Sharif Digital Repository

An efficient synthesis of pentacyclic indole derivatives is achieved via domino Knoevenagel-hetero-Diels-Alder reactions of indolin-2-thiones and O-propargylated salicylaldehyde derivatives in CH3CN in the presence of 10 mol % of ZnO as a heterogeneous catalyst. The products are formed in good to excellent yields  

N-Benzyl-DABCO tribromide, a stable, solid organic ammonium tribromide, has been used as a bromine source for the regioselective and high-yielding bromination of aromatic amines and phenols. Mono-bromination proceeds well in the presence of a stoichiometric amount of bromine source at room temperature  

This paper presents the results of an experimental and analytical study on the improvements gained in the axial compressive behavior of confined concrete. Among several parameters affecting compressive ductility of confined concrete, including confinement mechanical volumetric ratio, shape and size effect, number of confinement layers, strength of plain concrete and ductility of confining material, the latter was found to play the most important role in determining the ultimate strain and post peak behavior of concrete. Axial compressive tests were performed on small-scale circular or square section concrete columns, which were retrofitted either by CFRP jacket or by two types of... 

This paper presents the results of an experimental study on the application of pre-stressed high strength metal strips in retrofit of RC columns. Six 2/3 scale were deliberately designated with insufficient transverse reinforcement details and tested under constant axial and cyclic lateral load reversals. The level of axial load and the pattern of strengthening were parameters of this study. It was observed that the technique has been capable to enhance the lateral behavior of columns significantly, in terms of ductility. Very ductile behavior was obtained. The height-wise variations of lateral strain on confining strips are studied. The analysis of the fiber-based model of tested columns... 

Benzothiazoles were readily prepared in one step from thiobenzanilides using N-bromosuccinimide in CH2Cl2-CCl4 (1:1V/V) at room temperature, with good yields under mild reaction conditions  

The study of the anisotropy of the arrival directions is an essential tool to investigate the origin and propagation of cosmic rays primaries. A pentagon array has been designed to collect data around the knee region of cosmic ray spectrum. The experimental results of this array obtained from October 2016 to October 2017. During this period, more than 5.3×105 extensive air shower events at energies in the decade below 1 PeV has been accumulated by this array at Sharif University of Technology in Tehran (35°43′N, 51°20′E, 1200m a.s.l=890 g cm-2). In analyzing the data set, we have used appropriate techniques of analysis and considered environmental effects. We report the analysis of the... 

A facile and efficient synthesis of 2-oxindole derivatives bearing tetrahydropyrazine scaffold has been developed. Using water as solvent without any additional acid or metal catalyst, easy work up and high yield of products are the main advantages of this protocol. © 2018 Wiley Periodicals, Inc  

This study describes an odorless protocol for the synthesis of unsymmetrical sulfides via cobalt ferrite (CoFe2O4) catalyzed cross-coupling reaction of nitroarenes with alkyl halides in the presence of thiourea as sulfur source under ligand-free conditions. The catalyst was recycled using external magnetic field and reused for ten consecutive runs in the reaction of nitrobenzene, thiourea and benzyl bromide without significant loss of activity. Apart from being magnetically separable, being inexpensive and air-stable are another important features of this catalytic system. All the products were formed in good yields and short reaction times. © 2017 Elsevier B.V  

A rescheduling method for new order arrival is presented based on the concept of dynamic pegging in multi-level production. Upon the arrival of new, unplanned orders, dynamic pegging enables the re-assignment of the Work-In-Progress (WIP) to the existing or newly arrived orders in such a way that the cost of rescheduling is minimized. A simple yet inspiring Mixed Integer Programming (MIP) model is proposed that combines dynamic pegging with rescheduling. The resulting schedules are compared with the ones obtained from two other basic rescheduling approaches. Analysis of the comparisons confirm the superiority of the proposed method in terms of total rescheduling costs. © 2019  

An efficient and unprecedented green protocol has been developed for the synthesis of N,S-heterocycles from styrenes and alkyl dithiocarbamates with high to excellent yields. The reaction of primary or secondary amines, CS 2, and styrenes was carried out in water in the presence of a catalytic amount of an inorganic base. All products were made by using an N -bromosuccinimide-H 2O combination as a green and inexpensive reagent. © 2020 American Institute of Physics Inc.. All rights reserved  

This paper presents a new predictive-reactive rescheduling method for adjusting production schedules in response to the unplanned arrival of new orders in multi-level production. It is based on the concept of dynamic pegging, which enables the reassignment of the Work-In-Progress (WIP) to the existing or newly arrived orders at the time of rescheduling. Extending our previous work on reactive rescheduling with dynamic pegging, the new approach incorporates a probabilistic predictive model of new order arrival in the initial scheduling at the begging of the scheduling horizon. A Mixed Integer Programming (MIP) model is developed for two-phase, predictive-reactive scheduling before and after... 

Palladium nanoparticles immobilized on the magnetic nanoparticles@2-amino-N-(2-aminoethyl) benzamide (MNPs@A-N-AEB.Pd0) have been presented as an efficient, and reusable magnetically heterogeneous catalyst for the C-O coupling reaction, namely Ullmann condensation reactions in an aqueous medium. This heterogeneous catalyst shows superior reactivity for the C-O arylation of different aryl halide (chloride, bromide, and iodide) with phenol derivatives to afford the desired products in good to excellent yields within short reaction time. Moreover, the catalyst can be easily recovered and reused for seven runs without loss of catalytic activity. The catalyst was characterized by several... 

An eco-friendly gold-based catalyst supported on proline decorated montmorillonite was synthesized. The catalyst was characterized by combination of Fourier-transform infrared spectroscopy (FT-IR), Field Emission Scanning Electron Microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Brunauer–Emmett Teller (BET) surface area analysis, Ultraviolet–visible spectroscopy (UV-Vis), Energy-dispersive X-ray spectroscopy (EDX), thermo gravimetric analysis (TGA) and atomic absorption spectroscopy (AAS) techniques. The synthesized catalyst was found to be a highly efficient heterogeneous nanocatalyst for multi component A3 coupling reaction of aldehyde, amine and alkyne... 

Motion blur is one of the most common blurs that degrades images. Restoration of such images is highly dependent on estimation of motion blur parameters. Since 1976, many researchers have developed algorithms to estimate linear motion blur parameters. These algorithms are different in their performance, time complexity, precision and robustness in noisy environments. In this paper, we have presented a novel algorithm to estimate linear motion blur parameters such as direction and length. We used Radon transform to find direction and bispectrum modeling to find the length of motion. Our algorithm is based on the combination of spatial and frequency domain analysis. The great benefit of our... 

ZnO nanopowder has been successfully synthesized by a microwave-assisted solution approach using Zn(CH3CO2)2·2H2O and NaOH. The results obtained from X-ray diffraction (XRD), scanning electron microscopy (SEM) and transition electron microscope (TEM) show that the mean particle size is 30 nm. SEM and TEM micrographs of ZnO nanopowder also reveal that nanoparticles have spherical shape. Catalytic activity of ZnO nanopowder for O-acylation of alcohol and phenol has been investigated. The results show that the reaction time by using ZnO nanopowder has been reduced by almost 24 times with higher yield than ZnO bulk. © 2007  

In this article, behavior of cantilever retaining walls with various flexibilities, which retain saturated cohesive soil behind, is studied using numerical modeling. Generally, pattern of lateral earth pressure behind retaining walls is complex and this complexity becomes greater for clayey soils. In this investigation, effects of different wall bending stiffnesses, and backfill drainage conditions on the failure height and on the lateral earth pressure are investigated using finite elements. Comparison between the obtained results from numerical simulation and those based on empirical or conventional design methods indicate that soil-structure interaction and c drainage conditions play... 

This paper presents a simulation-based study of the stuck-open fault testing in CMOS logic circuits. A novel built-in self-test (BIST) technique is presented for detecting stuck-open faults in these logic families. This scheme does not need test-pattern generation, and thus can be used for robust on-line testing. Simulation results for area, delay, and power overheads are presented. © 2007 IEEE  

Motion blur is one of the most common causes of image degradation. Restoration of such images is highly dependent on accurate estimation of motion blur parameters. To estimate these parameters, many algorithms have been proposed. These algorithms are different in their performance, time complexity, precision,and robustness in noisy environments. In this paper, we present a novel algorithm to estimate direction and length of motion blur,using Radon transform and fuzzy set concepts. The most important advantage of this algorithm is its robustness and precision in noisy images. This method was tested on a wide range of different types of standard images that were degraded with different... 

(Chemical Equation Presented) An efficient and simple route is presented to the synthesis of some iminothiazolidinone derivatives. α-Chloro amide derivatives undergo coupling reaction with isothiocyanate in the presence of a mild base, followed by nucleophilic substitution of chlorine by the sulfur atom of isothiocyanate