... 

    Simulation of Asphaltene Slurry Flow for Oil Dominant Systems in Vertical Wells

    , Ph.D. Dissertation Sharif University of Technology Tavakkoli, Mohammad (Author) ; Taghikhani, Vahid (Supervisor) ; Pishvaie, Mahmoud Reza (Supervisor) ; Masihi, Mohsen (Co-Advisor) ; Chapman, Walter (Co-Advisor) ; Panuganti, Sai (Co-Advisor)
    Abstract
    In the upstream asphaltene flow assurance community, both academics and industries are actively involved to predict the asphaltene deposit profile in wellbores and pipelines. The main objective of this study is to contribute to the thermodynamic and transport modeling of asphaltene in order to predict its precipitation, aggregation and deposition. For a better knowledge of the flow properties of asphaltene containing crude oils, it is necessary to understand how asphaltene affect the rheological properties. In this work, the information on such rheological properties of oil-asphaltene slurry systems is provided. The results of rheological experiments for two Iranian crude oils show that the...