Sharif Digital Repository

Harvesting energy by magnetic shape memory alloy has many advantages against other various methods which harvested from environmental vibrations and has been considered due to high long longevity, large strain amplitude and good performance in low frequencies. These materials can display up to % recoverable strain in response to the application of a magnetic field or compressive mechanical stress. Microstructure of these materials changes under applying mechanical loading and/or magnetic field which cause magnetic vector rotating in magnetic domain. Change in magnetization of these materials, lead to harvesting energy by considering Faraday's law of induction. The model of this... 

In response to the growing energy consumptions levels in buildings, many countries have introduced standards and codes aimed at reducing their national building energy consumption levels as well as managing the amount of pollutants. Title 19 of Iran’s National Building Regulation (NBR) was first introduced in 1991. It is projected that Title 19 can lead to a 30 to 50% reduction in the amount of buildings energy consumption. Nevertheless, evidence suggests that the introduction of Title 19 NBR has not led to substantial reduction in building energy consumption in Iran. Unlike Title 19 NBR, similar standards in other countries have proven to be very effective in reducing the building energy... 

Annular combustion chambers used in small turbine motors which incorporate centrifugal (rotary) injectors for injecting fuel, are known as Slinger combustion chambers. The Slinger injector works in such a way that fuel enters from an inner tube in motor shaft and exits with high pressure from the holes on the cylinder connected to the shaft. Because of the high centrifugal force, the fuel is sprayed with high quality after entering the combustion chamber. Type and angle of spray, fuel-air mixing type, combustion phenomena and flame stability makes this different than other annular combustion chambers. The process of combustion in the Slinger chamber of YJ402 motor is numerically simulated in... 

StorAge selection (SAS) functions describe the mechanism by which water particles with different ages exit a hydrological system through outfluxes such as streamflow and evapotranspiration (ET). The shape of the ET SAS functions affects the storage residence time distributions, ET travel time distributions, and discharge travel time distributions that control the hydrochemical dynamics of water. They also carry fundamental information to understand the response behavior of the system, and are affected by processes such as precipitation, outflow, ET, as well as the physical properties of the system. To better understand the shape of these functions, other important factors such as the type... 

This study aimed to investigate the efficiency of machine learning algorithms in capturing the dynamics of water particles' age distribution and in estimating the time series of median travel time (MTT) in river basins. The mechanism of solute transport in a catchment does not follow the hydrograph shape of the catchment and depends on the spatial and temporal distribution of solute resident time. The equations governing the age dynamics of water particles discharged from a catchment have been presented analytically in recent research. These equations showed that the transfer of solutes depends on various factors, including climatic conditions, basin topography, and basin vegetation. Also,... 

Water shortage, population growth, and high levels of urban water demand are among main challenges of water demand management for developing countries and cities, and also for megacities. Urban water management systems, as they are complex adaptive systems, complex interactions exist among elements affecting the system. In other words, action from a subpart can trigger other parts, and also the whole system to respond in reaction. In this study, socio-economic water consumption behavior of households is studies and simulated in an agent-based modeling platform. First, households are interviewed and, using the qualitative data extracted from interviews and also the behavioral science... 

The purpose of this study is to introduce a new indicator to estimate the amount of irrigation water in excess of the need and also to determine the optimal irrigation pattern to reduce water loss in agriculture. According to the Food and Agriculture Organization of the United Nations, the major loss of fresh water takes place in agriculture, and the reduction of water resources is more significant in developing countries that do not have advanced agricultural equipment. One of the challenges in the studies related to reducing the amount of water used in agriculture is a lack of knowledge on the spatial distribution and temporal changes in water loss in a region. Although estimation of... 

Commercial solid phase microextraction fibers posses a few drawbacks such as relatively low recommended operating temperature, instability and swelling in organic solvents, breakage of the fiber, stripping of coatings, and bending of the needle. Some of these problems have been obviated by covalent bonding of the polymer phase to the fused-silica substrate by sol-gel technology, but the easy breakage of the fiber remains a problem. In this study a new technique for preparation of unbreakable, thin and very porous fiber coatings for solid phase microextraction was proposed. In this technique firstly an intermediate film consisting ... 

Attentions to nano materials due to their vast applications in different branches of science and technology have been remarkably increased in recent years. Nanofibers are an important class of nano materials which could be used as novel sorbents because of their high surface to volume ratio as a result of long lengths and nano-to-micro-scale diameters. Electrospinning is a broadly used technology which utilizes high electrostatic forces for producing nanofibers. In this study a novel high temperature resistant solid phase microextraction (SPME) fiber was prepared besed on Polyetherimide (PEI) by this method. The porosity of the PEI fiber was investigated by scanning electron microscopy... 

This thesis deals with the synthesis and characterization of some nanostructured conductive polymers and their applications toward microextraction of drugs, environmental pollutants and pesticides from aqueous and biological samples. In chapters 3–6, silver nanoparticles and their relevant nanocomposites were applied as the desired extracting media while in the last chapter, a polyaniline nanocomposite, containing titanium oxide nanoparticles, was synthesized and employed as an efficient medium for the extraction purposes. In the first work, a nanocomposite based on polyaniline-silver nanoparticles (PANI-Ag NPs) was synthesized and used as an extraction medium for microextraction in packed... 

A green aerogel was prepared by synthesizing amine-modified lignin from sugarcane bagasse and further modification by CS2 and subsequent freeze drying. This aerogel was implemented as an extractive phase in a home-made online micro solid phase extraction-high performance liquid chromatography (μSPE-HPLC) setup for analyzing cardiovascular drugs (valsartan and losartan) in urine samples. To study the effect of functionalization, bare or functionalized lignin powders were mixed with graphene oxide (GO) at different ratios while functionalized lignin showed the highest efficiency. The prepared aerogel was analyzed using CHNS elemental analysis, and FT-IR spectrometry. Effects of influencing... 

Nowadays, cleanrooms have a growing application in a broad range of industries, e.g. pharmacy, aerospace, nuclear energy and electronics. So, it seems that numerical modeling of airflow in such spaces becomes more essential. As computational fluid dynamics has become a powerful tool for indoor airflow studies, in this research, influence of effective parameters on the flow and concentration distribution in cleanrooms has been investigated by the use of CFD. To do so, aerosol flow in a 3-D cleanroom has been numerically modeled by Fluent 6.3, using Euler-Euler approach and standard k- turbulence model. Comparison between numerical results and experimental data shows a considerably good... 

Due to reliability importance in military and industrial sectors, increasing of reliability is inevitable. One of the most important ways to increase the reliability of a system is to use cold and warm standby components. In this thesis, the analysed system is a nonrepairable k out of n system consist of hot, warm and cold components. Considering the importance of switch operation in this system the imapcts of switches on the overall system reliability has been analysed. The behavior of components and switches oby exponential distribution. The hazard rate for hot, warm and cold components is shown respectively by, and. Also the hazard rate of switch for cold to warm is shown by and for... 

Many of Iran's wetlands are going dry because of the expansion of anthropogenic activities like the exorbitant withdrawal of groundwater resources and excessive use of water for agricultural purposes. Bakhtegan, Hoor-ol-azim, Anzali, and Miankaleh are some of the most notable examples of this issue in the past two decades. The crucial role of wetlands in preserving the biodiversity of flora and fauna and supplying groundwater resources necessitates continuous monitoring of the quantitative and qualitative changes in the surface water of wetlands. The main focus of this research is quantifying the reduction in wetlands' surface water using K-means and random forest algorithms based on... 

Sample preparation gradually becomes a major part of analysis, capable of taking up to 80% of the total time of a complete separation-based analytical process, which typically includes five steps, that is sampling, sample preparation, separation, detection and data analysis. Environmental application is a main cause driving the development of many procedures of sample preparation due to the increased public awareness that environmental contaminants are a health risk. The increased demands in the analysis of foods and natural products have brought another pressure to develop the technologies of sample preparation. The appearance of more sensitive and reliable methodology to monitor... 

This research is a bout a novel sample prepration procedure that used polypyrrole film into a stainless steel needle as a fiber coating for solid phase dynamic extraction(SPDE) with using a home-made SPDE devise and gas chromatography – mass spectroscopy for the extraction and detectionof Atrazine from the aqueous sample in direct mode of SPDE. Polypyrrole film was directly electrodeposited into the needle in a aqueous sodium dodecyl sulfonate solution with pecial set up in optimom condition of potential, time and concentration of polypyrrole. To enhance the sensitivity of the SPDE , variables affecting adsorption and desorption steps such as temperature,time,PH, flowrate and ionic strength...