Sharif Digital Repository

Growth of the world population, increasing demand for fossil fuel consumption and consequently increasing threat of global warming, has extended the need for production and use of clean fuels and normal hydrogen is an important utility in the production of clean fuels. In this paper, a mathematical optimization method is applied which is based on non-linear programming of superstructure for minimizing the consumption of hydrogen. The method considers all the pressure constraints and is suited for revamping industrial systems. The optimum placement of new equipments like purification unit has been also considered. It is tried to verify the method adopted, in addition, an industrial case study... 

This paper presents a state of the art review of adsorption models for a new plant-based surfactant adsorption onto sandstone minerals. The adsorption data at both kinetic and equilibrium modes were obtained from batch experiments. Four adsorption kinetic models, five two-parameter, and six three-parameter equilibrium models were used for interpretation of the obtained data. Among the two and three-parameter isotherm models applied, the Jovanovic and the Khan isotherms showed the best fit, respectively. And the pseudo-second order model presented a better fit than other kinetic models. Finally, a computer-based modeling approach was developed and used for predicting the kinetics of... 

The immiscible process appears to be one of the first feasible methods for the extraction of oil reserves. However, there is a lack of fundamental understanding of how fracture geometrical characteristics control the efficiency of oil recovery in this type of enhanced oil recovery technique. In this article, a series of experiments were conducted whereby the distilled water displaced n-decane in strongly oil wet glass micro-models having different fracture geometries. Breakthrough time, as a function of injected pore volume of distilled water, was measured using image analysis of the provided pictures. It has been observed that when the fractures' length is increased, the breakthrough time... 

Most of the reservoirs in Iran are heterogeneous fractured carbonate reservoirs. Heterogeneity causes an earlier breakthrough and an unstable front, which leads to a lower recovery. In this study, a series of experiments was conducted whereby the n-Heptane displaced n-Decane in glass micromodels having different fracture geometries. Experimental data from image analysis of miscible displacement processes are used to modify the fractional flow equations by a heterogeneity factor. It is shown that the heterogeneity factor in the modified equations can be expressed as a function of fracture length and orientation  

This paper presents a state of the art review of adsorption models for a new plant-based surfactant adsorption onto sandstone minerals. The adsorption data at both kinetic and equilibrium modes were obtained from batch experiments. Four adsorption kinetic models, five two-parameter, and six three-parameter equilibrium models were used for interpretation of the obtained data. Among the two and three-parameter isotherm models applied, the Jovanovic and the Khan isotherms showed the best fit, respectively. And the pseudo-second order model presented a better fit than other kinetic models. Finally, a computer-based modeling approach was developed and used for predicting the kinetics of... 

Most of the reservoirs in Iran and also around the world are in the middle of their production life and have passed their natural production period. Therefore, they should be a candidate for immiscible injection, e.g., water injection for secondary recovery, and/or miscible injection, like solvent injection for tertiary recovery. Also, it should be pointed out that most of the Iranian reservoirs are carbonate reservoirs. This type of reservoir is fractured and heterogenic. Heterogeneity causes an earlier breakthrough and immiscible injection causes an unstable front, which leads to a lower recovery. This article presents the modified equation of Buckley-Leverett and fractional flow... 

This paper concerns with the interfacial tension (IFT), wettability modification and adsorption behavior of a new plant-based surface active agent, Zizyphus Spina Christi, onto sandstone minerals which has been rarely attended in the available literature. Both kinetics and equilibrium adsorption data were obtained from batch mode tests. It was revealed that Freundlich isotherms matched better fit to the equilibrium data which implied that multilayer coverage of Zizyphus Spina Christi onto the sandstone particle surfaces was more likely to occur. Analysis of experimental kinetic data based on intraparticle diffusion model disclosed that the intraparticle diffusion mechanism is not the only... 

In order to define a new temperature correction factor in this study, accurate experimental values were presented for permeability and diffusivity of carbon dioxide and methane in imidazolium-based room temperature ionic liquid: [bmim][PF6] (1-butyl-3-methylimidazolium hexafluorophosphate) immobilized on an inorganic membrane support. Results were presented as a function of temperature and pressure for temperatures within 300-320K and pressures below 50kPa. According to the literature, experimental values of permeability and diffusivity for CH4 in [bmim][PF6] vs. temperature are reported for the first time in this study. Results obtained for CO2 permeability revealed good agreement with data... 

In this work, to investigate the source of pressure fluctuations, behavior of a single bubble in a two-dimensional gas–solid fluidized bed was studied. Pressure sensors located at different heights of the bed measured presure fluctuations, and simultaneously a high speed camera was used to pursue all steps from formation to eruption of bubbles. Two types of particles were applied with different sizes and densities. Experiments showed that the maximum amplitude of formation was independent of the bubble diameter. But, it depended on density of particles, velocity of injection and the distance from bed surface. When injection stopped, there was a minimum in pressure profile related to the... 

During the last decade, the importance of process development has persuaded researchers to propose a great number of optimization models on "production planning" and "production scheduling" for different productive processes. Although many scheduling and planning models are proposed in the past decade, there are few models that handle various applicable goals. In this paper the main objective is developing and extending the traditional scheduling formulations to accommodate optimization of utility (especially energy barriers) demands and supplies. In the context of optimization, the final formulation takes the form of a mixed-integer programming. For this purpose a mathematical model is... 

The optimization of chemical syntheses based on superstructure modeling is a perfect way for achieving the optimal plant design. However, the combinatorial optimization problem arising from this method is very difficult to solve, particularly for the entire plant. Relevant literature has focused on the use of mathematical programming approaches. Some research has also been conducted based on meta-heuristic algorithms. In this paper, two approaches are presented to optimize process synthesis superstructure. Firstly, mathematical formulation of a superstructure model is presented. Then, an ant colony algorithm is proposed for solving this nonlinear combinatorial problem. In order to ensure... 

There are different well-established strategies for making a process plant inherently safer. The benefits of applying these strategies on reducing the overall risk inside a plant are obvious. However, some of these changes are rejected many times because they appear to be too costly. But if the effects of applying inherently safer design strategies are investigated not only on the processing costs of a plant but also on the potential accident costs, the decision would in fact be different. In this paper an optimization procedure is proposed which integrates both processing and accident costs for different design schemes. In this procedure, some of the design variables are chosen with regard... 

The uncertainty and the complexity associated with the domino effect is a barrier to assessing the frequency of such accidents analytically. The use of simulation techniques, such as Monte Carlo, to examine the domino effect instead of analytical techniques has shown great promise. In this paper, a new method to assess the frequency of domino accidents is proposed-FREEDOM II-which is an improvement on the recent algorithm proposed by the authors (FREEDOM). The modifications on FREEDOM were carried out to overcome a limitation of the method and to extend its capabilities. A key shortcoming of the earlier method was its inability to handle multiple failure scenarios. This shortcoming has been...