Sharif Digital Repository

The geometry structures of hexa-coordinated [NiLX]X complexes (X = Cl -, Br-, I-) {L = 8,9,18,19-tetrahydro-7H,17H- dibenzo[f,o] [1,5,9,13]dioxadiaza cyclohexadecine-8,18-diol} are optimized by density functional theory (DFT) using B3LYP/LANL2DZ. The calculated geometric parameters are in good agreement with the corresponding experimental values. Calculation results about these complexes show that dipole moment decreases, and the energy levels of HOMOs descend from iodo-complex to chloro-complex. The energy levels of HOMOs descend gently from iodo-complex to chloro-complex, while the energy levels of LUMOs in the present complexes are almost similar; therefore the energy gapes between HOMOs... 

The granular activated carbon (GAC) was used as an adsorbent for its ability to remove haloacetic acids (HAAs) from drinking water by batch and column experiments. Various thermodynamic parameters, such as ΔG°, ΔH° and ΔS° have been calculated. The thermodynamics of HAAs onto GAC system indicates spontaneous and exothermic nature of the process. The ability of GAC to adsorb HAAs in a fixed bed column was investigated as well. The effect of operating parameters such as flow rate and inlet HAAs concentration on the sorption characteristics of GAC was investigated. The total adsorbed quantities, equilibrium uptakes and total removal percents of HAAs related to the effluent volumes were... 

The feasibility of a novel system to reliably estimate the normalized central blood pressure (CBPN) from the radial photoplethysmogram (PPG) is investigated. Right-wrist radial blood pressure and left-wrist PPG were simultaneously recorded in five different days. An industry-standard applanation tonometer was employed for recording radial blood pressure. The CBP waveform was amplitude-normalized to determine CBPN. A total of fifteen second-order autoregressive models with exogenous input were investigated using system identification techniques. Among these 15 models, the model producing the lowest coefficient of variation (CV) of the fitness during the five days was... 

Energy-Aware routing is a promising technique for reducing energy consumption in future networks. Under this scheme, traffic loads are aggregated over a subset of the network links, allowing other links to be turned off to save energy. Since the capacity of links is the main limiting constraint in this problem, to further improve energy saving, the idea of using redundancy elimination (RE) in energy-Aware routing has been proposed. As performing RE in routers consumes some energy, it should be specified, which routers should perform RE and which links should be deactivated so that the total energy consumption of the network is minimized. As a result, the problem of energy-Aware routing with... 

Porosity and permeability alteration due to the thermo-poro-elastic stress field disturbance from the cold fluid injection is a deciding factor for longer, more economic, and safer heat extraction from an enhanced geothermal system (EGS). In the Soultz-sous-Forêts geothermal system, faulted zones are the main flow paths, and the resulting porosity–permeability development over time due to stress reorientation is more sensitive in comparison with the regions without faulted zones. Available operational and field data are combined through a validated numerical simulation model to examine the mechanical impact on the pressure and temperature evolution. Results shows that near the injection... 

The main aim of the present paper is to assess the fatigue lifetime of ductile cast iron knuckles as one of the critical components of an automotive steering system. To this end, a real driving path, including various maneuvers, such as acceleration, braking, cornering, and moving on various types of road roughness, was considered. Different load histories, which are applied on various joints of the component (i.e., lower control arm, steering linkage, and Macpherson strut), were extracted through Multi-Body Dynamics (MBD) analysis of a full vehicle model. The achievements of previous studies have proved that the steering knuckle fails from the steering linkage and due to the rotational... 

Governments in developing countries have invested in institutions of higher learning in order to develop homegrown, high technology products. Among these, the National University of Malaysia (Universiti Kebangsaan Malaysia), recognized as a Research University, is actively involved in projects related to medical technology through its various faculties. The net result of these activities is impressing from the point of view of patents and publications, but unfortunately not yet in terms of commercialization. This paper starts by presenting the main obstacles towards the objective of bringing a laboratory prototype to the market in the context of Malaysia. Then, a framework is presented... 

In this research FeCl2/FeCl3/Perlite magnetic nanoparticles (FeCl2/FeCl3/PMNs), as a novel magnetic nanocomposite adsorbent was used for the removal of green malachite (GM) dye from aqueous solution in a batch and fixed bed column. Firstly, FeCl2/FeCl3/PMNs adsorption properties were investigated. Therefore, the solution of FeCl2·4H2O and FeCl3·6H2O by ratio 2/1 was mixed with perlite nanoparticles. The study investigates the effect of process parameters such as pH, adsorbent dosage, contact time and GM dye initial concentration. Next, GM dye was quantitatively evaluated by using the Langmuir, Freundlich and BET isotherms and pseudo-first- and pseudo-second-order kinetic model. The... 

In this paper, we prove the existence of capacity achieving linear codes with random binary sparse generating matrices over the Binary Symmetric Channel (BSC). The results on the existence of capacity achieving linear codes in the literature are limited to the random binary codes with equal probability generating matrix elements and sparse parity-check matrices. Moreover, the codes with sparse generating matrices reported in the literature are not proved to be capacity achieving for channels other than Binary Erasure Channel. As opposed to the existing results in the literature, which are based on optimal maximum a posteriori decoders, the proposed approach is based on a different decoder... 

Recycling of wastepaper is an effective way to achieve the sustainable paper manufacturing regarding sustainable development goals. Focusing on the mixed wastepaper sorting, recovery of suitable papers for deinking purpose and minimizing the impurities were developed in this study. In a wastepaper sorting process, each equipment has its own role in increasing recycling performance. In this study, disc screen was applied and evaluated for sorting of the mixed wastepaper considering independent variables such as inclination, velocity and moisture content. Response surface method was applied for design of the experiments. Sorting efficiency of 100% was achieved in two conditions: 1–20%... 

Recycling of wastepaper is an effective way to achieve the sustainable paper manufacturing regarding sustainable development goals. Focusing on the mixed wastepaper sorting, recovery of suitable papers for deinking purpose and minimizing the impurities were developed in this study. In a wastepaper sorting process, each equipment has its own role in increasing recycling performance. In this study, disc screen was applied and evaluated for sorting of the mixed wastepaper considering independent variables such as inclination, velocity and moisture content. Response surface method was applied for design of the experiments. Sorting efficiency of 100% was achieved in two conditions: 1–20%... 

The present study is focused on the investigation of the absorption properties of the bi-layer absorber with different thickness and orientation approaches. Improvement in absorption exclusively depends on the various parameters as interfacial polarization, multiple reflections among layers, conduction loss, phase cancellations, and shape anisotropy, etc. By considering these parameters. Calcium titanate micro-cubes CaTiO3 (CTO) and polypyrrole nanotubes (PPy) nanocomposites were prepared and microwave absorption from single layer coaxial absorbers having M1 = CaTiO3+15 wt% polymer and M2 = CaTiO3+30 wt% polymer were determined. Different layer orientations and thicknesses of the bi-layer... 

Many high performance steganographic schemes work at a limited or sparsely distributed set of embedding rates. We have shown that some steganographic changes will be wasted as these schemes are utilized individually for messages of various lengths. To measure the wasted changes and compare different schemes in this respect, we have built a framework based on two new criteria: the Relative Change Waste (RCW) and the Expected Changes per Pixel (ECP). To decrease the wasted changes a systematic combination of schemes is introduced and proved to be equivalent to nonlinear interpolation of points in a two-dimensional space. We have proved that a special case which leads to a linear interpolation... 

A family of matrix embedding steganographic schemes for digital images is investigated. The target schemes are applied to blocks of n pixels in a cover image. In every block, at most m pixels are allowed to change with q-ary steps. We have derived some upper bounds on the embedding efficiency of these schemes for different values on m. It is also shown that these upper bounds approach the general upper bound on the embedding efficiency of q-ary steganography. For the case of q=3, we have shown that there is no feasible optimum member of the family for m=2, although for m=1, a well-known example exists. Instead, for m=2, a new close-to-bound scheme in the family is presented which exploits... 

In this paper, a numerical optimization method has been carried out to optimize the shape and efficiency of a propeller. For analysis of the hydrodynamic performance parameters, an extended vortex lattice method was used by implementing an open-source code which is called OpenProp. The method of optimization is a non-gradient based algorithm. After a trade-off between a few gradient-based and non-gradient based algorithms, it is found that the problem of being trapped in local optimum solutions can be easily solved by choosing nongradient based ones. Hence, modified Genetic algorithm is used to implement the so-called hydrodynamic performance analyzer code. The objective function is to... 

A four stage LC-ring oscillator is presented. Eight different phases are generated in which there in 45 degrees phase difference between consecutive outputs and direction of phases is defined. Nmos capacitors in parallel with constant capacitors are used for coupling between stages. The control voltage is applied to Pmos varactors to adjust the oscillation frequency. The advantages of this structure are the rather small inductors size, low power consumption, and tuning curve linearity. The proposed structure is simulated in 0.18um CMOS technology. Power consumption for each stage is 4.8mW from a 1.8B supply. The proposed VCO has a phase noise of -121dBc/Hz at 1MHz offset from the center... 

The objective of this paper is to demonstrate a topology optimization method subject to displacement and stress constraints. The method does not rely on pseudo-densities; instead it exploits the concept of topological level-set where 'partial' elements are avoided. Consequently: (1) the stresses are well-defined at all points within the evolving topology, and (2) the finite-element analysis is robust and efficient. Further, in the proposed method, a series of topologies of decreasing volume fractions are generated in a single optimization run. The method is illustrated through numerical experiments in 2D  

A novel class AB architecture for single stage multipath differential amplifier is presented. The proposed amplifier combines the flipped voltage follower(FVF) for differential input and the nonlinear current mirror for active load. Applying these techniques to telescopic-cascode amplifier increases the unity-gain bandwidth, the DC gain and the slew rate while the same power consumption as the conventional telescopic cascade is achieved  

The performance of a three-dimensional optical code-division multiple-access system based on polarization-wavelength-time codes is investigated. The unwanted effects of multiple access interference are first studied and an accurate enough expression is given for the upper bound of the bit error rate. The proposed expression is obtained by decomposing the three-dimensional polarization-wavelength-time codes into horizontally and vertically polarized two-dimensional wavelength-time codes that are assumed to be statistically independent. It is shown by Monte Carlo simulation that the assumption of independence gives accurate enough bit error rate, whenever the number of chips is much larger... 

The performance of the adaptive spatial resolution technique is improved by making the resolution function of the coordinate transformation as smooth as possible. To this end, the smoothness of the resolution function is probed and a quantitative criterion is proposed to make the jump points; which were conventionally equidistant from each other, regularized. The here-proposed regularization is applied to two different recent formulations and its effects on the overall convergence rate and on the presence of numerical artifacts in analysis of highly conducting gratings are studied. Dielectric and metallic gratings at optical and microwave frequencies are considered and the helpfulness of the...